| Identification | More | [Name]
Allyltributyltin | [CAS]
24850-33-7 | [Synonyms]
ALLYLTRIBUTYLSTANNANE
ALLYLTRIBUTYLTIN
ALLYLTRIBUTYLTIN(IV)
ALLYLTRI-N-BUTYLTIN
TRIBUTYL-2-PROPENYLSTANNANE
Stannane, tributyl-2-propenyl-
Allytri-N-Butyltin
Allyltri-n-butyltin,97%
allyltri-n-butylstannane
tri-n-butyl-2-propenylstannane
(2-Propenyl)tributylstannane
2-Propenyltributylstannane
Tributylallylstannane | [EINECS(EC#)]
246-494-3 | [Molecular Formula]
C15H32Sn | [MDL Number]
MFCD00010346 | [Molecular Weight]
331.12 | [MOL File]
24850-33-7.mol |
| Chemical Properties | Back Directory | [Appearance]
CLEAR COLOURLESS LIQUID | [Melting point ]
134-135 °C | [Boiling point ]
88-92 °C0.2 mm Hg(lit.)
| [density ]
1.068 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.486(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
2-8°C
| [form ]
Liquid | [color ]
Clear colorless | [Specific Gravity]
1.068 | [Water Solubility ]
Immiscible with water. | [Hydrolytic Sensitivity]
1: no significant reaction with aqueous systems | [Sensitive ]
Air Sensitive | [BRN ]
3588340 | [InChIKey]
YLGRTLMDMVAFNI-UHFFFAOYSA-N | [CAS DataBase Reference]
24850-33-7(CAS DataBase Reference) | [NIST Chemistry Reference]
Allyltributyltin(24850-33-7) |
| Safety Data | Back Directory | [Hazard Codes ]
T,N | [Risk Statements ]
R21:Harmful in contact with skin.
R25:Toxic if swallowed.
R36/38:Irritating to eyes and skin .
R48/23/25:Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed .
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S35:This material and its container must be disposed of in a safe way .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S27:Take off immediately all contaminated clothing .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [RIDADR ]
UN 2788 6.1/PG 2
| [WGK Germany ]
3
| [F ]
13 | [TSCA ]
No | [HazardClass ]
6.1 | [PackingGroup ]
II | [HS Code ]
29319019 |
| Hazard Information | Back Directory | [Chemical Properties]
CLEAR COLOURLESS LIQUID | [Uses]
Allylation reagent for aldehydes catalyzed by chiral Lewis acids1,2 and ytterbium(III) trifluoromethanesulfonate (cat. no. 430595).3 Undergoes tetrakis(triphenylphosphine)palladium(0) (cat. no. 216666) catalyzed coupling with iodoquinones4 and allyl acetates.5,6Efficient allylation of aldehydes leading to homoallylic alcohols with trichloro-1,3,5-triazene.7 | [Purification Methods]
A possible impurity is tributylchlorostannane — test for Cl as Cl ion after hydrolysing. Dissolve it in *C6H6 (or toluene), shake this with dilute aqueous NaOH, dry (CaCl2), filter, evaporate and distil the residue in a vacuum [Jones et al. J Chem Soc 1446 1947, Bristow Aldrichimica Acta 17 75 1984, Yamamoto Aldrichimica Acta 20 45 1987]. [Beilstein 4 IV 4317.] |
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