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Chemical Safety Data Sheet MSDS / SDS

YTTRIUM NITRATE HEXAHYDRATE

Revision Date:2023-11-29Revision Number:1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Product identifier

  • Product name: YTTRIUM NITRATE HEXAHYDRATE
  • CBnumber: CB8706379
  • CAS: 13494-98-9
  • EINECS Number: 677-716-0
  • Synonyms: Yttrium nitrate,Yttrium nitrate hexahydrate

Relevant identified uses of the substance or mixture and uses advised against

  • Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
  • Uses advised against: none

Company Identification

  • Company: Chemicalbook
  • Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
  • Telephone: 400-158-6606

SECTION 2: Hazards identification

GHS Label elements, including precautionary statements

  • Symbol(GHS)
  • Signal wordDanger
Precautionary statements
P405 Store locked up.
P370+P378 In case of fire: Use … for extinction.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P221 Take any precaution to avoid mixing with combustibles/…
P220 Keep/Store away from clothing/…/combustible materials.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
Hazard statements
H335 May cause respiratory irritation
H319 Causes serious eye irritation
H315 Causes skin irritation
H272 May intensify fire; oxidizer

SECTION 3: Composition/information on ingredients

Substance

  • Product name: YTTRIUM NITRATE HEXAHYDRATE
  • Synonyms: Yttrium nitrate,Yttrium nitrate hexahydrate
  • CAS: 13494-98-9
  • EC number: 677-716-0
  • MF: H12N3O15Y
  • MW: 383.01

SECTION 4: First aid measures

Description of first aid measures

General advice
Show this material safety data sheet to the doctor in attendance.
If inhaled
After inhalation: fresh air.
In case of skin contact
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower.
In case of eye contact
After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.
If swallowed
After swallowing: immediately make victim drink water (two glasses at most). Consult a physician.

Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

Indication of any immediate medical attention and special treatment needed

No data available

SECTION 5: Firefighting measures

Extinguishing media

Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the
Unsuitable extinguishing media
For this substance/mixture no limitations of extinguishing agents are given.

Special hazards arising from the substance or mixture

Nitrogen oxides (NOx) Yttrium oxides

Not combustible.

Ambient fire may liberate hazardous vapours.

Advice for firefighters

In the event of fire, wear self-contained breathing apparatus.

Further information

Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.

NFPA 704

1
0
1
OX
HEALTH 1 Exposure would cause irritation with only minor residual injury (e.g. acetone, sodium bromate, potassium chloride)
FIRE 0 Materials that will not burn under typical fire conditions, including intrinsically noncombustible materials such as concrete, stone, and sand. Materials that will not burn in air when exposed to a temperature of 820 °C (1,500 °F) for a period of 5 minutes.(e.g. Carbon tetrachloride)
REACT 1 Normally stable, but can become unstable at elevated temperatures and pressures (e.g. propene)
SPEC. HAZ. OX

SECTION 6: Accidental release measures

Personal precautions, protective equipment and emergency procedures

Advice for non-emergency personnel: Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

For personal protection see section 8.

Environmental precautions

Do not let product enter drains.

Methods and materials for containment and cleaning up

Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts.

Reference to other sections

For disposal see section 13.

SECTION 7: Handling and storage

Precautions for safe handling

For precautions see section 2.2.

Conditions for safe storage, including any incompatibilities

Storage conditions

Tightly closed. Do not store near combustible materials. Hygroscopic.

Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

SECTION 8: Exposure controls/personal protection

control parameter

Hazard composition and occupational exposure limits
Does not contain substances with occupational exposure limits.

Exposure controls

Personal protective equipment
Eye/face protection

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles

Skin protection

This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Full contact

Material: Nitrile rubber

Minimum layer thickness: 0,11 mm Break through time: 480 min

Material tested:KCL 741 Dermatril? L

Splash contact Material: Nitrile rubber

Minimum layer thickness: 0,11 mm Break through time: 480 min

Material tested:KCL 741 Dermatril? L

Body Protection

protective clothing

Respiratory protection

required when dusts are generated.

Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.

Recommended Filter type: Filter type P2

The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer.

These measures have to be properly documented.

Control of environmental exposure

Do not let product enter drains.

SECTION 9: Physical and chemical properties

Information on basic physicochemical properties

  • Appearance Crystals with lumps
  • OdourNo data available
  • Odour ThresholdNo data available
  • pH3.5 (50g/l, H2O, 20℃)
  • Melting point/freezing point51.8°C
  • Initial boiling point and boiling rangeNo data available
  • Flash pointNot applicable
  • Evaporation rateNo data available
  • Flammability (solid, gas)No data available
  • Upper/lower flammability or explosive limitsNo data available
  • Vapour pressure No data available
  • Vapour density No data available
  • Relative densityNo data available
  • Water solubility2304g/l
  • Partition coefficient: n-octanol/waterNot applicable for inorganic substances
  • Autoignition temperatureNo data available
  • Decomposition temperatureNo data available
  • ViscosityViscosity, kinematic: No data available Viscosity, dynamic: No data available
  • Explosive propertiesNo data available
  • Oxidizing propertiesNo data available

Other safety information

No data available

SECTION 10: Stability and reactivity

Reactivity

No data available

Chemical stability

The product is chemically stable under standard ambient conditions (room temperature) .

Possibility of hazardous reactions

Risk of ignition or formation of inflammable gases or vapours with:

Reducing agents oxidisable substances

organic combustible substances alkalines

Strong acids Cyanides Isocyanates


Conditions to avoid

no information available

Incompatible materials

Organic materials, Powdered metals

Hazardous decomposition products

In the event of fire: see section 5

SECTION 11: Toxicological information

Information on toxicological effects

Acute toxicity
LD50 Oral - Rat - male and female - 1.650 mg/kg (OECD Test Guideline 401)
Remarks: (anhydrous substance)
The value is given in analogy to the following substances: Yttrium(III) nitrate Inhalation: Irritating to respiratory system.
Symptoms: Possible damages:, mucosal irritations, bronchitis LD50 Dermal - Rat - male and female - > 2.000 mg/kg (OECD Test Guideline 402)
Remarks: (anhydrous substance)
The value is given in analogy to the following substances: Yttrium(III) nitrate
Skin corrosion/irritation
Skin - Rabbit
Result: No skin irritation - 24 h (OECD Test Guideline 404) Remarks: (anhydrous substance)
The value is given in analogy to the following substances: Yttrium(III) nitrate
Serious eye damage/eye irritation
Eyes - Rabbit
Result: Causes serious eye damage. (OECD Test Guideline 405) Remarks: (anhydrous substance)
The value is given in analogy to the following substances: Yttrium(III) nitrate
Respiratory or skin sensitization
(OECD Test Guideline 406) Remarks: (anhydrous substance)
The value is given in analogy to the following substances: Yttrium(III) nitrate
Germ cell mutagenicity
No data available Test Type: Ames test
Test system: Escherichia coli/Salmonella typhimurium Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471
Result: negative
Remarks: (anhydrous substance)
The value is given in analogy to the following substances: Yttrium(III) nitrateTest Type: In vitro mammalian cell gene mutation test
Test system: mouse lymphoma cells
Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 476
Result: negative
Remarks: (anhydrous substance)
The value is given in analogy to the following substances: Yttrium(III) nitrateTest Type: Chromosome aberration test in vitro
Test system: Chinese hamster ovary cells
Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 473
Result: negative
Remarks: (anhydrous substance)
The value is given in analogy to the following substances: Yttrium(III) nitrate
No data available
Reproductive toxicity
No data available
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
Toxicity
LD50 orally in Rabbit: 3890 mg/kg

SECTION 12: Ecological information

Toxicity

Toxicity to fish
semi-static test LC50 - Oncorhynchus mykiss (rainbow trout) - 0,62 mg/l - 96 h

(OECD Test Guideline 203) Remarks: (anhydrous substance)

The value is given in analogy to the following substances: Yttrium(III) nitrate


Toxicity to daphnia and other aquatic invertebrates

static test EC50 - Daphnia magna (Water flea) - > 100 mg/l - 48 h (Regulation (EC) No. 440/2008, Annex, C.2)

Remarks: (anhydrous substance)

The value is given in analogy to the following substances: Yttrium(III) nitrate


Toxicity to bacteria
static test EC50 - activated sludge - 470 mg/l - 3 h (OECD Test Guideline 209)

Remarks: (anhydrous substance)

The value is given in analogy to the following substances: Yttrium(III) nitrate


Persistence and degradability

The methods for determining the biological degradability are not applicable to inorganic substances.

Bioaccumulative potential

No data available

Mobility in soil

No data available

Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Other adverse effects

Depending on the concentration, phosphorus and/or nitrogen compounds may contribute to the eutrophication of drinking- water supplies.

Discharge into the environment must be avoided.

SECTION 13: Disposal considerations

Waste treatment methods

Product

See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.

SECTION 14: Transport information

UN number

ADR/RID: 1477 IMDG: 1477 IATA: 1477

UN proper shipping name


ADR/RID: NITRATES, INORGANIC, N.O.S. IMDG: NITRATES, INORGANIC, N.O.S.


IATA: Nitrates, inorganic, n.o.s.

14.3

Transport hazard class(es)

ADR/RID: 5.1 IMDG: 5.1


IATA: 5.1

14.4

Packaging group

ADR/RID: II IMDG: II


IATA: II

14.5

Environmental hazards

ADR/RID: no IMDG Marine pollutant: no


IATA: no

14.6

Special precautions for user

No data available


SECTION 15: Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or mixture

Regulations on the Safety Management of Hazardous Chemicals
China Catalog of Hazardous chemicals 2015:Listed. website: https://www.mem.gov.cn/
Measures for Environmental Management of New Chemical Substances
Philippines Inventory of Chemicals and Chemical Substances (PICCS):Not Listed. website: https://emb.gov.ph/
United States Toxic Substances Control Act (TSCA) Inventory:Not Listed. website: https://www.epa.gov/
Vietnam National Chemical Inventory:Listed. website: https://chemicaldata.gov.vn/
New Zealand Inventory of Chemicals (NZIoC):Listed. website: https://www.epa.govt.nz/
Korea Existing Chemicals List (KECL):Not Listed. website: http://ncis.nier.go.kr
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC):Listed. website: https://www.mee.gov.cn/
European Inventory of Existing Commercial Chemical Substances (EINECS):Not Listed. website: https://echa.europa.eu/
EC Inventory:Not Listed.

SECTION 16: Other information

Abbreviations and acronyms

  • CAS: Chemical Abstracts Service
  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
  • IMDG: International Maritime Dangerous Goods
  • IATA: International Air Transportation Association
  • TWA: Time Weighted Average
  • STEL: Short term exposure limit
  • LC50: Lethal Concentration 50%
  • LD50: Lethal Dose 50%
  • EC50: Effective Concentration 50%

References

【1】CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple

【2】ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp

【3】ECHA - European Chemicals Agency, website: https://echa.europa.eu/

【4】eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en

【5】ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg

【6】Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp

【7】HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm

【8】IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/

【9】IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home

【10】Sigma-Aldrich, website: https://www.sigmaaldrich.com/

Disclaimer:

The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.

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