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ChemicalBook CAS DataBase List DI-N-HEXYL SULFIDE
6294-31-1

DI-N-HEXYL SULFIDE synthesis

10synthesis methods
-

Yield:6294-31-1 92%

Reaction Conditions:

with cerium(III) bromide;dihydrogen peroxide in tetrahydrofuran;water at 20; for 0.1 - 1.5 h;

Steps:

7 Example 7

1 g (1 mmol, 118.2 mg) was dissolved in THF (1.5 ml), CeBr3 (0.02 mmol, 7.6 mg) and H2O2 aqueous solution (30 wt%, 0.6 mmol, 61.3 μl) were successively added to the mixture, and the mixture was stirred at room temperature. Reaction 0.1-1.5h. After completion of the reaction, the reaction was quenched with Na2S2O3 solution (0.1M, 1.5ml) and extracted with ethyl acetate (30ml). The organic phase was collected and the aqueous phase was extracted with ethyl acetate (3 x 10 ml). The organic phases were combined, washed with water in sequence, dried over anhydrous sodium sulfate, filtered, and concentrated under reduced pressure to obtain 2 g of the target product (yield: 92%).

References:

CN113860982,2021,A Location in patent:Paragraph 0046-0048

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