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ChemicalBook--->CAS DataBase List--->1560-54-9

1560-54-9

1560-54-9 Structure

1560-54-9 Structure
IdentificationMore
[Name]

Allyltriphenylphosphonium bromide
[CAS]

1560-54-9
[Synonyms]

ALLYLTRIPHENYLPHOSPHONIUM BROMIDE
TAL
allyltriphenyl-phosphoniubromide
allyltriphenylphosphonium
ALLYLTRIPHENYLPHOSPHONIUM BROMIDE (TAL)
Allyltriphenylphosphoniumbromide,99%
Phosphonium, triphenyl-2-propenyl-, bromide
2-Propenyltriphenylphosphonium bromide
Triphenyl(2-propenyl)phosphonium bromide
Triphenylallylphosphonium bromide
Triphenyl-prop-2-enylphosphanium bromide
[EINECS(EC#)]

216-332-6
[Molecular Formula]

C21H20BrP
[MDL Number]

MFCD00011808
[Molecular Weight]

383.26
[MOL File]

1560-54-9.mol
Chemical PropertiesBack Directory
[Appearance]

white crystalline powder
[Melting point ]

222-225 °C (lit.)
[storage temp. ]

Sealed in dry,Room Temperature
[form ]

Powder
[color ]

White
[Water Solubility ]

decomposes
[Sensitive ]

Hygroscopic
[BRN ]

3579053
[InChI]

InChI=1S/C21H20P.BrH/c1-2-18-22(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21;/h2-17H,1,18H2;1H/q+1;/p-1
[InChIKey]

FWYKRJUVEOBFGH-UHFFFAOYSA-M
[SMILES]

[P+](CC=C)(C1C=CC=CC=1)(C1=CC=CC=C1)C1C=CC=CC=1.[Br-]
[CAS DataBase Reference]

1560-54-9(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
[WGK Germany ]

3
[RTECS ]

TA1843000
[HS Code ]

29310095
[Toxicity]

mouse,LD50,intravenous,22mg/kg (22mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#01708,
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Allyl bromide-->Toluene
[Preparation Products]

1,3-Hexadien-5-yne.-->(7Z,9E)-dodeca-7,9-dienyl acetate
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Allyltriphenylphosphonium bromide(1560-54-9).msds
Hazard InformationBack Directory
[Chemical Properties]

white crystalline powder
[Uses]

Reactant for:
  • Preparation of a diol and carbamate chemistry library for common functional groups
  • Regioselective synthesis of alkenes via semihydrogenation and semihydrogenation-oxidation of dienes
  • Alkene addition of frustrated Lewis pairs
  • Olefination of N-sulfonyl imines for stereoselective synthesis of vinyl arenes
  • Wittig olefination of aldehydes for preparation of conjugated dienes
  • Tandem Michael addition / ylide olefination reactions for the synthesis of highly functionalized cyclohexadienes
[Application]

Reactant for:
Preparation of a diol and carbamate chemistry library for common functional groups
Regioselective synthesis of alkenes via semihydrogenation and semihydrogenation-oxidation of dienes
Alkene addition of frustrated Lewis pairs
Olefination of N-sulfonyl imines for stereoselective synthesis of vinyl arenes
Wittig olefination of aldehydes for preparation of conjugated dienes
Tandem Michael addition / ylide olefination reactions for the synthesis of highly functionalized cyclohexadienes
Reaction of allyltriphenylphosphonium bromide and Garner's aldehyde in basic media provided β- hydroxy-1,3-dienes.
Methyl 3-(buta-1,3-dienyl)benzoate
1-(Buta-1,3-dienyl)-4-(trifluoromethyl)benzene
1-(Buta-1,3-dienyl)-2-chlorobenzene
1-Bromo-4-(buta-1,3-dienyl)benzene
Buta-1,3-dienylbenzene
[Preparation]

Allyltriphenylphosphonium bromide was synthesized from the reaction of triphenylphosphine and allyl bromide in dry toluene.
[reaction suitability]

reaction type: C-C Bond Formation
Spectrum DetailBack Directory
[Spectrum Detail]

Allyltriphenylphosphonium bromide(1560-54-9)MS
Allyltriphenylphosphonium bromide(1560-54-9)1HNMR
Allyltriphenylphosphonium bromide(1560-54-9)IR1
Allyltriphenylphosphonium bromide(1560-54-9)IR2
Allyltriphenylphosphonium bromide(1560-54-9)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Allyltriphenylphosphonium bromide, 99%(1560-54-9)
[Alfa Aesar]

Allyltriphenylphosphonium bromide, 99%(1560-54-9)
[Sigma Aldrich]

1560-54-9(sigmaaldrich)
[TCI AMERICA]

Allyltriphenylphosphonium Bromide,>98.0%(T)(1560-54-9)
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