| Identification | More | [Name]
(1S,2R)-2-Amino-1,2-diphenylethanol | [CAS]
23364-44-5 | [Synonyms]
(1R,2S)-(-)-2-AMINO-1,2-DIPHENYLETHANOL
(1R,2S)-2-AMINO-1,2-DIPHENYLETHANOL
(1R,2S)-(-)-DIPHENYL-2-AMINOETHANOL
(1R,2S)-(-)-ERYTHRO-2-AMINO 1,2-DIPHENYLETHANOL
(1S,2R)-(-)-2-AMINO-1,2-DIPHENYLETHANOL
(1S,2R)-(+)-2-AMINO-1,2-DIPHENYLETHANOL
(1S,2R)-2-AMINO-1,2-DIPHENYLETHANOL
(1S,2R)-(+)-DIPHENYL-2-AMINOETHANOL
BENZENEETHANOL, B-AMINO-A-PHENYL-, (AR,BS)-
BENZENEETHANOL, B-AMINO-A-PHENYL-, (AS,BR)-
(1S,2r)-(+)-2-Amino-1,2-Diphenylehanol
(1S,2R)-(+)-2-Amino-1,2-dipenylethanol
(1S,2R)-(+)-1,2-DIPHENYLHYDROXYETHYLAMINE
(1S,2R)-(+)-2-AMINO-1,2-DIPHENYLETHANOL 99% E.E. 98% ASSAY
(1S,2R)-(-)-1,2-DIPHENYLHYDROXYETHYLENEDIAMINE
(1S,2R)-(+)-2-Amino-1,2-diphenylethanol ,98% [ee：99%]
(1R,2S)-1,2-Diphenyl-1-amino-2-hydroxyethane | [EINECS(EC#)]
628-513-0 | [Molecular Formula]
C14H15NO | [MDL Number]
MFCD00074960 | [Molecular Weight]
213.27 | [MOL File]
23364-44-5.mol |
| Chemical Properties | Back Directory | [Appearance]
white to light yellow crystal powde | [Melting point ]
142-144 °C(lit.)
| [alpha ]
7 º (c=0.6, EtOH) | [Boiling point ]
374.3±37.0 °C(Predicted) | [density ]
1.148±0.06 g/cm3(Predicted) | [refractive index ]
7 ° (C=0.6, EtOH) | [storage temp. ]
2-8°C
| [solubility ]
very faint turbidity in Methanol | [form ]
Crystalline Powder | [pka]
11.70±0.45(Predicted) | [color ]
White to beige | [optical activity]
[α]25/D +7.0°, c = 0.6 in ethanol | [Detection Methods]
HPLC,NMR | [BRN ]
1212828 | [InChIKey]
GEJJWYZZKKKSEV-KGLIPLIRSA-N | [CAS DataBase Reference]
23364-44-5(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,Xn | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [F ]
9 | [HS Code ]
29221990 |
| Hazard Information | Back Directory | [Chemical Properties]
white to light yellow crystal powde | [Uses]
(1S,2R)-(+)-2-Amino-1,2-diphenylethanol can be used:
- To prepare vanadium(V) Schiff base complexes, which are used as catalysts in the oxidation of sulfides and olefins.
- To prepare chiral selectors, which are immobilized on aminated silica gel, applicable as chiral stationary phase in HPLC.
- To immobilize on the frame of α-zirconium phosphate to yield layered zirconium phosphonates, which are used in the heterogeneous catalysis.
- As a chiral auxiliary in the preparation of homopropargylic alcohols from aliphatic and aromatic aldehydes.
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| Questions And Answer | Back Directory | [Reaction]
- Ligand used to make chiral oxaborolidines for the enantioselective alkynylation of aldehydes
- Ligand used in organoindium reagents for asymmetric Barbier-type allylations
- Ligand used in organoindium reagents for asymmetric Barbier-type propargylations
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| Spectrum Detail | Back Directory | [Spectrum Detail]
(1S,2R)-2-Amino-1,2-diphenylethanol(23364-44-5)MS
(1S,2R)-2-Amino-1,2-diphenylethanol(23364-44-5)1HNMR
(1S,2R)-2-Amino-1,2-diphenylethanol(23364-44-5)13CNMR
(1S,2R)-2-Amino-1,2-diphenylethanol(23364-44-5)IR1
(1S,2R)-2-Amino-1,2-diphenylethanol(23364-44-5)IR2
(1S,2R)-2-Amino-1,2-diphenylethanol(23364-44-5)Raman
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