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ChemicalBook CAS DataBase List 11beta,21-dihydroxypregna-1,4,16-triene-3,20-dione 21-acetate
3044-42-6

11beta,21-dihydroxypregna-1,4,16-triene-3,20-dione 21-acetate synthesis

7synthesis methods
-

Yield:3044-42-6 81%

Steps:

9 EXAMPLE 9
EXAMPLE 9 One gram of 17α,21-diacetoxy-11β-hydroxy-1,4- pregnadiene-3,20-dione is treated analogously to Example 1 in "Dowtherm" for 50 minutes at 250° C. and worked up. Recrystallization from isopropyl ether yields 700 mg of 21-acetoxy-11β-hydroxy-1,4,16-pregnatriene-3,20-dione (81% of theory). UV (methanol): ε242 =22,500.

References:

Schering Aktiengesellschaft US4290963, 1981, A

FullText

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