CHLOROMETHYLDIMETHYLPHENYLSILANE
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- $9 - $710
- Product name: CHLOROMETHYLDIMETHYLPHENYLSILANE
- CAS: 1833-51-8
- MF: C9H13ClSi
- MW: 184.74
- EINECS:217-392-6
- MDL Number:MFCD00040858
- Synonyms:(chloromethyl)dimethylphenyl-silan ;Dichloromethyldimethylphenylsilane;Phenyldimethyl(chloromethyl)silane;CHLOROMETHYLDIMETHYLPHENYLSILANE;Silane, (chloromethyl)dimethylphenyl-;Dimethylphenylsilyldichloromethane;Chloromethylphenyldimethylsilane;Phenyl(chloromethyl)dimethylsilane
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Brand
- AK Scientific
- Ambeed
- Biosynth Carbosynth
- Chemenu
- Crysdot
- Matrix Scientific
- Sigma-Aldrich
- TCI Chemical
- TRC
- Usbiological
Package
- 250mg
- 500mg
- 1g
- 2.5g
- 5g
- 10g
- 25g
- 50g
- 100g
- ManufacturerAK Scientific
- Product number9605AA
- Product description(Chloromethyl)dimethyl(phenyl)silane
- Packaging5g
- Price$120
- Updated2021-12-16
- Buy
- ManufacturerAK Scientific
- Product number9605AA
- Product description(Chloromethyl)dimethyl(phenyl)silane
- Packaging25g
- Price$259
- Updated2021-12-16
- Buy
- ManufacturerAmbeed
- Product numberA985316
- Product description(Chloromethyl)dimethyl(phenyl)silane 97%
- Packaging250mg
- Price$9
- Updated2021-12-16
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- ManufacturerAmbeed
- Product numberA985316
- Product description(Chloromethyl)dimethyl(phenyl)silane 97%
- Packaging1g
- Price$22
- Updated2021-12-16
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- ManufacturerAmbeed
- Product numberA985316
- Product description(Chloromethyl)dimethyl(phenyl)silane 97%
- Packaging5g
- Price$36
- Updated2021-12-16
- Buy
- ManufacturerAmbeed
- Product numberA985316
- Product description(Chloromethyl)dimethyl(phenyl)silane 97%
- Packaging25g
- Price$145
- Updated2021-12-16
- Buy
- ManufacturerAmbeed
- Product numberA985316
- Product description(Chloromethyl)dimethyl(phenyl)silane 97%
- Packaging100g
- Price$454
- Updated2021-12-16
- Buy
- ManufacturerBiosynth Carbosynth
- Product numberFC61180
- Product descriptionChloromethyldimethylphenylsilane
- Packaging5G
- Price$51
- Updated2021-12-16
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- ManufacturerBiosynth Carbosynth
- Product numberFC61180
- Product descriptionChloromethyldimethylphenylsilane
- Packaging10g
- Price$88
- Updated2021-12-16
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- ManufacturerBiosynth Carbosynth
- Product numberFC61180
- Product descriptionChloromethyldimethylphenylsilane
- Packaging25g
- Price$175
- Updated2021-12-16
- Buy
- ManufacturerBiosynth Carbosynth
- Product numberFC61180
- Product descriptionChloromethyldimethylphenylsilane
- Packaging50g
- Price$298
- Updated2021-12-16
- Buy
- ManufacturerBiosynth Carbosynth
- Product numberFC61180
- Product descriptionChloromethyldimethylphenylsilane
- Packaging100g
- Price$507
- Updated2021-12-16
- Buy
- ManufacturerChemenu
- Product numberCM137899
- Product description(Chloromethyl)dimethyl(phenyl)silane 95%
- Packaging100g
- Price$359
- Updated2021-12-16
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- ManufacturerCrysdot
- Product numberCD42000985
- Product description(Chloromethyl)dimethyl(phenyl)silane 95+%
- Packaging100g
- Price$384
- Updated2021-12-16
- Buy
- ManufacturerMatrix Scientific
- Product number098595
- Product description(Chloromethyl)dimethyl(phenyl)silane 95+%
- Packaging5g
- Price$95
- Updated2021-12-16
- Buy
- ManufacturerMatrix Scientific
- Product number098595
- Product description(Chloromethyl)dimethyl(phenyl)silane 95+%
- Packaging10g
- Price$135
- Updated2021-12-16
- Buy
| Manufacturer | Product number | Product description | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|
| AK Scientific | 9605AA | (Chloromethyl)dimethyl(phenyl)silane | 5g | $120 | 2021-12-16 | Buy |
| AK Scientific | 9605AA | (Chloromethyl)dimethyl(phenyl)silane | 25g | $259 | 2021-12-16 | Buy |
| Ambeed | A985316 | (Chloromethyl)dimethyl(phenyl)silane 97% | 250mg | $9 | 2021-12-16 | Buy |
| Ambeed | A985316 | (Chloromethyl)dimethyl(phenyl)silane 97% | 1g | $22 | 2021-12-16 | Buy |
| Ambeed | A985316 | (Chloromethyl)dimethyl(phenyl)silane 97% | 5g | $36 | 2021-12-16 | Buy |
| Ambeed | A985316 | (Chloromethyl)dimethyl(phenyl)silane 97% | 25g | $145 | 2021-12-16 | Buy |
| Ambeed | A985316 | (Chloromethyl)dimethyl(phenyl)silane 97% | 100g | $454 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FC61180 | Chloromethyldimethylphenylsilane | 5G | $51 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FC61180 | Chloromethyldimethylphenylsilane | 10g | $88 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FC61180 | Chloromethyldimethylphenylsilane | 25g | $175 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FC61180 | Chloromethyldimethylphenylsilane | 50g | $298 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FC61180 | Chloromethyldimethylphenylsilane | 100g | $507 | 2021-12-16 | Buy |
| Chemenu | CM137899 | (Chloromethyl)dimethyl(phenyl)silane 95% | 100g | $359 | 2021-12-16 | Buy |
| Crysdot | CD42000985 | (Chloromethyl)dimethyl(phenyl)silane 95+% | 100g | $384 | 2021-12-16 | Buy |
| Matrix Scientific | 098595 | (Chloromethyl)dimethyl(phenyl)silane 95+% | 5g | $95 | 2021-12-16 | Buy |
| Matrix Scientific | 098595 | (Chloromethyl)dimethyl(phenyl)silane 95+% | 10g | $135 | 2021-12-16 | Buy |
Properties
Boiling point :106-107 °C/15 mmHg (lit.)
Density :1.024 g/mL at 25 °C (lit.)
refractive index :n20/D 1.520(lit.)
Flash point :196 °F
storage temp. :2-8°C
form :clear liquid
color :Colorless to Almost colorless
Specific Gravity :1.031
Hydrolytic Sensitivity :4: no reaction with water under neutral conditions
BRN :2935991
CAS DataBase Reference :1833-51-8(CAS DataBase Reference)
EPA Substance Registry System :Silane, (chloromethyl)dimethylphenyl- (1833-51-8)
Density :1.024 g/mL at 25 °C (lit.)
refractive index :n
Flash point :196 °F
storage temp. :2-8°C
form :clear liquid
color :Colorless to Almost colorless
Specific Gravity :1.031
Hydrolytic Sensitivity :4: no reaction with water under neutral conditions
BRN :2935991
CAS DataBase Reference :1833-51-8(CAS DataBase Reference)
EPA Substance Registry System :Silane, (chloromethyl)dimethylphenyl- (1833-51-8)
Safety Information
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Description
The first reported preparation and use of (chloromethyl)dimethylphenylsilane was in 1949.At the time, the main utility of (chloromethyl)dimethylphenylsilane was as the starting material for conversion to the corresponding Grignard reagent (see below). Since then, it has also been used for heteroatom alkylation, carbon alkylation, and conversion to a variety of organometallic and organolanthanide reagents. The main advantage of this reagent over the closely related (chloromethyl)trimethylsilane is the ability of (chloromethyl)dimethylphenylsilane to undergo a Fleming oxidation, thus allowing (chloromethyl)dimethylphenylsilane to serve as a masked hydroxyl group. This utility has been exploited for both the C-substituted and Nsubstituted adducts. A major disadvantage of the use of (chloromethyl)dimethylphenylsilane is its propensity to undergo rearrangements under a variety of conditions (see below). (Chloromethyl) dimethylphenylsilane is used as the precursor for the preparation of (phenyldimethylsilyl)methoxymethyl chloride (SMOM-Cl), a hydroxyl protecting group.(Chloromethyl)dimethylphenylsilane (1) can be utilized to install a silylmethyl group on carbon via base promoted C-alkylation of terminal alkynes,dihydropyrazines,malonic esters,phenylacetonitriles,sulfoxides,and imines.Although has been used directly in the alkylation, conversion to the corresponding iodide via Finkelstein displacement (eq 1) prior to alkylation is sometimeswarranted. Except for the malonic esters (eq 2), strongly basic conditions and lowtemperatures (with slow warming) are generally employed in the transformation (eqs 3 and 4).
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Suppliers and manufacturers
Shanghai Daken Advanced Materials Co.,Ltd
Hangzhou FandaChem Co.,Ltd.
Chongqing Chemdad Co., Ltd
Hubei Co-Formula Material Tech Co., Ltd.
Hefei TNJ Chemical Industry Co.,Ltd.
Dayang Chem (Hangzhou) Co.,Ltd.
Zhejiang J&C Biological Technology Co.,Limited
CD Chemical Group Limited
Labnetwork lnc.
