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ChemicalBook >> CAS DataBase List >> Lithium Triethylborohydride

Lithium Triethylborohydride

Lithium Triethylborohydride price.
  • $27.4 - $874
  • Product name: Lithium Triethylborohydride
  • CAS: 22560-16-3
  • MF: C6H13BLi
  • MW: 102.92
  • EINECS:245-076-8
  • MDL Number:MFCD00011703
  • Synonyms:lithiumtriethylborohydride,calselect?lt, ;lithiumtriethylborohydride,calselect?lt,intetrahydrofuran ;Lithium triethylborohydrideLithium triethylhydroborate;Lithium triethylborahydride (super-hydride);Super-Hydride solution,Lithium triethylborohydride solution;Lithium triethylborohydride, 1M solution in THF, AcroSeal;LithiuM triethylborohydride, 1M solution in THF, AcroSeal 100ML;LithiuM triethylborohydride, 1M solution in THF, AcroSeal 800ML
20 prices
Selected condition:
Brand
  • Alfa Aesar
  • American Custom Chemicals Corporation
  • Sigma-Aldrich
  • TCI Chemical
  • TRC
  • Usbiological
Package
  • 5MG
  • 25ml
  • 50ml
  • 100ml
  • 4X25ML
  • 250ml
  • 500ml
  • 800ml
  • 2l
  • 8l
  • ManufacturerAlfa Aesar
  • Product number089144
  • Product descriptionLithium triethylborohydride, 1M in THF
  • Packaging25ml
  • Price$27.4
  • Updated2022-04-27
  • Buy
  • ManufacturerAlfa Aesar
  • Product number042491
  • Product descriptionLithium triethylborohydride, 1M in THF, packaged under Argon in resealable ChemSeal? bottles
  • Packaging25ml
  • Price$33.2
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number042491
  • Product descriptionLithium triethylborohydride, 1M in THF, packaged under Argon in resealable ChemSeal? bottles
  • Packaging50ml
  • Price$60.4
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberH36830
  • Product descriptionLithium triethylborohydride, 1.7M in THF packaged under Nitrogen in resealable AcroSeal[t bottles
  • Packaging100ml
  • Price$80.9
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number089144
  • Product descriptionLithium triethylborohydride, 1M in THF
  • Packaging100ml
  • Price$83.1
  • Updated2022-04-27
  • Buy
  • ManufacturerAlfa Aesar
  • Product number042491
  • Product descriptionLithium triethylborohydride, 1M in THF, packaged under Argon in resealable ChemSeal? bottles
  • Packaging100ml
  • Price$98
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number042491
  • Product descriptionLithium triethylborohydride, 1M in THF, packaged under Argon in resealable ChemSeal? bottles
  • Packaging500ml
  • Price$366
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberH36830
  • Product descriptionLithium triethylborohydride, 1.7M in THF packaged under Nitrogen in resealable AcroSeal[t bottles
  • Packaging800ml
  • Price$366
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number089144
  • Product descriptionLithium triethylborohydride, 1M in THF
  • Packaging500ml
  • Price$366
  • Updated2022-04-27
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0010991
  • Product descriptionLITHIUM TRIETHYLBOROHYDRIDE 95.00%
  • Packaging25ML
  • Price$131
  • Updated2021-12-16
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0010991
  • Product descriptionLITHIUM TRIETHYLBOROHYDRIDE 95.00%
  • Packaging5MG
  • Price$500.87
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number179728
  • Product descriptionSuper-Hydride? solution 1.0 M lithium triethylborohydride in THF
  • Packaging100ml
  • Price$110
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number179728
  • Product descriptionSuper-Hydride? solution 1.0?M lithium triethylborohydride in THF
  • Packaging4X25ML
  • Price$152
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number179728
  • Product descriptionSuper-Hydride? solution 1.0 M lithium triethylborohydride in THF
  • Packaging800ml
  • Price$477
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number179728
  • Product descriptionSuper-Hydride? solution 1.0 M lithium triethylborohydride in THF
  • Packaging8l
  • Price$820
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number179728
  • Product descriptionSuper-Hydride? solution 1.0 M lithium triethylborohydride in THF
  • Packaging2l
  • Price$874
  • Updated2023-06-20
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Alfa Aesar 089144 Lithium triethylborohydride, 1M in THF 25ml $27.4 2022-04-27 Buy
Alfa Aesar 042491 Lithium triethylborohydride, 1M in THF, packaged under Argon in resealable ChemSeal? bottles 25ml $33.2 2021-12-16 Buy
Alfa Aesar 042491 Lithium triethylborohydride, 1M in THF, packaged under Argon in resealable ChemSeal? bottles 50ml $60.4 2021-12-16 Buy
Alfa Aesar H36830 Lithium triethylborohydride, 1.7M in THF packaged under Nitrogen in resealable AcroSeal[t bottles 100ml $80.9 2021-12-16 Buy
Alfa Aesar 089144 Lithium triethylborohydride, 1M in THF 100ml $83.1 2022-04-27 Buy
Alfa Aesar 042491 Lithium triethylborohydride, 1M in THF, packaged under Argon in resealable ChemSeal? bottles 100ml $98 2021-12-16 Buy
Alfa Aesar 042491 Lithium triethylborohydride, 1M in THF, packaged under Argon in resealable ChemSeal? bottles 500ml $366 2021-12-16 Buy
Alfa Aesar H36830 Lithium triethylborohydride, 1.7M in THF packaged under Nitrogen in resealable AcroSeal[t bottles 800ml $366 2021-12-16 Buy
Alfa Aesar 089144 Lithium triethylborohydride, 1M in THF 500ml $366 2022-04-27 Buy
American Custom Chemicals Corporation ING0010991 LITHIUM TRIETHYLBOROHYDRIDE 95.00% 25ML $131 2021-12-16 Buy
American Custom Chemicals Corporation ING0010991 LITHIUM TRIETHYLBOROHYDRIDE 95.00% 5MG $500.87 2021-12-16 Buy
Sigma-Aldrich 179728 Super-Hydride? solution 1.0 M lithium triethylborohydride in THF 100ml $110 2024-03-01 Buy
Sigma-Aldrich 179728 Super-Hydride? solution 1.0?M lithium triethylborohydride in THF 4X25ML $152 2024-03-01 Buy
Sigma-Aldrich 179728 Super-Hydride? solution 1.0 M lithium triethylborohydride in THF 800ml $477 2024-03-01 Buy
Sigma-Aldrich 179728 Super-Hydride? solution 1.0 M lithium triethylborohydride in THF 8l $820 2024-03-01 Buy
Sigma-Aldrich 179728 Super-Hydride? solution 1.0 M lithium triethylborohydride in THF 2l $874 2023-06-20 Buy

Properties

Melting point :66-67° (Binger); mp 78-83° (dec) (Brown, 1977)
Density :0.892 g/mL at 25 °C
Flash point :1 °F
storage temp. :Flammables + water-Freezer (-20°C)e area
solubility :Miscible with tetrahydrofuran and benzene.
form :Liquid
color :Colorless to light gray
Sensitive :Air & Moisture Sensitive
Merck :14,5544
BRN :4151240
Exposure limits :ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3) CAS DataBase Reference :22560-16-3(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H260 In contact with water releases flammable gases which may ignite spontaneously Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 1 Danger GHS hazard pictograms P223, P231+P232, P280, P335+ P334,P370+P378, P402+P404, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger GHS hazard pictograms P280, P305+P351+P338, P310
H333 May be harmful if inhaled Acute toxicity,inhalation Category 5 P304+P312
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P231+P232 Handle under inert gas. Protect from moisture.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.
P402+P404 Store in a dry place. Store in a closed container.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.

Description

Lithium triethylborohydride is used as a powerful reducing agent in organic synthesis for the conversion of carbonyl compounds to alcohols. It is also used in the preparation of alkynyl alcohols from the cleavage of cyclic keto-vinyl triflates. It is also used in the reduction of esters and lactones to alcohol and diol respectively. Further, it is used to prepare 1-methylcyclohexanol and 1,4-butanediol from 1,2-epoxybutane and gamma-butyrolactone respectively. It is also utilized for reductive cleavage of mesylates and tosylates in synthetic organic chemistry.

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