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ChemicalBook--->CAS DataBase List--->18166-02-4

18166-02-4

18166-02-4 Structure

18166-02-4 Structure
IdentificationMore
[Name]

(Trimethylsilyl)methylamine
[CAS]

18166-02-4
[Synonyms]

2-AMINOMETHYLTRIMETHYLSILANE
(AMINOMETHYL)TRIMETHYLSILANE
(TRIMETHYLSILYL)METHYLAMINE
Methylamine, 1-(trimethylsilyl)-,
1-(trimethylsilyl)methylamine
Aminomethyltrimethylsilane**CUSTOMSYNTHESISPLEASEASK**
(trimethylsilyl)methanamine
AMTMS
Trimethylsilylmethaneamine
[EINECS(EC#)]

242-049-2
[Molecular Formula]

C4H13NSi
[MDL Number]

MFCD00042931
[Molecular Weight]

103.24
[MOL File]

18166-02-4.mol
Chemical PropertiesBack Directory
[Melting point ]

<0°C
[Boiling point ]

92-94 °C(lit.)
[density ]

0.771 g/mL at 20 °C(lit.)
[refractive index ]

n20/D 1.416
[Fp ]

9°C
[storage temp. ]

Keep in dark place,Inert atmosphere,Room temperature
[form ]

liquid
[pka]

10.89±0.10(Predicted)
[Specific Gravity]

0.7697
[Hydrolytic Sensitivity]

4: no reaction with water under neutral conditions
[BRN ]

1731488
[CAS DataBase Reference]

18166-02-4(CAS DataBase Reference)
[NIST Chemistry Reference]

Trimethylsilylmethylamine(18166-02-4)
Safety DataBack Directory
[Hazard Codes ]

F,C
[Risk Statements ]

R11:Highly Flammable.
R34:Causes burns.
R37:Irritating to the respiratory system.
[Safety Statements ]

S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 2733 3/PG 2
[WGK Germany ]

3
[F ]

3-10
[TSCA ]

No
[HazardClass ]

3.1
[PackingGroup ]

II
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

18166-02-4(sigmaaldrich)
Hazard InformationBack Directory
[Purification Methods]

A possible contaminant is hexamethyldisiloxane. It should have two 1H NMR signals in CDCl3; if not, dissolve it in *C6H6, shake it with 15% aqueous KOH, separate, dry (Na2SO4), filter, evaporate and distil it using a still of ca 10 theoretical plates. The water azeotrope has b 83o/735mm; hence it is important to dry the extract well. The hydrochloride has m 198-199o (from MeOH or Me2CO). [Noll et al. J Am Chem Soc 73 3867 1951, Beilstein 4 IV 3878.]
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