| Identification | More | [Name]
2-Methyl-4-methoxybenzenamine | [CAS]
102-50-1 | [Synonyms]
1-AMINO-4-METHOXY-2-METHYLBENZENE
2-METHYL-4-METHOXYBENZENAMINE
2-METHYL-P-ANISIDINE
3-METHYL-4-AMINOANISOLE
4-METHOXY-2-METHYLANILINE
4-METHOXY-O-TOLUIDINE
6-AMINO-3-METHOXYTOLUENE
AKOS 91136
M-CRESIDINE
2-methyl-p-anisidin
4-methoxy-2-methyl-benzenamin
4-Methoxy-2-methylbenzenamine
NCI-C02993
p-Anisidine, 2-methyl-
2-Methyl-4-Methoxybenzenamine 2-Amino-5-Methoxytoluene
5-methoxy-2-methylbenzenamine
meta-cresidine
2-Methyl-p-anisidine(NH2=1)
4-Methoxy-2-methylaniline (m-Cresidine)
2-Amino-5-Methoxytoluene | [EINECS(EC#)]
203-036-7 | [Molecular Formula]
C8H11NO | [MDL Number]
MFCD00007735 | [Molecular Weight]
137.18 | [MOL File]
102-50-1.mol |
| Chemical Properties | Back Directory | [Appearance]
brick red crystals or liquid | [Melting point ]
13-14 °C(lit.)
| [Boiling point ]
248-249 °C(lit.)
| [density ]
1.065 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.565(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
Refrigerator | [solubility ]
Acetonitrile (Slightly), Chloroform (Slightly), DMSO, Methanol (Slightly) | [form ]
Oil | [pka]
5.05±0.10(Predicted) | [color ]
Light Brown to Very Dark Red | [Stability:]
Stable. May be light or air-sensitive. Combustible. Incompatible with acids, strong oxidizing agents. | [Water Solubility ]
insoluble, <0.1 g/100 mL at 21.5 ºC | [Detection Methods]
HPLC,NMR | [BRN ]
774727 | [InChIKey]
CDGNLUSBENXDGG-UHFFFAOYSA-N | [CAS DataBase Reference]
102-50-1(CAS DataBase Reference) | [IARC]
3 (Vol. 27, Sup 7) 1987 | [NIST Chemistry Reference]
Benzenamine, 4-methoxy-2-methyl-(102-50-1) | [EPA Substance Registry System]
102-50-1(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,Xn,T | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R40:Limited evidence of a carcinogenic effect.
R45:May cause cancer. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S53:Avoid exposure-obtain special instruction before use .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
2810 | [WGK Germany ]
3
| [RTECS ]
BZ6730000
| [TSCA ]
Yes | [HazardClass ]
6.1 | [PackingGroup ]
III | [HS Code ]
29222990 | [Safety Profile]
Suspected carcinogen
with experimental carcinogenic and
tumorigenic data. Mutation data reported.
When heated to decomposition it emits
toxic fumes of NOx. | [Hazardous Substances Data]
102-50-1(Hazardous Substances Data) |
| Hazard Information | Back Directory | [General Description]
Crystals or brick red liquid. | [Reactivity Profile]
M-CRESIDINE(102-50-1) neutralizes acids in weakly exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. May generate hydrogen, a flammable gas, in combination with strong reducing agents such as hydrides. Reacts with oxidizing agents . | [Air & Water Reactions]
Sensitive to prolonged exposure to air and light. Insoluble in water. | [Health Hazard]
ACUTE/CHRONIC HAZARDS: This compound is a local irritant. When heated to decomposition it emits toxic fumes of NOx. This compound is an experimental animal carcinogen. | [Fire Hazard]
This chemical is probably combustible. | [Chemical Properties]
brick red crystals or liquid | [Uses]
4-Methoxy-2-methylaniline is a reagent used in organic synthesis of more complex compounds that have a more specific function. For example, enzyme inhibitors. | [Definition]
ChEBI: Meta-Cresidine is a member of methoxybenzenes. |
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