Oxidizing solids, Category 2

Acute toxicity - Category 4, Oral

Skin corrosion, Sub-category 1B

Hazardous to the aquatic environment, short-term (Acute) - Category Acute 1

H272 May intensify fire; oxidizer

H302 Harmful if swallowed

H314 Causes severe skin burns and eye damage

H400 Very toxic to aquatic life

P220 Keep/Store away from clothing/…/combustible materials.

P221 Take any precaution to avoid mixing with combustibles/…

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P310 Immediately call a POISON CENTER or doctor/physician.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405 Store locked up.

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P220 Keep away from clothing and other combustible materials.

P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...

P264 Wash ... thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P273 Avoid release to the environment.

P370+P378 In case of fire: Use ... to extinguish.

P301+P317 IF SWALLOWED: Get medical help.

P330 Rinse mouth.

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P363 Wash contaminated clothing before reuse.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P316 Get emergency medical help immediately.

P321 Specific treatment (see ... on this label).

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P391 Collect spillage.

P405 Store locked up.

P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

no data available

Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention.

Remove contaminated clothes. Rinse skin with plenty of water or shower.

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Rinse mouth. Give one or two glasses of water to drink. Do NOT induce vomiting. Refer for medical attention .

Excerpt from ERG Guide 140 [Oxidizers]: Inhalation, ingestion or contact (skin, eyes) with vapors or substance may cause severe injury, burns or death. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may cause pollution. (ERG, 2016)

Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR as necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. Hypochlorite and Related Compounds

If material involved in fire: Extinguish using agent suitable for type of surrounding fire. (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog. Cool all affected containers with flooding quantities of water. Apply water from as far a distance as possible. Chlorinated lime, liquid

Excerpt from ERG Guide 140 [Oxidizers]: These substances will accelerate burning when involved in a fire. Some may decompose explosively when heated or involved in a fire. May explode from heat or contamination. Some will react explosively with hydrocarbons (fuels). May ignite combustibles (wood, paper, oil, clothing, etc.). Containers may explode when heated. Runoff may create fire or explosion hazard. (ERG, 2016)

NO powder. Use water in large amounts. In case of fire: keep drums, etc., cool by spraying with water.

Personal protection: chemical protection suit, face shield and filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered air-tight, dry containers. Then store and dispose of according to local regulations.

Personal protection: chemical protection suit, face shield and filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered air-tight, dry containers. Then store and dispose of according to local regulations.

Personal protection: chemical protection suit, face shield and filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered air-tight, dry containers. Then store and dispose of according to local regulations.

NO contact with combustible substances or reducing agents. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

Well closed. Store in an area without drain or sewer access. Separated from food and feedstuffs. See Chemical Dangers.Store in a cool, dry, well-ventilated location at a temperature below 120 deg F (50 deg C) to avoid slow decomposition. Separate from oxidizing materils, acids, ammonia, amines, and other chlorinating agents. Immediately remove and properly dispose of any spilled material. Calcium hypochlorite, dry or calcium hypochlorite, mixtures, dry

no data available

no data available

Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.

Wear face shield or eye protection in combination with breathing protection.

Protective gloves. Protective clothing.

Use local exhaust or breathing protection.

no data available

Decomposes rapidly above 175°C . Decomposes rapidly on contact with acids. This produces chlorine and oxygen. This generates fire and explosion hazard. The substance is a strong oxidant. It reacts violently with combustible and reducing materials. The solution in water is a medium strong base. Reacts violently with ammonia, amines, nitrogen compounds and many other substances. This generates explosion hazard. Attacks many metals. This produces flammable/explosive gas (hydrogen - see ICSC 0001). Attacks plastics.

All hypochlorite soln are unstable, esp if acidified; slowly decomp on contact with air hypochlorite soln

Contact with combustible materials will increase fire hazard. May undergo accelerated decomposition with release of heat above 350 deg F (177 deg C). /Calcium hypochlorite, dry, or calcium hypochlorite, mixtures, dry/CALCIUM HYPOCHLORITE is a powerful oxidizing agent, particularly in the presence of water or as it decomposes when heated to release oxygen and chlorine gases. May react vigorously with carbon; reacts potentially explosively with finely divided carbon. Reacts with acetylene to form explosive chloroacetylenes. Reactions with organic matter, oil, hydrocarbons; alcohols may lead to explosions. Reactions with nitromethane, methanol, ethanol (and other alcohols) can become violent after a delay. Reacts with possible ignition and/or explosion with organic sulfur compounds and with sulfides. Decomposes evolving oxygen, a change that can be catalyzed by rust on metal containers. Forms highly explosive NCl3 on contact with urea or ammonia. Evolves highly toxic gaseous chlorine gas when heated or on contact with acids [Sax, 9th ed., 1996, p. 1905]. A mixture with damp sulfur reacted violently, and molten sulfur was ejected [Chem Eng. News, 1965, 46(29), 6]. The combination of calcium hypochlorite, sodium hydrogen sulfate, starch, and sodium carbonate, when compressed, caused the materials to incandescence, followed by explosion, [Ind. Eng. Chem., 1937, 15, 282].

no data available

Reacts with water and with acids releasing chlorine. Forms explosive compounds with ammonia and amines. Strong oxidizer. Other incompatible materials include organics, nitrogen containing compounds, dry chemical fire extinguishers containing mono-ammonium phosphate, combustible or flammable materials. Calcium hypochlorite, dry or calcium hypochlorite, mixtures, dry

The 70% grade may decomp violently if exposed to heat or direct sunlight. Gives off chlorine and chlorine monoxide above 350 deg F (poisonous gases).

no data available

no data available

no data available

no data available

Evaluation: There is inadequate evidence for the carcinogenicity of hypochlorite salts in experimental animals. No data were available from studies in humans on the carcinogenicity of hypochlorite salts. Overall evaluation: Hypochlorite salts are not classifiable as to their carcinogenicity to humans (Group 3). Hypochlorite salts

no data available

The substance is corrosive to the eyes, skin and respiratory tract. Corrosive on ingestion. Inhalation of decomposition products may cause lung oedema. See Notes. The effects may be delayed. Medical observation is indicated.

no data available

A harmful concentration of airborne particles can be reached quickly when dispersed, especially if powdered.

no data available

no data available

no data available

no data available

The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

ADR/RID: UN1748 (For reference only, please check.)

IMDG: UN1748 (For reference only, please check.)

IATA: UN1748 (For reference only, please check.)

ADR/RID: CALCIUM HYPOCHLORITE, DRY or CALCIUM HYPOCHLORITE MIXTURE, DRY with more than 39% available chlorine (8.8% available oxygen) (For reference only, please check.)

IMDG: CALCIUM HYPOCHLORITE, DRY or CALCIUM HYPOCHLORITE MIXTURE, DRY with more than 39% available chlorine (8.8% available oxygen) (For reference only, please check.)

IATA: CALCIUM HYPOCHLORITE, DRY or CALCIUM HYPOCHLORITE MIXTURE, DRY with more than 39% available chlorine (8.8% available oxygen) (For reference only, please check.)

ADR/RID: 5.1 (For reference only, please check.)

IMDG: 5.1 (For reference only, please check.)

IATA: 5.1 (For reference only, please check.)

ADR/RID: II (For reference only, please check.)

IMDG: II (For reference only, please check.)

IATA: II (For reference only, please check.)

ADR/RID: Yes

IMDG: Yes

IATA: Yes

no data available

no data available

Rinse contaminated clothing with plenty of water because of fire hazard.The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort.Rest and medical observation is therefore essential.Immediate administration of an appropriate inhalation therapy by a doctor or a person authorized by him/her, should be considered.