Identification | More | [Name]
2-(2-Bromoethyl)-1,3-dioxolane | [CAS]
18742-02-4 | [Synonyms]
2-(2-BROMOETHYL)-1,3-DIOXOLANE 3-BROMOPROPIONALDEHYDE ETHYLENE ACETAL 1,3-Dioxolane, 2-(2-bromoethyl)- 4-(cyclopropylcarbonyl)-2,2-dimethylbenzeneacetonitrile 2-(2-BROMOETHYL)-1,3-DIOXOLANE, STAB. 2-(2-Bromoethyl)-1,3-dioxolane, stabilized, 96% Bromoethyldioxolane 2-(2-Bromoethyl) 1,3-Dioxolane (Bedo) 3-bromopropanal 1,2-ethanediol acetal 1-BROMO-3,3-(ETHYLENEDIOXY)-PROPANE 2-(2-Bromoethyl)-1,3-dioxolane, 95%, stab. with silver [2-(1,3-Dioxolane-2-yl)ethyl] bromide 2-(1,3-Dioxolane-2-yl)ethyl bromide 3-Bromopropanal ethylene acetal | [EINECS(EC#)]
242-551-1 | [Molecular Formula]
C5H9BrO2 | [MDL Number]
MFCD00003216 | [Molecular Weight]
181.03 | [MOL File]
18742-02-4.mol |
Safety Data | Back Directory | [Hazard Codes ]
Xn,Xi | [Risk Statements ]
R22:Harmful if swallowed. R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S37/39:Wear suitable gloves and eye/face protection . | [RIDADR ]
UN 2810 6.1/PG 3
| [WGK Germany ]
2
| [F ]
8-9 | [HazardClass ]
6.1 | [PackingGroup ]
Ⅲ | [HS Code ]
29329990 |
Hazard Information | Back Directory | [Chemical Properties]
Clear colorless to yellow or brown liquid | [Uses]
Alkylating agent for amines,1 dithianes,2 and carboximides,3 and via the Grignard reagent, aldehydes.4 | [General Description]
Copper-catalyzed borylation of 2-(2-bromoethyl)-1,3-dioxolane with bis(pinacolato)diboron followed by treatment with potassium bifluoride affords the key organotrifluoroborate reagent. | [Purification Methods]
Dissolve it in pentane, wash with 5% aqueous NaHCO3, dry (Na2SO4), and evaporate. Distil the residue. [NMR: Büchi & Wüest J Org Chem 34 1122 1969, Kriesat & Gisvold J Pharm Sci 60 1250 1971, Beilstein 19/1 V 69.] |
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