ChemicalBook CAS DataBase List tert-Butanol

tert-Butanol synthesis

12synthesis methods

Product Name:tert-Butanol
CAS Number:75-65-0
Molecular formula:C4H10O
Molecular Weight:74.12

t-Butyl alcohol is produced as a by-product from the isobutane oxidation process for manufacturing propylene oxide. t-Butyl alcohol is also produced by the acidcatalyzed hydration of isobutylene, a process no longer used in the United States.

13058-24-7 Synthesis

13058-24-7
111 suppliers
$54.00/5ML

75-65-0
752 suppliers
$10.00/10ml

Yield:75-65-0 99%

Reaction Conditions:

with methanol;1,3-disulfonic acid imidazolium hydrogen sulfate at 20; for 0.0833333 h;Green chemistry;

Steps:

General procedure for the deprotection of trimethylsilyl ethers

General procedure: A mixture of the substrate (1 mmol), ionic liquid [Dsim]HSO4 (6.5 mg, ～0.02 mmol) in methanol (2 mL) was stirred at room temperature. After completion of the reaction (monitored by TLC), solvent was evaporated, water (1 mL) was added to the mixture, and stirred vigorously. Decantation of the mixture gave almost pure product(s). The products were characterized by comparison of their IR and NMR data. The ionic liquid was dried at 65 ?C under vacuum to remove moisture, and then reused.

References:

Shirini, Farhad;Khaligh, Nader Ghaffari;Akbari-Dadamahaleh, Somayeh [Journal of Molecular Catalysis A: Chemical,2012,vol. 365,p. 15 - 23]

75-28-5 Synthesis