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ChemicalBook--->CAS DataBase List--->1016-58-6

1016-58-6

1016-58-6 Structure

1016-58-6 Structure
IdentificationMore
[Name]

4,5-DIMETHOXY-2-NITROBENZYL ALCOHOL
[CAS]

1016-58-6
[Synonyms]

4,5-DIMETHOXY-2-NITROBENZYL ALCOHOL
6-NITROVERATRYL ALCOHOL
LABOTEST-BB LT00847721
RARECHEM AL BD 0187
TIMTEC-BB SBB009964
4,5-Dimethoxy-2-nitrobenzyl alcohol 98%
6-NITROVERATRYL ALCOHOL 98+%
4,5-Dimethoxy-2-nitrobenzyl alcohol, 98+%
2-Nitro-4,5-dimethoxybenzenemethanol
2-Nitro-4,5-dimethoxybenzyl alcohol
4,5-Dimethoxy-2-nitrobenzenemethanol
(4,5-Dimethoxy-2-nitro-phenyl)-methanol
[EINECS(EC#)]

213-806-4
[Molecular Formula]

C9H11NO5
[MDL Number]

MFCD00014701
[Molecular Weight]

213.19
[MOL File]

1016-58-6.mol
Chemical PropertiesBack Directory
[Appearance]

white to light yellow crystal powde
[Melting point ]

145-148 °C (lit.)
[Boiling point ]

383.9±37.0 °C(Predicted)
[density ]

1.307±0.06 g/cm3(Predicted)
[storage temp. ]

Keep in dark place,Sealed in dry,Room Temperature
[form ]

powder to crystal
[pka]

13.59±0.10(Predicted)
[color ]

White to Yellow to Green
[Water Solubility ]

Soluble in water.
[Sensitive ]

Light Sensitive
[λmax]

400nm(CH3CN)(lit.)
[BRN ]

1880093
[CAS DataBase Reference]

1016-58-6(CAS DataBase Reference)
Safety DataBack Directory
[Safety Statements ]

S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

3
[F ]

8
[HazardClass ]

IRRITANT
[HS Code ]

29094990
Hazard InformationBack Directory
[Chemical Properties]

white to light yellow crystal powde
[Uses]

4,5-Dimethoxy-2-nitrobenzyl alcohol (6-nitroveratryl alcohol) is suitable reagent used in the synthesis of 4,5-dimethoxy-2-nitrobenzyl methacrylate, a photolabile monomer and 2-(4-((4-(4,5-dimethoxy-2-nitrobenzyloxy)phenyl)cyclohexylidene)methyl)phenoxy)-N,N-dimethylethanamine, a caged cyclofen-OH ligand.

It may be used in the synthesis of the following:
  • 1-[[(chlorocarbonyl)oxy]methyl]-4,5-dimethoxy-2-nitrobenzene
  • bis(4,5-dimethoxy-2-nitrophenyl)ethylene glycol, a photolabile protecting group
  • optically-sensitive monomer
  • nitroveratryl (NV) protected α-hydroxyacetic acid (αG) (NV-αG-OH), required in the preparation of nitroveratryl (NV) protected cyanomethyl (CM) ester of α-hydroxyacetic acid (αG) (NV-αG-CM)
  • 4,5-dimethoxy-2-nitrobenzyl p-nitro-phenylcarbonate
  • 6-nitroveratryloxycarbonyl chloride (NVOCCl), a reagent used in the protection of amino function in amino sugars
[Uses]

4,5-Dimethoxy-2-nitrobenzyl alcohol, is used as Reagent for the protection of alcohols, etc., as ethers which can be cleaved by photolysis involving intramolecular rearrangement to derivatives of o-nitrosobenzaldehyde, which are readily cleaved by hydrolysis. It is also used as photochemical protecting groups in organic synthesis. It is also used as a pharmaceutical intermediate.
[General Description]

4,5-Dimethoxy-2-nitrobenzyl alcohol (6-Nitroveratryl Alcohol) is 2-nitrobenzyl alcohol derivative. It has been reported to be one of the oxidation products of veratryl (3,4-dimethoxybenzyl) alcohol by lignin peroxidase (isolated from Phanerochaete chrysosporium).
Spectrum DetailBack Directory
[Spectrum Detail]

4,5-DIMETHOXY-2-NITROBENZYL ALCOHOL(1016-58-6)IR
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

4,5-Dimethoxy-2-nitrobenzyl alcohol, 98%(1016-58-6)
[Sigma Aldrich]

1016-58-6(sigmaaldrich)
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