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ChemicalBook >> CAS DataBase List >> tert-Butyldichlorophosphine

tert-Butyldichlorophosphine

tert-Butyldichlorophosphine price.
  • $20.65 - $4640
  • Product name: tert-Butyldichlorophosphine
  • CAS: 25979-07-1
  • MF: C4H9Cl2P
  • MW: 158.99
  • EINECS:247-386-9
  • MDL Number:MFCD00013615
  • Synonyms:DICHLORO-TERT-BUTYLPHOSPHINE;AURORA KA-1260;T-BUTYLDICHLOROPHOSPHINE;T-BUTYLPHOSPHONOUS DICHLORIDE;TERT-BUTYLDICHLOROPHOSPHINE;Phosphonous dichloride, (1,1-dimethylethyl)-;tert-Butylphosphonous dichloride;tert-C4H9PCl2
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  • AHH
  • Alfa Aesar
  • American Custom Chemicals Corporation
  • Chemenu
  • JR MediChem
  • Sigma-Aldrich
  • Strem Chemicals
Package
  • 1g
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  • 10g
  • 50g
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  • ManufacturerAHH
  • Product numberMT-04023
  • Product descriptiontert-Butyldichlorophosphine 98%
  • Packaging100g
  • Price$356
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberH27360
  • Product descriptiontert-Butyldichlorophosphine 98%
  • Packaging1g
  • Price$20.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberH27360
  • Product descriptiontert-Butyldichlorophosphine 98%
  • Packaging10g
  • Price$109
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberH27360
  • Product descriptiontert-Butyldichlorophosphine 98%
  • Packaging50g
  • Price$361
  • Updated2024-03-01
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberOPC0001079
  • Product descriptionTERT-BUTYLDICHLOROPHOSPHINE 95.00%
  • Packaging1G
  • Price$160.44
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberOPC0001079
  • Product descriptionTERT-BUTYLDICHLOROPHOSPHINE 95.00%
  • Packaging10G
  • Price$1190.92
  • Updated2021-12-16
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  • ManufacturerChemenu
  • Product numberCM329125
  • Product descriptiontert-butyl(dichloro)phosphane 95%+
  • Packaging50g
  • Price$524
  • Updated2021-12-16
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  • ManufacturerChemenu
  • Product numberCM329125
  • Product descriptiontert-butyl(dichloro)phosphane 95%+
  • Packaging100g
  • Price$1012
  • Updated2021-12-16
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  • ManufacturerChemenu
  • Product numberCM329125
  • Product descriptiontert-butyl(dichloro)phosphane 95%+
  • Packaging1000g
  • Price$4640
  • Updated2021-12-16
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  • ManufacturerJR MediChem
  • Product numberJR6-L9312
  • Product descriptionPhosphonousdichloride,P-(1,1-dimethylethyl)- 96%
  • Packaging100g
  • Price$918
  • Updated2021-12-16
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  • ManufacturerSigma-Aldrich
  • Product number381020
  • Product descriptiontert-Butyldichlorophosphine 98%
  • Packaging10g
  • Price$119
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number707230
  • Product descriptiontert-Butyldichlorophosphine solution 1.0M in diethyl ether
  • Packaging100ml
  • Price$180
  • Updated2024-03-01
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  • ManufacturerStrem Chemicals
  • Product number15-0500
  • Product descriptiont-Butyldichlorophosphine, 98%
  • Packaging2g
  • Price$33
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number15-0500
  • Product descriptiont-Butyldichlorophosphine, 98%
  • Packaging10g
  • Price$99
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AHH MT-04023 tert-Butyldichlorophosphine 98% 100g $356 2021-12-16 Buy
Alfa Aesar H27360 tert-Butyldichlorophosphine 98% 1g $20.65 2024-03-01 Buy
Alfa Aesar H27360 tert-Butyldichlorophosphine 98% 10g $109 2024-03-01 Buy
Alfa Aesar H27360 tert-Butyldichlorophosphine 98% 50g $361 2024-03-01 Buy
American Custom Chemicals Corporation OPC0001079 TERT-BUTYLDICHLOROPHOSPHINE 95.00% 1G $160.44 2021-12-16 Buy
American Custom Chemicals Corporation OPC0001079 TERT-BUTYLDICHLOROPHOSPHINE 95.00% 10G $1190.92 2021-12-16 Buy
Chemenu CM329125 tert-butyl(dichloro)phosphane 95%+ 50g $524 2021-12-16 Buy
Chemenu CM329125 tert-butyl(dichloro)phosphane 95%+ 100g $1012 2021-12-16 Buy
Chemenu CM329125 tert-butyl(dichloro)phosphane 95%+ 1000g $4640 2021-12-16 Buy
JR MediChem JR6-L9312 Phosphonousdichloride,P-(1,1-dimethylethyl)- 96% 100g $918 2021-12-16 Buy
Sigma-Aldrich 381020 tert-Butyldichlorophosphine 98% 10g $119 2024-03-01 Buy
Sigma-Aldrich 707230 tert-Butyldichlorophosphine solution 1.0M in diethyl ether 100ml $180 2024-03-01 Buy
Strem Chemicals 15-0500 t-Butyldichlorophosphine, 98% 2g $33 2024-03-01 Buy
Strem Chemicals 15-0500 t-Butyldichlorophosphine, 98% 10g $99 2024-03-01 Buy

Properties

Melting point :44-49 °C(lit.)
Boiling point :142-150 °C
Density :0.766 g/mL at 25 °C
storage temp. :Inert atmosphere,2-8°C
form :Low Melting Crystalline Mass
color :White to light yellow
Water Solubility :Reacts with water. Soluble in n-Pentane, n-Hexane, Ether, Toluene,THF. tert-Butyldichlorophosphine is infinitely soluble in hydrocarbon and ethereal solvents.
Sensitive :Air Sensitive
Hydrolytic Sensitivity :8: reacts rapidly with moisture, water, protic solvents
CAS DataBase Reference :25979-07-1(CAS DataBase Reference)
NIST Chemistry Reference :Tert-butyldichlorophosphine(25979-07-1)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P363 Wash contaminated clothing before reuse.

Description

Reactant for the synthesis of alkali metal complexes. As intermediates. tert-Butyldichlorophosphine (TBDCP) is used primarily in the preparation of monoand bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations and other asymmetric reactions as well as transition metal coupling reactions. This reagent is also used in the preparation of other phosphines in catalytic polymerization reactions.

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