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55637-37-1

(S)-1-CYCLOPROPYLETHANOL synthesis

5synthesis methods
-

Yield:6516-09-2 99%

Reaction Conditions:

with bis(1,5-cyclooctadiene)diiridium(I) dichloride;(SC,SC,RFC)-1-(diphenylphosphino)-2-[1-N-((4S)-4-tert-butyl-2-oxazolinyl-2-ylmethyl)ethyl]ferrocene;hydrogen;potassium carbonate in isopropyl alcohol at 25; under 15201 Torr; for 2 h;Glovebox;Autoclave;enantioselective reaction;

References:

Wu, Weilong;Liu, Shaodong;Duan, Meng;Tan, Xuefeng;Chen, Caiyou;Xie, Yun;Lan, Yu;Dong, Xiu-Qin;Zhang, Xumu [Organic Letters,2016,vol. 18,# 12,p. 2938 - 2941] Location in patent:supporting information

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