ChemicalBook CAS DataBase List 1-Cyclohexenyloxytrimethylsilane

1-Cyclohexenyloxytrimethylsilane synthesis

14synthesis methods

Product Name:1-Cyclohexenyloxytrimethylsilane
CAS Number:6651-36-1
Molecular formula:C9H18OSi
Molecular Weight:170.32

10416-59-8
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108-94-1 Synthesis

108-94-1
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6651-36-1
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$18.00/5g

Yield:6651-36-1 81%

Reaction Conditions:

with polystyrene-bound 2-tert-butylimino-2-diethylamino-1,3-dimethylperhydro-1,3,2-diazaphosphorine in neat (no solvent) at 60; for 3 h;

Steps:

General procedure for preparation of silyl enol ethers7p-s, 7v, 7x
General procedure: Aliphatic ketone or aldehyde (1.0 mmol), BSA (244 μL, 1.0mmol) and PS-BEMP (10 mol %, 45 mg)were added in a vial and stirred at 60°C and for the time reported in the manuscript. The productswere isolated by distillation under pressure to give the pure products. Trimethyl-(cyclohex-1-enyloxy)-silane (yellow oil, 81% yield, 140 mg) 1H-NMR (200MHz, CDCl3)δ:0.12 (s, 9H), 1.31-1.54 (m, 4H), 1.78-1.93 (m, 4H), 4.67-4.71 (m, 1H). The spectroscopic data of7p are in accordance with those described in the literature.16

References:

Morozzi, Chiara;Rosati, Ornelio;Curini, Massimo;Lanari, Daniela [Synlett,2018,vol. 29,# 1,art. no. ST-2017-B0386-L,p. 126 - 130] Location in patent:supporting information

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