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ChemicalBook CAS DataBase List VINYL METHACRYLATE
4245-37-8

VINYL METHACRYLATE synthesis

4synthesis methods
-

Yield:-

Reaction Conditions:

decacarbonyldirhenium(0) in toluene at 140; under 15001.5 Torr; for 13 h;Product distribution / selectivity;

Steps:

18

Example 18; A mixture of 30.0 g (348 mmol) of methacrylic acid, 0.5 g of Re2(CO)10 (0.77 mmol) and 90 ml of toluene was subjected to vinylation at 140° C., a nitrogen pressure of 2 bar and an acetylene pressure of 18 bar for 13 h. Vinyl methacrylate was detected as the main product by means of GC-MS and GC analysis.

References:

US2008/308765,2008,A1 Location in patent:Page/Page column 6

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