ETHYLBENZENE-2,3,4,5,6-D5 synthesis
- Product Name:ETHYLBENZENE-2,3,4,5,6-D5
- CAS Number:20302-26-5
- Molecular formula:C8H5D5
- Molecular Weight:111.2
Yield:20302-26-5 97 % ，74-85-1 1 %
Reaction Conditions:
with aluminum chlorofluoride;tri-n-butyl-tin hydride in benzene-d6 at 70;Schlenk technique;
Steps:
C-F bond activation of fluoroethane at ACF in the presence of HSnBu3
A reaction of fluoroethane (0.12 mmol) in C6D6 gave after 4 days with 97% yield ethylbenzene-d5 and 1% yield ethene. NMR data of ethylbenzene[18]: 1H NMR (300 MHz, C6D6): δ= 2.42 (q, 2H, CH2, 3JH,H= 7.6Hz), 0.94 (t, 3H, CH3, 3JH,H= 7.4Hz) ppm.
References:
Pan, Xinzi;Talavera, Maria;Braun, Thomas [Journal of Fluorine Chemistry,2022,vol. 263,art. no. 110046] Location in patent:supporting information
74-85-1
101 suppliers
$79.00/11l
1076-43-3
227 suppliers
$21.00/10x0.5ml
20302-26-5
27 suppliers
$498.11/5MG
100-42-5
631 suppliers
$20.00/25mL
20302-26-5
27 suppliers
$498.11/5MG
100-41-4
341 suppliers
$5.00/5G
20302-26-5
27 suppliers
$498.11/5MG