| Identification | More | [Name]
Borane-methyl sulfide complex | [CAS]
13292-87-0 | [Synonyms]
BMS
BORANE-DIMETHYLSULFIDE
BORANE-DIMETHYLSULFIDE COMPLEX
BORANE DIMETHYL SULPHIDE COMPLEX
BORANE-METHYL SULFIDE COMPLEX
DIMETHYL SULFIDE BORANE
DMSB
METHYL SULFIDE BORANE
Borane, compd. with dimethylsulfide
borane,compd.withdimethylsulfide
Boron, trihydro[thiobis[methane]]-, (T-4)-
Boron,trihydro[thiobis[methane]]-,(T-4)-
dimethylsulfide-borane(3)(1:1)
dimethylsulfideborane,dmsb
dimethylsulfideborane,dmsb,in
dimethylsulfideborane,dmsb,intetrahydrofuran
Methyl sulfide, compd. with borane (1:1)
methylsulfide,compd.withborane(1:1)
BMS~Borane-methyl sulphide~Dimethyl sulphide borane
dimethyl sulphide--borane | [EINECS(EC#)]
236-313-6 | [Molecular Formula]
C2H9BS | [MDL Number]
MFCD00013189 | [Molecular Weight]
75.97 | [MOL File]
13292-87-0.mol |
| Chemical Properties | Back Directory | [Appearance]
CLEAR COLOURLESS SOLUTION | [Melting point ]
-40--37°C | [Boiling point ]
~34 °C
| [density ]
1.287 g/mL at 25 °C
| [refractive index ]
1.4570 | [Fp ]
65 °F
| [storage temp. ]
2-8°C
| [solubility ]
Miscible with ethyl ether, tetrahydrofurane, dichloromethane, benzene, xylene, hexane, diglyme, dimethyl ether, ethyl acetate, toluene, methylene chloride and other aprotic solvents. | [form ]
Solution | [color ]
Colorless to pale yellow | [Specific Gravity]
0.801 | [Water Solubility ]
reacts | [Sensitive ]
Air & Moisture Sensitive | [BRN ]
3663489 | [InChIKey]
RMHDLBZYPISZOI-UHFFFAOYSA-N | [CAS DataBase Reference]
13292-87-0(CAS DataBase Reference) | [NIST Chemistry Reference]
Borane-methyl sulfide complex(13292-87-0) | [EPA Substance Registry System]
13292-87-0(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
F+,Xn,F,Xi | [Risk Statements ]
R12:Extremely Flammable.
R14/15:Reacts violently with water, liberating extremely flammable gases .
R19:May form explosive peroxides.
R20/22:Harmful by inhalation and if swallowed .
R37/38:Irritating to respiratory system and skin .
R41:Risk of serious damage to eyes.
R67:Vapors may cause drowsiness and dizziness.
R65:Harmful: May cause lung damage if swallowed.
R63:Possible risk of harm to the unborn child.
R48/20:Harmful: danger of serious damage to health by prolonged exposure through inhalation .
R38:Irritating to the skin.
R11:Highly Flammable.
R22:Harmful if swallowed.
R14:Reacts violently with water.
R40:Limited evidence of a carcinogenic effect.
R36:Irritating to the eyes.
R21:Harmful in contact with skin. | [Safety Statements ]
S36/37:Wear suitable protective clothing and gloves .
S62:If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label .
S36/39:Wear suitable protective clothing and eye/face protection .
S33:Take precautionary measures against static discharges .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S16:Keep away from sources of ignition-No smoking .
S36:Wear suitable protective clothing .
S24/25:Avoid contact with skin and eyes .
S7/8:Keep container tightly closed and dry . | [RIDADR ]
UN 3399 4.3/PG 1
| [WGK Germany ]
3
| [RTECS ]
PV5080000
| [F ]
10-13-23 | [TSCA ]
Yes | [HazardClass ]
4.3 | [PackingGroup ]
II | [HS Code ]
29309090 |
| Hazard Information | Back Directory | [Chemical Properties]
clear colorless to light yellow solution | [Uses]
Borane-dimethyl sulfide complex is used for hydroborations and reductions. Used with a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones. CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to 1,3-diols. Highly enantioselective reduction of ketones catalyzed by C3-symmetric tripodal hydroxyamides. | [General Description]
Borane dimethyl sulfide complex (BMS) acts as a highly efficient and selective reducing agent in the presence of catalytic sodium tetrahydroborate for α-hydroxy esters. Asymmetric borane reduction of a variety of prochiral ketones with BMS using spiroborate esters as catalyst has been reported. |
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