ChemicalBook CAS DataBase List 4-tert-Butyltoluene

4-tert-Butyltoluene synthesis

14synthesis methods

Product Name:4-tert-Butyltoluene
CAS Number:98-51-1
Molecular formula:C11H16
Molecular Weight:148.24

Synthesis of 4-tert-butyltoluene: Put toluene in the reaction kettle, add catalyst, then add tert-butane chloride, after the reaction, wash with water and layer, and the organic layer is distilled to obtain the product. Alkylation of isobutylene and toluene in the presence of sulfuric acid can also be used to produce 4-tert-butyltoluene.

877-65-6 Synthesis

877-65-6
185 suppliers
$41.89/5g

98-51-1
221 suppliers
$10.00/1g

Yield:98-51-1 90 %Chromat.

Reaction Conditions:

with triethylsilane in ethanol at 20; for 0.166667 h;Inert atmosphere;

Steps:

2.4. General procedure for benzyl alcohol hydrogenolysis
General procedure: To a solution of benzyl alcohol (1mmol) and triethylsilane (amountindicated in Table 2) in ethanol (5mL)was added 10 mg of Pd NPs/rGO under an argon atmosphere. The resulting mixture was stirred for thetime indicated in Table 2 prior to GC-MS analysis. The resultingmixturewas filtered and washed by ethyl acetate for catalyst separation. Thepure product in entry 1 was isolated by distillation; for entries 2-10the products were isolated by column chromatography using hexane/ethyl acetate (9/1) as eluent.

References:

Mirza-Aghayan, Maryam;Molaee Tavana, Mahdieh;Boukherroub, Rabah [Catalysis Communications,2015,vol. 69,p. 97 - 103]

49543-63-7 Synthesis