| Identification | More | [Name]
(OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE) | [CAS]
166330-10-5 | [Synonyms]
2,2'-BIS(DIPHENYLPHOSPHINO)DIPHENYL ETHER
BIS(2-DIPHENYLPHOSPHINOPHENYL)ETHER
DPEPHOS
(OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE)
Bisdiphenylphosphinophenylether
Bis(2-diphenylphosphinophenyl)ether, DPEphos
Bis(2-diphenylphosphinophenyl)ether,98%DPEphos
Bis(2-diphenylphosphino)phenylü ether, 98% | [EINECS(EC#)]
678-206-0 | [Molecular Formula]
C36H28OP2 | [MDL Number]
MFCD00233863 | [Molecular Weight]
538.55 | [MOL File]
166330-10-5.mol |
| Chemical Properties | Back Directory | [Appearance]
White to off-white crystalline powder or crystals | [Melting point ]
184-187 °C (lit.) | [Boiling point ]
608.2±40.0 °C(Predicted) | [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [solubility ]
Chloroform (Slightly), Methanol (Slightly) | [form ]
Crystalline Powder or Crystals | [color ]
White to off-white | [BRN ]
7729718 | [InChIKey]
RYXZOQOZERSHHQ-UHFFFAOYSA-N | [CAS DataBase Reference]
166330-10-5(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R22:Harmful if swallowed. | [Safety Statements ]
S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [WGK Germany ]
3
| [TSCA ]
No | [HS Code ]
29319090 |
| Hazard Information | Back Directory | [Chemical Properties]
White to off-white crystalline powder or crystals | [Uses]
suzuki reaction | [General Description]
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information. | [reaction suitability]
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: Heck Reaction
reagent type: ligand
reaction type: Hydroaminations
reagent type: ligand
reaction type: Negishi Coupling
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling |
| Questions And Answer | Back Directory | [Reaction]
- Useful as a ligand in the Pd-catalyzed formation of diaryl amines.
- Has been recently applied to the C3 benzylation of indoles.
- Has been recently applied to the monoallylation of ammonia.
- Ligand used in the palladium-catalyzed, aerobic oxidation coupling of acyl chlorides with arylboronic acids.
- Ligand used in carbonylation of aryl iodides.
- Ligand used in the direct C-H arylation of benzothiodiazoles.
- Ligand used in stereo-retentive azacyclization of propargylic carbonates.
- Ligand used in palladium catalyzed benzyne trimerization.
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