| Identification | More | [Name]
trans-1,3-Dichloropropene | [CAS]
10061-02-6 | [Synonyms]
1,3-DICHLORO-1-PROPENE
1,3-dichloro-2-propene
1,3-DICHLOROPENE
1,3-DICHLOROPROPENE
1,3-DICHLOROPROPENE-1
1,3-DICHLOROPROPYLENE
3-CHLOROALLYL CHLORIDE
A-CHLOROALLYL CHLORIDE
D-D
DICHLOROPROPYLENE
(e)-1,3-dichloroprop-1-ene
NEMATOX
TELONE
TELONE(R)
TRANS-1,3-DICHLORO-1-PROPENE
TRANS-1,3-DICHLOROPENE
TRANS-1,3-DICHLOROPROPENE
TRANS-1,3-DICHLOROPROPYLENE
(e)-1,3-dichloro-1-propene
(E)-1,3-Dichloropropene | [EINECS(EC#)]
208-826-5 | [Molecular Formula]
C3H4Cl2 | [MDL Number]
MFCD00000985 | [Molecular Weight]
110.97 | [MOL File]
10061-02-6.mol |
| Chemical Properties | Back Directory | [Appearance]
1,3-Dichloropropene is a colorless to strawcolored liquid. Sharp, sweet, irritating, chloroform-like odor. | [Boiling point ]
97-112 °C(lit.)
| [density ]
1.198 g/mL at 25 °C(lit.)
| [vapor pressure ]
79.1 at 50 °C, 523.5 at 100 °C (Wilding et al., 2002) | [refractive index ]
n20/D 1.472(lit.)
| [Fp ]
78 °F
| [storage temp. ]
0-6°C
| [solubility ]
Miscible with acetone, benzene, carbon tetrachloride, heptane, methanol (Worthing and Hance,
1991), methylene chloride, chloroform, trichloroethylene, and 1,1,2,2-tetrachloroethane. | [form ]
neat | [color ]
Colorless to Light yellow to Light orange | [Specific Gravity]
1.217 | [Stability:]
Stable. Flammable. Incompatible with strong oxidizing agents, aluminium, aluminium alloys, some metal salts and halogens. May be light sensitive. | [Water Solubility ]
2.8g/L(20 ºC) | [Merck ]
3075 | [Henry's Law Constant]
1.3 x 10-3 atm?m3/mol (Pankow and Rosen, 1988)
0.793 x 10-3 atm?m3/mol at 20 °C, 1.87 at 40 °C (static headspace-GC, Kim et al., 2003) | [Exposure limits]
ACGIH TLV: TWA 1 ppm for cis and trans isomers (adopted). | [CAS DataBase Reference]
10061-02-6(CAS DataBase Reference) | [NIST Chemistry Reference]
1-Propene, 1,3-dichloro-, (E)-(10061-02-6) | [EPA Substance Registry System]
10061-02-6(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
T,N,Xn,F | [Risk Statements ]
R10:Flammable.
R20/21:Harmful by inhalation and in contact with skin .
R25:Toxic if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin .
R43:May cause sensitization by skin contact.
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R40:Limited evidence of a carcinogenic effect.
R22:Harmful if swallowed.
R39/23/24/25:Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed .
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R11:Highly Flammable. | [Safety Statements ]
S36/37:Wear suitable protective clothing and gloves .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S16:Keep away from sources of ignition-No smoking .
S7:Keep container tightly closed . | [RIDADR ]
UN 1992 3/PG 3
| [WGK Germany ]
3
| [RTECS ]
UC8310000
| [HazardClass ]
3.2 | [PackingGroup ]
III | [HS Code ]
29032990 | [Hazardous Substances Data]
10061-02-6(Hazardous Substances Data) | [Toxicity]
LC50 (96-hour) for bluegill sunfish 7.1 mg/L and rainbow trout 7.1 mg/L (Worthing
and Hance, 1991); acute oral LD50 of the isomeric mixture for male and female rats
713 and 470 mg/kg, respectively (Verschueren, 1983). |
| Hazard Information | Back Directory | [General Description]
A clear colorless liquid with chloroform odor . Flash point 95°. Density 1.225 g/cm3 and insoluble in water. Hence sinks in water. A strong irritant. Used as a soil fumigant. | [Reactivity Profile]
TRANS-1,3-DICHLOROPROPENE(10061-02-6) reacts with aluminum, aluminum alloys, with other active metals and with some metal salts and halogens. Can react vigorously with oxidizing materials. . | [Air & Water Reactions]
Highly flammable. Insoluble in water. | [Potential Exposure]
Used as a soil fumigant prior to
planting crops, such as cotton, sugar beet, potatoes; used in
combinations with dichloropropanes as a soil fumigant.
Workers engaged in manufacture, formulation and application of this soil fumigant and nematocide. | [Fire Hazard]
Flash point data for this chemical are not available, however literature indicates that this material is flammable. | [First aid]
If this chemical gets into the eyes, remove any
contact lenses at once and irrigate immediately for at least
15 minutes, occasionally lifting upper and lower lids.
Seek medical attention immediately. If this chemical
contacts the skin, remove contaminated clothing and wash
immediately with soap and water. Seek medical attention
immediately. If this chemical has been inhaled, remove
from exposure, begin rescue breathing (using universal
precautions, including resuscitation mask) if breathing has
stopped and CPR if heart action has stopped. Transfer
promptly to a medical facility. When this chemical
has been swallowed, get medical attention. Give large
quantities of water and induce vomiting. Do not make an
unconscious person vomit. | [Shipping]
UN2047 Dichloropropene, Hazard Class: 3;
Labels: 3-Flammable liquid. | [Incompatibilities]
Vapor may form explosive mixture
with air. Incompatible with oxidizers (chlorates, nitrates,
peroxides, permanganates, perchlorates, chlorine, bromine,
fluorine, etc.); contact may cause fires or explosions. Keep
away from alkaline materials, strong bases, strong acids,
oxoacids, and epoxides. May accumulate static electrical
charges, and may cause ignition of its vapors. Incompatible
with strong acids; oxidizers, aluminum or magnesium compounds; aliphatic amines; alkanolamines, alkaline materials;
halogens, or corrosives. Note: Epichlorohydrin may be
added as a stabilizer. | [Description]
Trans-1,3-dichloropropene appears as a clear colorless liquid with chloroform odor. Flash point 95 °F. Density 1.225 g/cm3 and insoluble in water. Hence sinks in water. A strong irritant. Used as a soil fumigant. It is used as an intermediate in the manufacture of 3,3-dichloro-1-propene and other pesticides. | [Chemical Properties]
1,3-Dichloropropene is a colorless to strawcolored liquid. Sharp, sweet, irritating, chloroform-like odor. | [Chemical Properties]
colourless liquid | [Waste Disposal]
Incineration, preferably
after mixing with another combustible fuel. Care must be
exercised to assure complete combustion to prevent the
formation of phosgene. An acid scrubber is necessary to
remove the halo acids produced. In accordance with
40CFR165, follow recommendations for the disposal of
pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting
your local or federal environmental control agency, or by
contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on
acceptable disposal practices. Generators of waste containing this contaminant (≧100 kg/mo) must conform with
EPA regulations governing storage, transportation, treatment, and waste disposal. | [Physical properties]
Colorless to pale yellow liquid with a chloroform-like odor. Evaporates quickly when spilled. | [Uses]
The isomer mixture is used as a soil fumigant and a nematocide. | [Definition]
ChEBI: (E)-1,3-dichloropropene is a 1,3-dichloropropene with a (E)-configuration. It has a role as a fumigant. It is a 1,3-dichloropropene and a chloroalkene. It derives from a hydride of a propene. | [Environmental Fate]
Biological. The isomeric mixture showed significant degradation with gradual adaptation
in a static-culture flask-screening test (settled domestic wastewater inoculum) conducted
at 25°C. At concentrations of 5 and 10 mg/L, percent losses after 4 weeks of
incubation were 85 and 84, respectively. Ten days into the incubation study, 7–19% was
lost due to volatilization (Tabak et al., 1981).
Chemical/Physical. Hydrolysis in distilled water at 25°C produced trans-3-chloro-2-
propen-1-ol and hydrochloric acid. The reported half-life for this reaction is only 2 days (Kollig, 1993; Milano et al., 1988). trans-1,3-Dichloropropylene was reported to hydrolyze
to 3-chloro-2-propen-1-ol and can be biologically oxidized to 3-chloropropenoic acid
which is further oxidized to formylacetic acid. Decarboxylation of this compound yields
carbon dioxide (Connors et al., 1990). Chloroacetaldehyde, formyl chloride and chloroacetic
acid were formed from the ozonation of dichloropropylene at approximately 23°C
and 730 mmHg. Chloroacetaldehyde and formyl chloride also formed from the reaction
of dichloropropylene and hydroxyl radicals (Tuazon et al., 1984).
The evaporation half-life of trans-1,3-dichloropropylene (1 mg/L) from water at 25°C
using a shallow-pitch propeller stirrer at 200 rpm at an average depth of 6.5 cm is 24.6
minutes (Dilling, 1977).
Emits chlorinated acids when incinerated. Incomplete combustion may release toxic
phosgene (Sittig, 1985). | [Solubility in water]
Miscible with acetone, benzene, carbon tetrachloride, heptane, methanol (Worthing and Hance,
1991), methylene chloride, chloroform, trichloroethylene, and 1,1,2,2-tetrachloroethane. |
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