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ChemicalBook CAS DataBase List 4-Bromo-1H-imidazole
2302-25-2

4-Bromo-1H-imidazole synthesis

7synthesis methods
-

Yield:2302-25-2 89%

Reaction Conditions:

with sodium sulfite in water at 110; for 6 h;

Steps:

1.3 (3) Synthesis of 4-bromoimidazole (Intermediate 6)
To a single-necked flask was added 2,4,5-tribromoimidazole (49 g, 161 mmol)Sodium sulfite (101.5 g, 806 mmol)And water (500 ml) were added and stirred at 110 ° C for 6 h,Ethyl acetate was added,The organic layers were combined and dried over anhydrous sodium sulfate,Rotate the ethyl acetate to give compound 6 (20.5 g, yield 89%)

References:

Hinova Pharmaceuticals Inc.;Fan, Lei;Chen, Ke;Li, Xinghai;Chen, Yuanwei CN106256830, 2016, A Location in patent:Paragraph 0044; 0052; 0053; 0054

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