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ChemicalBook--->CAS DataBase List--->24169-02-6

24169-02-6

24169-02-6 Structure

24169-02-6 Structure
IdentificationMore
[Name]

Econazole nitrate
[CAS]

24169-02-6
[Synonyms]

1-[2-[(4-chlorophenyl)methoxy]-2-(2,4-dichlorophenyl)-ethyl]-1h-imidazole mononitrate
1-[2-([4-CHLOROPHENYL]METHOXY)-2-(2,4-DICHLOROPHENYL)ETHYL]-1H-IMIDAZOLE NITRATE
1-[2-([4-CHLOROPHENYL]METHOXY)-2-(2,4-DICHLOROPHENYL)ETHYL]-1H-IMIDAZOLE NITRATE SALT
1-[2-[(4-CHLOROPHENYL)METHOXY]-2-(2,4-DICHLOROPHENYL)-ETHYL]IMIDAZOLE NITRATE
1-(2,4-dichloro-beta-((p-chlorobenzyl)oxy)phenethyl)imidazole nitrate
ECONAZOLE NITRATE
ECONAZOLE NITRATE SALT
ECONAZOL NITRATE
(RS)-1-[2,4-DICHLORO-BETA-(P-CHLOROBENZYLOXY)PHENETHYL]-IMIDAZOLE NITRATE
1-[2-[(4-chlorophenyl)methoxy]-2-(2,4-dichlorophenyl)ethyl]-1H-imidazolium nitrate
ECONAZOLE NITRATE 99%-101%
1H-Imidazole, 1-2-(4-chlorophenyl)methoxy-2-(2,4-dichlorophenyl)ethyl-, mononitrate
1-[2-(4-Chlorobenzyloxy)-2-(2,4-dichlorophenyl)ethyl]imidazole nitrate
Gyno-Pevaril
Imidazole, 1-[2,4-dichloro-β-[(p-chlorobenzyl)oxy]phenethyl]-, mononitrate (8CI)
Micofugal
Micogin
NSC 243115
Pargin
SQ 13050
[EINECS(EC#)]

246-053-5
[Molecular Formula]

C18H16Cl3N3O4
[MDL Number]

MFCD00058160
[Molecular Weight]

444.7
[MOL File]

24169-02-6.mol
Chemical PropertiesBack Directory
[Melting point ]

162°C
[storage temp. ]

Inert atmosphere,Room Temperature
[solubility ]

chloroform/methanol: soluble25mg/mL (choloroform:methanol (1:1))
[form ]

powder
[color ]

white to off-white
[Water Solubility ]

<0.1 g/100 mL at 19 ºC
[Merck ]

14,3502
[InChIKey]

DDXORDQKGIZAME-UHFFFAOYSA-N
[CAS DataBase Reference]

24169-02-6(CAS DataBase Reference)
[EPA Substance Registry System]

24169-02-6(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xn,Xi
[Risk Statements ]

R22:Harmful if swallowed.
R36/38:Irritating to eyes and skin .
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S36/37:Wear suitable protective clothing and gloves .
[WGK Germany ]

3
[RTECS ]

NI4450000
[HS Code ]

29332900
[Toxicity]

LD50 in mice, rats (mg/kg): 462.7, 667.7 orally (Thienpont)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

4-Chlorobenzyl chloride-->Nitric acid-->Sodium hydride
[Preparation Products]

Econazole
Hazard InformationBack Directory
[General Description]

White crystalline powder.
[Air & Water Reactions]

Insoluble in water.
[Fire Hazard]

Flash point data for this chemical are not available; however, ECONAZOLE NITRATE is probably combustible.
[Chemical Properties]

White to Off-White Solid
[Originator]

Pevaryl,Cilag Chemie,France,1976
[Uses]

Antifungal;Ergosterol synthesis inhibition
[Uses]

Azole antifungal
[Uses]

Econazole nitrate is an antifungal agent of the imidazole type used in topical and vaginal preparations to prevent growth of dermatophytes, yeast, and mold.
[Manufacturing Process]

A suspension of 10.3 parts of α-(2,4-dichlorophenyl)-imidazole-1-ethanol and 2.1 parts of sodium hydride in 50 parts of dry tetrahydrofuran is stirred andrefluxed for 2 hours. After this reaction-time, the evolution of hydrogen is ceased. Then there are added successively 60 parts dimethylformamide and 8 parts of p-chlorobenzylchloride and stirring and refluxing is continued for another two hours. The tetrahydrofuran is removed at atmospheric pressure. The dimethylformamide solution is poured onto water. The product, 1-[2,4- dichloro-β-(p-chlorobenzyloxy)phenethyl]imidazole, is extracted with benzene. The extract is washed with water, dried, filtered and evaporated in vacuo. From the residual oily free base, the nitrate salt is prepared in the usual manner in 2-propanol by treatment with concentrated nitric acid, yielding, after recrystallization of the crude solid salt from a mixture of 2-propanol, methanol and diisopropylether, 1-[2,4-dichloro-β-(pchlorobenzyloxy)phenethyl]imidazole nitrate; MP 162°C.
[Brand name]

Spectazole (Johnson & Johnson).
[Therapeutic Function]

Antifungal
[Biochem/physiol Actions]

Econazole interacts with 14-α demethylase, a cytochrome P-450 enzyme necessary to convert lanosterol to ergosterol. Inhibition of ergosterol results in increased cellular permeability causing leakage of cellular contents. Econazole may also inhibit endogenous respiration, interact with membrane phospholipids, inhibit the transformation of yeasts to mycelial forms, inhibit purine uptake, and impair triglyceride and phospholipid biosynthesis.
[storage]

Store at -20°C
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

1-(2,4-Dichloro-beta-((p-chlorobenzyl)oxy)phenethyl)imidazole nitrate(24169-02-6).msds
Questions And AnswerBack Directory
[Description]

Econazole nitrate is the nitrate salt form of Econazole. It belongs to imidazole-class antifungal medication sold in various places around the world including US, Canada, Western Europe, and Asia. It is usually manufactured into cream form for sale. Econazole nitrate is mainly used for the treatment of skin infections including athlete's foot, tinea, pityriasis versicolor, ringworm, and jock itch caused by fungi such as Trichophyton rubrum, Trichophyton tonsurans and Microsporum audouini. As an imidazole-class drug, Econazole nitrate takes effects through inhibiting the biosynthesis of ergosterol, a key component of fungal cell membrane, thus disrupting the normal permeability of fungal membrane. This causes leakage of essential cellular contents of fungi, further killing them.
[References]

http://www.rxlist.com/econazole-nitrate-cream-drug/clinical-pharmacology.htm
https://en.wikipedia.org/wiki/Econazole
http://www.pdr.net/drug-summary/Econazole-Nitrate-econazole-nitrate-731
Spectrum DetailBack Directory
[Spectrum Detail]

Econazole nitrate(24169-02-6)1HNMR
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

24169-02-6(sigmaaldrich)
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