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ChemicalBook >> CAS DataBase List >> (-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE

(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE

(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE price.
  • $88.8 - $1725
  • Product name: (-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
  • CAS: 213343-65-8
  • MF: C22H40BF4P2Rh-
  • MW: 556.21
  • EINECS:
  • MDL Number:MFCD32853739
  • Synonyms:(+)-1,2-Bis[(2S,5S)-2,5-diMethylphospholano]ethane(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate, 97%;(-)-1,2-Bis((2S,5S)-2,5-diMethylphospholano)ethane(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate (S,S)-Me-BPE-Rh;(à)-Methyl 2-benzyloxycarbonylamino-2-(dimethoxyphosphinyl)acetat;(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE;(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium(I)tetrafluoroborate,98+%(S,S)-Me-BPE-Rh;(S,S)-ME-BPE-RH;(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Me-BPE-Rh;(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(1,5-CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE,98+%(S,S)-ME-BPE-RH
12 prices
Selected condition:
Brand
  • Ambeed
  • American Custom Chemicals Corporation
  • Arctom
  • Sigma-Aldrich
  • Strem Chemicals
Package
  • 50mg
  • 100mg
  • 250mg
  • 500MG
  • 1g
  • 2g
  • ManufacturerAmbeed
  • Product numberA1371103
  • Product description1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate 98+%
  • Packaging50mg
  • Price$124
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1371103
  • Product description1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate 98+%
  • Packaging100mg
  • Price$196
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1371103
  • Product description1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate 98+%
  • Packaging250mg
  • Price$320
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1371103
  • Product description1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate 98+%
  • Packaging1g
  • Price$855
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberOGM0000021
  • Product description(S,S)-ME-BPE-RH 95.00%
  • Packaging100MG
  • Price$707.64
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberOGM0000021
  • Product description(S,S)-ME-BPE-RH 95.00%
  • Packaging500MG
  • Price$1102.99
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS713321
  • Product description1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate
  • Packaging100mg
  • Price$232
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number675547
  • Product description1,2-Bis[(2S,5S)-2,5-dimethylphospholano]ethane(cyclooctadiene)rhodium(I) tetrafluoroborate
  • Packaging100mg
  • Price$88.8
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number675547
  • Product description1,2-Bis[(2S,5S)-2,5-dimethylphospholano]ethane(cyclooctadiene)rhodium(I) tetrafluoroborate
  • Packaging500mg
  • Price$212
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number45-0169
  • Product description(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Me-BPE-Rh
  • Packaging100mg
  • Price$125
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number45-0169
  • Product description(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Me-BPE-Rh
  • Packaging500mg
  • Price$531
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number45-0169
  • Product description(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Me-BPE-Rh
  • Packaging2g
  • Price$1725
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Ambeed A1371103 1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate 98+% 50mg $124 2021-12-16 Buy
Ambeed A1371103 1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate 98+% 100mg $196 2021-12-16 Buy
Ambeed A1371103 1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate 98+% 250mg $320 2021-12-16 Buy
Ambeed A1371103 1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate 98+% 1g $855 2021-12-16 Buy
American Custom Chemicals Corporation OGM0000021 (S,S)-ME-BPE-RH 95.00% 100MG $707.64 2021-12-16 Buy
American Custom Chemicals Corporation OGM0000021 (S,S)-ME-BPE-RH 95.00% 500MG $1102.99 2021-12-16 Buy
Arctom AS713321 1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate 100mg $232 2021-12-16 Buy
Sigma-Aldrich 675547 1,2-Bis[(2S,5S)-2,5-dimethylphospholano]ethane(cyclooctadiene)rhodium(I) tetrafluoroborate 100mg $88.8 2024-03-01 Buy
Sigma-Aldrich 675547 1,2-Bis[(2S,5S)-2,5-dimethylphospholano]ethane(cyclooctadiene)rhodium(I) tetrafluoroborate 500mg $212 2024-03-01 Buy
Strem Chemicals 45-0169 (-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Me-BPE-Rh 100mg $125 2024-03-01 Buy
Strem Chemicals 45-0169 (-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Me-BPE-Rh 500mg $531 2024-03-01 Buy
Strem Chemicals 45-0169 (-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Me-BPE-Rh 2g $1725 2024-03-01 Buy

Properties

Melting point :152.2-156.3 °C
form :Crystalline Powder
color :Orange to red to brown
Sensitive :air sensitive

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

Catalyst for:
  • Asymmetric hydrogenation

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