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    Chemical Safety Data Sheet MSDS / SDS

    Silicon dioxide

    Revision Date:2024-11-02Revision Number:1

    SECTION 1: Identification of the substance/mixture and of the company/undertaking

    Product identifier

    • Product name: Silicon dioxide
    • CBnumber: CB8138262
    • CAS: 7631-86-9
    • EINECS Number: 231-545-4
    • Synonyms: Silicon dioxide,Aerosil

    Relevant identified uses of the substance or mixture and uses advised against

    • Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
    • Uses advised against: none

    Company Identification

    • Company: Chemicalbook
    • Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
    • Telephone: 400-158-6606

    SECTION 2: Hazards identification

    GHS Label elements, including precautionary statements

    • Symbol(GHS)
    • Signal wordWarning
    Precautionary statements
    P201 Obtain special instructions before use.
    P260 Do not breathe dust/fume/gas/mist/vapours/spray.
    P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
    P264 Wash hands thoroughly after handling.
    P264 Wash skin thouroughly after handling.
    P280 Wear protective gloves/protective clothing/eye protection/face protection.
    P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
    P308+P313 IF exposed or concerned: Get medical advice/attention.
    P314 Get medical advice/attention if you feel unwell.
    P333+P313 IF SKIN irritation or rash occurs: Get medical advice/attention.
    P405 Store locked up.
    Hazard statements
    H317 May cause an allergic skin reaction
    H319 Causes serious eye irritation
    H320 Causes eye irritation
    H335 May cause respiratory irritation
    H350 May cause cancer
    H360 May damage fertility or the unborn child
    H373 May cause damage to organs through prolonged or repeated exposure
    H401 Toxic to aquatic life
    H402 Harmful to aquatic life
    H411 Toxic to aquatic life with long lasting effects

    SECTION 3: Composition/information on ingredients

    Substance

    • Product name: Silicon dioxide
    • Synonyms: Silicon dioxide,Aerosil
    • CAS: 7631-86-9
    • EC number: 231-545-4
    • MF: O2Si
    • MW: 60.08

    SECTION 4: First aid measures

    Description of first aid measures

    If inhaled
    If breathed in, move person into fresh air. If not breathing, give artificial respiration.
    In case of skin contact
    Wash off with soap and plenty of water.
    In case of eye contact
    Flush eyes with water as a precaution.
    If swallowed
    Never give anything by mouth to an unconscious person. Rinse mouth with water.

    Most important symptoms and effects, both acute and delayed

    The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

    Indication of any immediate medical attention and special treatment needed

    No data available

    SECTION 5: Firefighting measures

    Extinguishing media

    Suitable extinguishing media
    Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

    Special hazards arising from the substance or mixture

    silicon oxides Not combustible.

    Advice for firefighters

    Wear self-contained breathing apparatus for firefighting if necessary.

    Further information

    No data available

    NFPA 704

    2
    1
    0
    HEALTH 2 Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury (e.g. diethyl ether, ammonium phosphate, iodine)
    FIRE 1 Materials that require considerable preheating, under all ambient temperature conditions, before ignition and combustion can occur. Includes some finely divided suspended solids that do not require heating before ignition can occur. Flash point at or above 93.3 °C (200 °F). (e.g. mineral oil, ammonia)
    REACT 0 Normally stable, even under fire exposure conditions, and is not reactive with water (e.g. helium,N2)
    SPEC. HAZ.

    SECTION 6: Accidental release measures

    Personal precautions, protective equipment and emergency procedures

    Avoid breathing vapors, mist or gas. For personal protection see section 8.

    Environmental precautions

    No special environmental precautions required.

    Methods and materials for containment and cleaning up

    Keep in suitable, closed containers for disposal.

    Reference to other sections

    For disposal see section 13.

    SECTION 7: Handling and storage

    Precautions for safe handling

    For precautions see section 2.2.

    Conditions for safe storage, including any incompatibilities

    Storage conditions

    Keep container tightly closed in a dry and well-ventilated place. Store in cool place.

    Specific end use(s)

    Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

    SECTION 8: Exposure controls/personal protection

    control parameter

    Hazard composition and occupational exposure limits
    Does not contain substances with occupational exposure limits.

    Exposure controls

    Personal protective equipment
    Eye/face protection

    Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

    Skin protection

    Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

    The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.

    Body Protection

    Impervious clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

    Respiratory protection

    Respiratory protection not required. For nuisance exposures use type OV/AG (US) or type ABEK (EU EN 14387) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

    Control of environmental exposure

    No special environmental precautions required.

    SECTION 9: Physical and chemical properties

    Information on basic physicochemical properties

    • Appearance liquid
    • OdourNo data available
    • Odour ThresholdNo data available
    • pH5-8 (100g/l, H2O, 20℃)(slurry)
    • Melting point/freezing point>1600 °C(lit.)
    • Initial boiling point and boiling range>100 °C(lit.)
    • Flash point2230°C
    • Evaporation rateNo data available
    • Flammability (solid, gas)No data available
    • Upper/lower flammability or explosive limitsNo data available
    • Vapour pressure No data available
    • Vapour density No data available
    • Relative density1.29
    • Water solubilityPractically insoluble in water and in mineral acids except hydrofluoric acid. It dissolves in hot solutions of alkali hydroxides.
    • Partition coefficient: n-octanol/waterNo data available
    • Autoignition temperatureNo data available
    • Decomposition temperatureNo data available
    • ViscosityViscosity, kinematic: No data available Viscosity, dynamic: No data available
    • Explosive propertiesNo data available
    • Oxidizing propertiesNo data available

    Other safety information

    No data available

    SECTION 10: Stability and reactivity

    Reactivity

    No data available

    Chemical stability

    Stable under recommended storage conditions.

    Possibility of hazardous reactions

    No data available

    Conditions to avoid

    No data available

    Incompatible materials

    Strong oxidizing agents

    Hazardous decomposition products

    In the event of fire: see section 5

    SECTION 11: Toxicological information

    Information on toxicological effects

    Acute toxicity
    No data available
    Skin corrosion/irritation
    No data available
    Serious eye damage/eye irritation
    No data available
    Respiratory or skin sensitization
    No data available
    Germ cell mutagenicity
    No data available
    Carcinogenicity
    No data available
    Reproductive toxicity
    No data available
    Specific target organ toxicity - single exposure
    No data available
    No data available
    Aspiration hazard
    No data available
    Toxicity
    LC inhalation in rat: > 200gm/m3/1H

    SECTION 12: Ecological information

    Toxicity

    Mixture

    No data available

    Persistence and degradability

    No data available

    Bioaccumulative potential

    No data available

    Mobility in soil

    No data available

    Results of PBT and vPvB assessment

    This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

    Other adverse effects

    No data available

    SECTION 13: Disposal considerations

    Waste treatment methods

    Product

    Offer surplus and non-recyclable solutions to a licensed disposal company.

    Incompatibilities

    Silica, amorphous is a noncombustible solid. Generally unreactive chemically. Incompatible with fluorine, oxygen difluoride, chlorine trifluoride. Soluble in molten alkalis and reacts with most metallic oxides at high temperature.

    Waste Disposal

    Sanitary landfill.

    Contaminated packaging

    Dispose of as unused product.

    SECTION 14: Transport information

    UN number

    ADR/RID: - IMDG: - IATA: -

    UN proper shipping name

    ADR/RID: Not dangerous goods IMDG: Not dangerous goods IATA: Not dangerous goods

    Transport hazard class(es)

    ADR/RID: - IMDG: - IATA: -

    Packaging group

    ADR/RID: - IMDG: - IATA: -

    Environmental hazards

    ADR/RID: no IMDG Marine pollutant: no IATA: no

    Special precautions for user

    Further information

    Not classified as dangerous in the meaning of transport regulations.

    SECTION 15: Regulatory information

    Safety, health and environmental regulations/legislation specific for the substance or mixture

    Regulations on the Safety Management of Hazardous Chemicals
    China Catalog of Hazardous chemicals 2015:Not Listed. website: https://www.mem.gov.cn/
    Measures for Environmental Management of New Chemical Substances
    Chinese Chemical Inventory of Existing Chemical Substances (China IECSC):Listed. website: https://www.mee.gov.cn/
    EC Inventory:Listed.
    European Inventory of Existing Commercial Chemical Substances (EINECS):Listed. website: https://echa.europa.eu/
    Korea Existing Chemicals List (KECL):Listed. website: http://ncis.nier.go.kr
    New Zealand Inventory of Chemicals (NZIoC):Listed. website: https://www.epa.govt.nz/
    Philippines Inventory of Chemicals and Chemical Substances (PICCS):Listed. website: https://emb.gov.ph/
    United States Toxic Substances Control Act (TSCA) Inventory:Listed. website: https://www.epa.gov/
    Vietnam National Chemical Inventory:Listed. website: https://chemicaldata.gov.vn/

    SECTION 16: Other information

    Abbreviations and acronyms

    • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
    • CAS: Chemical Abstracts Service
    • EC50: Effective Concentration 50%
    • IATA: International Air Transportation Association
    • IMDG: International Maritime Dangerous Goods
    • LC50: Lethal Concentration 50%
    • LD50: Lethal Dose 50%
    • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
    • STEL: Short term exposure limit
    • TWA: Time Weighted Average

    References

    【1】CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple

    【2】ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp

    【3】ECHA - European Chemicals Agency, website: https://echa.europa.eu/

    【4】eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en

    【5】ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg

    【6】Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp

    【7】HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm

    【8】IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/

    【9】IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home

    【10】Sigma-Aldrich, website: https://www.sigmaaldrich.com/

    Disclaimer:

    The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.

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