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ChemicalBook--->CAS DataBase List--->14126-37-5

14126-37-5

14126-37-5 Structure

14126-37-5 Structure
IdentificationMore
[Name]

BIS(TRIPHENYLPHOSPHINE)NICKEL(II) BROMIDE
[CAS]

14126-37-5
[Synonyms]

BIS(TRIPHENYLPHOSPHINE)NICKEL(II) BROMIDE
DIBROMOBIS(TRIPHENYLPHOSPHINE)NICKEL(II)
bis(triphenylphosphine)nickel(II) dibromide
DIBROMOBIS(TRIPHENYLPHOSPHINE)NICKEL
Bis(triphenylphosphine)nickel(II)bromide,99%
Nickel(II)bromidebis(triphenylphosphine)
BIS(TRIPHENYLPHOSPHINE)NICKELBROMIDE
Nickel,dibromobis[triphenylphosphine]-
Bis-(triphenylphosphino)-nickel bromide
[Molecular Formula]

C36H30Br2NiP2
[MDL Number]

MFCD00015865
[Molecular Weight]

743.07
[MOL File]

14126-37-5.mol
Chemical PropertiesBack Directory
[Appearance]

DARK GREEN CRYSTALLINE POWDER OR CRYSTALS
[Melting point ]

219-223 °C (lit.)
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

crystal
[color ]

green
[Exposure limits]

NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
[InChI]

InChI=1S/2C18H15P.2BrH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
[InChIKey]

QEKXARSPUFVXIX-UHFFFAOYSA-L
[SMILES]

P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.[Ni](Br)Br
[CAS DataBase Reference]

14126-37-5(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S36/37:Wear suitable protective clothing and gloves .
[RIDADR ]

UN 1759 8/PG 2
[WGK Germany ]

3
[HazardClass ]

6.1(b)
[PackingGroup ]

III
[HS Code ]

29319090
Hazard InformationBack Directory
[Chemical Properties]

DARK GREEN CRYSTALLINE POWDER OR CRYSTALS
[Uses]

Catalysts for the cross-coupling reactions, C-X bond reduction, homocoupling of Csp2 halides, displacement of aryl halides, and oligomerization of dienes
[Uses]

As a polymerization catalyst
Spectrum DetailBack Directory
[Spectrum Detail]

BIS(TRIPHENYLPHOSPHINE)NICKEL(II) BROMIDE(14126-37-5)IR1
BIS(TRIPHENYLPHOSPHINE)NICKEL(II) BROMIDE(14126-37-5)IR2
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Bis(triphenylphosphine)nickel(II)bromide, 99%(14126-37-5)
[Alfa Aesar]

Dibromobis(triphenylphosphine)nickel(II), 99%(14126-37-5)
[Sigma Aldrich]

14126-37-5(sigmaaldrich)
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