成人免费xx,国产又黄又湿又刺激不卡网站,成人性视频app菠萝网站,色天天天天

Welcome to chemicalbook!
Chinese English Japanese Germany Korea
400-158-6606
Try our best to find the right business for you.
Do not miss inquiry messages Please log in to view all inquiry messages.

Welcome back!

ChemicalBook CAS DataBase List 4-Pentylcyclohexanone
61203-83-6

4-Pentylcyclohexanone synthesis

11synthesis methods
-

Yield: 74%

Reaction Conditions:

with 2,2,6,6-tetramethyl-piperidine;n-butyllithium in tetrahydrofuran;hexane at -20 - 20; for 16 h;Inert atmosphere;

Steps:

General procedure for the deprotection of 1,3-dioxolanes promoted by lithium 2,2,6,6-tetramethylpiperidide (Table 2 and Table 3)
General procedure: To a solution of 2,2,6,6-tetramethylpiperidine (TMP) (0.34 mL, 2.00 mmol, 4.0 equiv.) in THF (4 mL) was added n-BuLi (2.4 M in hexane, 0.83 mL, 2.00 mmol, 4.0 equiv.) at -20 or 0 . After stirring for 30 min, a solution of compound 1 or compound 4 (0.50 mmol, 1.0 equiv.) in THF (1 mL) was added. The resulting mixture was stirred before the completion of the reaction (monitored by TLC). Then the reaction mixture was poured into saturated NH4Cl solution (2.5 mL) at 0 and diluted with H2O (5 mL). The layers of the resulting mixture were separated and the aqueous layer was extracted with Et2O (4 × 15 mL). The combined organic layers were dried over Na2SO4, filtered and concentrated under reduced pressure. The residue was purified by flash column chromatography on silica gel to afford products.

References:

Yuan, Changchun;Yang, Li;Yue, Guizhou;Yu, Tianzi;Zhong, Weiming;Liu, Bo [Tetrahedron Letters,2012,vol. 53,# 51,p. 6972 - 6976] Location in patent:supporting information

4-Pentylcyclohexanone Related Search: