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ChemicalBook >> CAS DataBase List >> n-Butyllithium

n-Butyllithium

n-Butyllithium price.
  • $30 - $2110
  • Product name: n-Butyllithium
  • CAS: 109-72-8
  • MF: C4H9Li
  • MW: 64.06
  • EINECS:203-698-7
  • MDL Number:MFCD00009414
  • Synonyms:LITHIUMBUTYL;N-BUTYLLITHIUM;BUTYLLITHIUM SOLUTION, ~2.7 M IN HEPTANE;N-BUTYLLITHIUM, 2.2M SOLUTION IN CYCLOHEXANE;n-Butyllithium1.6M solution in hexanesAcroSeal§3;n-Butyllithium2.5M solution in hexanesAcroSeal§3;n-Butyllithium2.2M solution in cyclohexaneAcroSeal§3;n-Butyllithium2.6M solution in tolueneAcroSeal§3
32 prices
Selected condition:
Brand
  • Alfa Aesar
  • Oakwood
  • Sigma-Aldrich
  • Strem Chemicals
Package
  • 0.2mole
  • 0.25mole
  • 50ml
  • 1mole
  • 100ml
  • 4x25ml
  • 4x100ml
  • 400ml
  • 500ml
  • 800ml
  • 8l
  • 18L
  • ManufacturerAlfa Aesar
  • Product number044109
  • Product descriptionn-Butyllithium 2.2M in hexane
  • Packaging0.2mole
  • Price$38.5
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number041248
  • Product descriptionn-Butyllithium, 2.2M in hexane packaged under Argon in resealable ChemSeal? bottles
  • Packaging0.2mole
  • Price$38.5
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number047107
  • Product descriptionn-Butyllithium, 1.6M in hexanes packaged under Argon in resealable ChemSeal? bottles
  • Packaging100ml
  • Price$41.9
  • Updated2021-12-16
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  • ManufacturerAlfa Aesar
  • Product number044109
  • Product descriptionn-Butyllithium 2.2M in hexane
  • Packaging1mole
  • Price$70.8
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number047107
  • Product descriptionn-Butyllithium, 1.6M in hexanes packaged under Argon in resealable ChemSeal? bottles
  • Packaging500ml
  • Price$117
  • Updated2021-12-16
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  • ManufacturerOakwood
  • Product number044819
  • Product description1.6 M N-Butyl lithium in hexanes
  • Packaging100ml
  • Price$30
  • Updated2021-12-16
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  • ManufacturerOakwood
  • Product number044819
  • Product description1.6 M N-Butyl lithium in hexanes
  • Packaging400ml
  • Price$55
  • Updated2021-12-16
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  • ManufacturerOakwood
  • Product number044819
  • Product description1.6 M N-Butyl lithium in hexanes
  • Packaging800ml
  • Price$104
  • Updated2021-12-16
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  • ManufacturerSigma-Aldrich
  • Product number186171
  • Product descriptionn-Butyllithium solution 1.6M in hexanes
  • Packaging50ml
  • Price$40.8
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number186171
  • Product descriptionn-Butyllithium solution 1.6M in hexanes
  • Packaging4x25ml
  • Price$62.3
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number186171
  • Product descriptionn-Butyllithium solution 1.6M in hexanes
  • Packaging100ml
  • Price$65.6
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number302120
  • Product descriptionn-Butyllithium solution 2.0 M in cyclohexane
  • Packaging4x25ml
  • Price$68.7
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number230707
  • Product descriptionn-Butyllithium solution 2.5M in hexanes
  • Packaging4x25ml
  • Price$69.3
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number302120
  • Product descriptionn-Butyllithium solution 2.0 M in cyclohexane
  • Packaging100ml
  • Price$72.3
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number186171
  • Product descriptionn-Butyllithium solution 1.6M in hexanes
  • Packaging8l
  • Price$941
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number230707
  • Product descriptionn-Butyllithium solution 2.5M in hexanes
  • Packaging8l
  • Price$1340
  • Updated2024-03-01
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Manufacturer Product number Product description Packaging Price Updated Buy
Alfa Aesar 044109 n-Butyllithium 2.2M in hexane 0.2mole $38.5 2021-12-16 Buy
Alfa Aesar 041248 n-Butyllithium, 2.2M in hexane packaged under Argon in resealable ChemSeal? bottles 0.2mole $38.5 2021-12-16 Buy
Alfa Aesar 047107 n-Butyllithium, 1.6M in hexanes packaged under Argon in resealable ChemSeal? bottles 100ml $41.9 2021-12-16 Buy
Alfa Aesar 044109 n-Butyllithium 2.2M in hexane 1mole $70.8 2021-12-16 Buy
Alfa Aesar 047107 n-Butyllithium, 1.6M in hexanes packaged under Argon in resealable ChemSeal? bottles 500ml $117 2021-12-16 Buy
Oakwood 044819 1.6 M N-Butyl lithium in hexanes 100ml $30 2021-12-16 Buy
Oakwood 044819 1.6 M N-Butyl lithium in hexanes 400ml $55 2021-12-16 Buy
Oakwood 044819 1.6 M N-Butyl lithium in hexanes 800ml $104 2021-12-16 Buy
Sigma-Aldrich 186171 n-Butyllithium solution 1.6M in hexanes 50ml $40.8 2024-03-01 Buy
Sigma-Aldrich 186171 n-Butyllithium solution 1.6M in hexanes 4x25ml $62.3 2024-03-01 Buy
Sigma-Aldrich 186171 n-Butyllithium solution 1.6M in hexanes 100ml $65.6 2024-03-01 Buy
Sigma-Aldrich 302120 n-Butyllithium solution 2.0 M in cyclohexane 4x25ml $68.7 2024-03-01 Buy
Sigma-Aldrich 230707 n-Butyllithium solution 2.5M in hexanes 4x25ml $69.3 2024-03-01 Buy
Sigma-Aldrich 302120 n-Butyllithium solution 2.0 M in cyclohexane 100ml $72.3 2024-03-01 Buy
Sigma-Aldrich 186171 n-Butyllithium solution 1.6M in hexanes 8l $941 2024-03-01 Buy
Sigma-Aldrich 230707 n-Butyllithium solution 2.5M in hexanes 8l $1340 2024-03-01 Buy

Properties

Melting point :-95 °C
Boiling point :80 °C
Density :0.68 g/mL at 20 °C
Flash point :10 °F
storage temp. :2-8°C
solubility :Miscible with diethyl ether and cyclohexane.
form :liquid
color :yellow
Specific Gravity :0.695
Odor :Odor of the solvent
Water Solubility :vigorous reaction
Hydrolytic Sensitivity :8: reacts rapidly with moisture, water, protic solvents
Sensitive :Air & Moisture Sensitive
BRN :1209227
Exposure limits :ACGIH: TWA 50 ppm (Skin)
OSHA: TWA 500 ppm(1800 mg/m3)
NIOSH: IDLH 1100 ppm; TWA 50 ppm(180 mg/m3) LogP :1.25-2.31
CAS DataBase Reference :109-72-8(CAS DataBase Reference)
NIST Chemistry Reference :Butyl lithium(109-72-8)
EPA Substance Registry System :Lithium, butyl- (109-72-8)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H250 Catches fire spontaneously if exposed to air Pyrophoric liquids; Pyrorophoric solids Category 1 Danger GHS hazard pictograms P210, P222, P280, P302+P334,P370+P378, P422
H252 Self-heating in large quantities; may catch fire Self-heating substances and mixtures Category 2 Warning P235+P410, P280, P407, P413, P420
H260 In contact with water releases flammable gases which may ignite spontaneously Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 1 Danger GHS hazard pictograms P223, P231+P232, P280, P335+ P334,P370+P378, P402+P404, P501
H261 In contact with water releases flammable gas Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 2
Category 3
Danger
Warning
GHS hazard pictograms P231+P232, P280, P370+P378,P402+P404, P501
H304 May be fatal if swallowed and enters airways Aspiration hazard Category 1 Danger GHS hazard pictograms
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger GHS hazard pictograms P280, P305+P351+P338, P310
H332 Harmful if inhaled Acute toxicity,inhalation Category 4 Warning GHS hazard pictograms P261, P271, P304+P340, P312
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
H361 Suspected of damaging fertility or the unborn child Reproductive toxicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
H401 Toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 2 P273, P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning GHS hazard pictograms P273, P391, P501
H411 Toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 2
Precautionary statements:
P201 Obtain special instructions before use.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P222 Do not allow contact with air.
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P231+P232 Handle under inert gas. Protect from moisture.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302+P334 IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P331 Do NOT induce vomiting.
P370+P378 In case of fire: Use … for extinction.
P405 Store locked up.
P422 Store contents under …

Description

n-Butyllithium is used as a polymerization initiator in the production of elastomers like polybutadiene and styrene- butadiene- styrene. As a strong base, it is utilized in the synthesis of organic compounds. It undergoes thermal decomposition to prepare 1-butene.

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