| Identification | More | [Name]
HEXAFLUOROANTIMONIC ACID | [CAS]
16950-06-4 | [Synonyms]
FLUOROANTIMONIC ACID
HEXAFLUOROANTIMONIC ACID
HYDROGEN HEXAFLUOROANTIMONATE(V)
hydrogen,(oc-6-11)-antimonate(1-hexafluoro-
hexafluoroantimonyic acid
FLUOROANTIMONIC ACID, TRIPLE-DISTILLED
Hexafluoroantimonicacid6H2O
Hydrogenhexafluoroantimonate(V),65-70%aqueoussolution
Hexafluoroantimonic acid hexahydrate 98%
Hexafluoroantimonicacidhexahydrate98%
HEXAFLUOROANTIMONIC ACID, ANHYDROUS
Hydrogen hexafluoroantimonate(V), ≈65% aq. soln. | [EINECS(EC#)]
241-023-8 | [Molecular Formula]
F6HSb | [MDL Number]
MFCD00011327 | [Molecular Weight]
236.76 | [MOL File]
16950-06-4.mol |
| Hazard Information | Back Directory | [Chemical Properties]
superacid; moisture sensitive [KIR78] [ALD94] | [Uses]
Hydrogen hexafluoroantimonate(V) is an excellent medium for the preparation of alkylidene oxonium salts. | [Preparation]
Fluoroantimonic acid is produced by reacting hydrogen fluoride (HF) with antimony pentafluoride (SbF5).
SbF5+HF→SbF6+HF | [General Description]
HF/SbF5 may be synthesized by mixing hydrogen fluoride and antimony fluoride.1 Fluoroantimonic acid (HF/SbF5), is a combination of SbF5 and HF. It is the known strongest liquid superacid. | [References]
[1] J. OLAH G. O. Synthetic Method and Reactions; V. 1 Fluoroantimonic Acid, a Convenient Superacid Catalyst for the Improved Isomerization of Tetrahydrodicyclopentadiene to Adamantane[J]. Synthesis-Stuttgart, 2002, 106 1: 488-488. DOI:10.1055/S-1973-22239.
[2] ZENGSHE LIU Atanu B. Fluoroantimonic acid hexahydrate (HSbF6·6H2O) catalysis: The ring-opening polymerization of epoxidized soybean oil[J]. Applied Catalysis A: General, 2013, 453: Pages 370-375. DOI:10.1016/j.apcata.2012.12.028. |
| Safety Data | Back Directory | [Hazard Codes ]
Xn,N,C | [Risk Statements ]
R20/22:Harmful by inhalation and if swallowed .
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment . | [Safety Statements ]
S61:Avoid release to the environment. Refer to special instructions safety data sheet . | [RIDADR ]
UN 2922 8/PG 2
| [WGK Germany ]
2
| [Hazard Note ]
Corrosive | [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
II |
|
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