| Identification | More | [Name]
Bromoxynil | [CAS]
1689-84-5 | [Synonyms]
2，6-Dibromo-4-cyanophenol
2-methylthio-4-ethylamino-6-isopropylamino-1,3,5-triazine
3,5-DIBROMO-4-HYDROXYBENZONITRILE
3,5-DIBROMO-4-HYDROXYPHENYL CYANIDE
4-HYDROXY-3,5-DIBROMOBENZONITRILE
BROMINAL
BROMINAL(R)
BROMINIL(R)
BROMOTRIL
BROMOX
BROMOXAN
BROMOXYNIL
BUCTRIL
BUCTRIL(R)
BUTTPARK 84\02-48
EMBLEM
KALEIS
MB 10064
N-ethyl-N'-(1-methylethyl)-6-methylthio-1,3,5-triazine-2,4-diamine
TRIONYL | [EINECS(EC#)]
216-882-7 | [Molecular Formula]
C7H3Br2NO | [MDL Number]
MFCD00002153 | [Molecular Weight]
276.91 | [MOL File]
1689-84-5.mol |
| Safety Data | Back Directory | [Hazard Codes ]
T+,N | [Risk Statements ]
R25:Toxic if swallowed.
R26:Very Toxic by inhalation.
R43:May cause sensitization by skin contact.
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R63:Possible risk of harm to the unborn child. | [Safety Statements ]
S27/28:After contact with skin, take off immediately all contaminated clothing and wash imediately with plenty of.... (to be specified by the manufacturer) .
S36/37:Wear suitable protective clothing and gloves .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S63:In case of accident by inhalation, remove casualty to fresh air and keep at rest. | [RIDADR ]
UN 2811 6.1/PG 3
| [WGK Germany ]
3
| [RTECS ]
DI3150000
| [HazardClass ]
6.1(b) | [PackingGroup ]
III | [Hazardous Substances Data]
1689-84-5(Hazardous Substances Data) | [Toxicity]
LD50 orally in mice: 111 mg/kg (Carpenter, 1964) |
| Hazard Information | Back Directory | [General Description]
Colorless solid. Melting point 382-384°F (194-195°C). Sublimes at 275°F (135°C) under pressure of 0.15 mm Hg. Used as a herbicide. | [Reactivity Profile]
BROMOXYNIL is a weak acid. | [Hazard]
Toxic. | [Potential Exposure]
Bromoxynil is a hydroxybenzonitrile
herbicide used for postemergent control of broadleaf
weeds; on alfalfa, garlic, corn, sorghum, flax, cereals,
turf and on pasture and rangelands. A United States
Environmental Protection Agency RUP. | [First aid]
Move victim to fresh air. Call 911 or emergency
medical service. Give artificial respiration if victim is not
breathing. Do not use mouth-to-mouth method if victim
ingested or inhaled the substance; give artificial respiration
with the aid of a pocket mask equipped with a one-way
valve or other proper respiratory medical device.
Administer oxygen if breathing is difficult. Remove and
isolate contaminated clothing and shoes. In case of contact
with substance, immediately flush skin or eyes with running
water for at least 20 minutes. For minor skin contact,
avoid spreading material on unaffected skin. Keep victim
warm and quiet. Effects of exposure (inhalation, ingestion
or skin contact) to substance may be delayed. Ensure that
medical personnel are aware of the material(s) involved
and take precautions to protect themselves. | [Shipping]
UN2588 Pesticides, solid, toxic, Hazard Class:
6.1; Labels: 6.1—Poisonous materials, Technical Name
Required. | [Incompatibilities]
A weak acid; keep away from bases and
alkalies. React with boranes, alkalies, aliphatic amines,
amides, nitric acid, sulfuric acid. Keep away from oxidizers
(chlorates, nitrates, peroxides, permanganates, perchlorates,
chlorine, bromine, fluorine, etc.) and strong acids. | [Chemical Properties]
Bromoxynil is a colorless to white crystalline
solid or tan powder. Odorless (pure). | [Chemical Properties]
Off-white to salmon crystalline powder | [Waste Disposal]
Do not discharge into drains
or sewers. Dispose of waste material as hazardous waste
using a licensed disposal contractor to an approved landfill.
Incineration with effluent gas scrubbing is recommended.
Consult with environmental regulatory agencies for guidance
on acceptable disposal practices. If allowed,
Incineration with effluent gas scrubbing is recommended.
Containers must be disposed of properly by following
package label directions or by contacting your local or federal
environmental control agency, or by contacting your
regional EPA office. | [Uses]
Bromoxynil is a nitrile herbicide. Bromoxynil is effective in post-emergent control of broad leaf weeds in cereal, corn, sorghum, onions, flax, mint, turf, and on non-cropland. | [Uses]
Selective contact foliage-applied herbicide used to control many broad-leaved weeds
in cereals. | [Definition]
ChEBI: A dibromobenzene that is 2,6-dibromophenol substituted by a cyano group at position 4. | [Agricultural Uses]
Herbicide: A U.S. EPA restricted Use Pesticide (RUP). For
post-emergent control of broadleaf weeds. Used on alfalfa,
garlic, corn, sorghum, flax, cereals, turf and on pasture and
rangelands. | [Trade name]
BRIOTRIL®; BRUCIL®; BRITTOX®;
BROMINAL®; BROMINEX®; BROMINAL®;
BROMINAL ME-4®; BROMINIL®; BROMILIL
PLUS®; Bromox 2E; BROMOTRIL®; BROMOXYNIL
NITRILE HERBICIDE®; BRONATE®; BROXYNIL®;
BUCTRIL® Bromoxynil; BUCTRIL® GEL HERBICIDE
(octanoate); BUCTRIL® 4EC GEL (mixture of bromoxynil
octanoate + bromoxynil heptanoate); BUCTRIL
INDUSTRIAL®; CHIPCO BUCTRIL®; CHIPCO
CRAB-KLEEN®; FLAGON®, 400 EC; HOBANE®;
LABUCTRIL®; LITAROL®; M&B 10064®; MB
10064®; MB 10731® (octanoate); M&B 10731®; ME4
BROMINAL®; MERIT®; MEXTROL-BIOX®; MOXY
2E®; NCR CE EE DOV7® (octanoate); NU-LAWN
WEEDER®; OXYTRIL M®; PARDNER®; SABRE®;
TORCH® | [Environmental Fate]
Biological. Duke et al. (1991) reported that bromoxynil can be converted to 3,5-
dibromo-4-hydroxybenzoic acid by a microbial nitrolase.
Soil. In soils, Klebsiella pneumoniae metabolized bromoxynil to 3,5-dibromo-4-
hydroxybenzoic acid and ammonia (McBride et al., 1986). In soil, bromoxynil undergoes
nitrile and then amide hydrolysis yielding 3,5-dibromo-4-hydroxybenzoic acid and
Nitrification in soils is inhibited when bromacil is applied at a concentration of <50
ppm (Debona and Audus, 1970). The half-life in soil is approximately 10 days (Hartley
and Kidd, 1987).
Plant. In plants, the cyano group is hydrolyzed to an amido group which is subsequently
oxidized to a carboxylic acid. Hydrolyzes to hydroxybenzoic acid (Hartley and Kidd,
1987). In plants, bromoxynil may hydrolyze to a benzoic acid (Humburg et al., 1989).
Bromoxynil-resistant cotton was recently developed by inserting a bxn gene cloned from
the soil bacterium Klebsiella ozaenae. This gene, which encodes a specific nitrolase,
converted bromoxynil to its primary metabolite 3,5-dibromo-4-hydroxybenzoic acid
(Stalker et al., 1988).
Chemical/Physical. Emits toxic fumes of nitrogen oxides and bromine when heated
to decomposition (Sax and Lewis, 1987). Reacts with bases forming water-soluble salts
(Worthing and Hance, 1991). Bromacil is stable to UV light (Hartley and Kidd, 19 |
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