1,3-Dichloro-1,3,5-triazine-2,4,6(1H,3H,5H)-trione sodium salt dihydrate
Product identifier
- Product name: 1,3-Dichloro-1,3,5-triazine-2,4,6(1H,3H,5H)-trione sodium salt dihydrate
- CBnumber: CB5315444
- CAS: 51580-86-0
- EINECS Number: 610-700-3
- Synonyms: sodium dichloroisocyanurate dihydrate,Troclosene sodium
Relevant identified uses of the substance or mixture and uses advised against
- Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
- Uses advised against: none
Company Identification
- Company: Chemicalbook
- Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
- Telephone: 400-158-6606
GHS Label elements, including precautionary statements
-
Symbol(GHS)
- Signal wordWarning
Substance
- Product name: 1,3-Dichloro-1,3,5-triazine-2,4,6(1H,3H,5H)-trione sodium salt dihydrate
- Synonyms: sodium dichloroisocyanurate dihydrate,Troclosene sodium
- CAS: 51580-86-0
- EC number: 610-700-3
- MF: C3H4Cl2N3NaO4
- MW: 239.97
Description of first aid measures
General adviceMost important symptoms and effects, both acute and delayed
Indication of any immediate medical attention and special treatment needed
Extinguishing media
Suitable extinguishing mediaSpecial hazards arising from the substance or mixture
Carbon oxides Nitrogen oxides (NOx) Hydrogen chloride gas Sodium oxides
Not combustible.
Avoid shock and friction. Risk of dust explosion.
Ambient fire may liberate hazardous vapours.
In the event of decomposition: danger of explosion!
Advice for firefighters
In the event of fire, wear self-contained breathing apparatus.
Further information
Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.
Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel: Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.
For personal protection see section 8.
Environmental precautions
Do not let product enter drains.
Methods and materials for containment and cleaning up
Sweep up and shovel. Do not flush with water. Keep in suitable, closed containers for disposal.Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts.
Reference to other sections
For disposal see section 13.
Precautions for safe handling
Advice on protection against fire and explosion
Keep away from open flames, hot surfaces and sources of ignition.
Hygiene measures
Change contaminated clothing. Preventive skin protection recommended. Wash hands after working with substance.
For precautions see section 2.2.
Conditions for safe storage, including any incompatibilities
Storage conditions
Tightly closed. Dry.
Do not store near acids.
Store under inert gas. Moisture sensitive.
Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
control parameter
Hazard composition and occupational exposure limitsExposure controls
Personal protective equipmentUse equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).
Full contact
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm Break through time: 480 min
Material tested:KCL 741 Dermatril? L
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).
Splash contact Material: Nitrile rubber
Minimum layer thickness: 0,11 mm
Break through time: 480 min
Material tested:KCL 741 Dermatril? L
protective clothing
required when dusts are generated.
Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.
Recommended Filter type: Filter type P2
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer.
These measures have to be properly documented.
Do not let product enter drains.
Information on basic physicochemical properties
- Appearancewhite solid
- Odourweakly of hydrochloric acid
- Odour ThresholdNo data available
- pH6 at 10 g/l at 20 °C
- Melting point/freezing pointMelting point/range: 240 - 250 °C
- Initial boiling point and boiling rangeNo data available
- Flash pointNo data available
- Evaporation rateNo data available
- Flammability (solid, gas)The product is not flammable. - Flammability (solids)
- Upper/lower flammability or explosive limitsNo data available
- Vapour pressure< 0,006 hPa at 20 °C - (anhydrous substance)
- Vapour density No data available
- Relative densityNo data available
- Water solubility236,8 g/l at 25 °C - US-EPA- completely soluble
- Partition coefficient: n-octanol/waterNo data available
- Autoignition temperatureNo data available
- Decomposition temperature240 °C - (anhydrous)
- ViscosityViscosity, kinematic: No data available Viscosity, dynamic: No data available
- Explosive propertiesExplosive when dry., Risk of explosion if heated under confinement.
- Oxidizing propertiesNo data available
Other safety information
No data available
Reactivity
sensitive to shock sensitive to shock
Contact with acids liberates toxic gas.
Chemical stability
The product is chemically stable under standard ambient conditions (room temperature) .
Possibility of hazardous reactions
Risk of ignition or formation of inflammable gases or vapours with: combustible substances
Organic Substances
A risk of explosion and/or of toxic gas formation exists with the following substances:
Ammonia urea
ammonium compounds Bases
acids
Generates dangerous gases or fumes in contact with: Acids
Generates dangerous gases or fumes in contact with: Acids
Conditions to avoid
no information available
Strong heating (decomposition).
Incompatible materials
No data available
Hazardous decomposition products
In the event of fire: see section 5
Information on toxicological effects
Acute toxicityLC50 Inhalation - Rat - male and female - 4 h - 0,27 - 1,17 mg/l (OECD Test Guideline 403)
Inhalation: Irritating to respiratory system.
LD50 Dermal - Rat - male and female - > 5.000 mg/kg (US-EPA)
Test system: Escherichia coli/Salmonella typhimurium Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471
Result: negative
Test Type: sister chromatid exchange assay Test system: Chinese hamster ovary cells
Metabolic activation: with and without metabolic activation Method: Regulation (EC) No. 440/2008, Annex, B.19 Result: negative
Test Type: In vitro mammalian cell gene mutation test Test system: mouse lymphoma cells
Metabolic activation: with and without metabolic activation Method: Regulation (EC) No. 440/2008, Annex, B.17 Result: negative
Test Type: Mutagenicity (mammal cell test): chromosome aberration. Species: Rat
Cell type: Bone marrow Application Route: Oral
Method: OECD Test Guideline 475 Result: negative
Toxicity
(US-EPA)
static test EC50 - Daphnia magna (Water flea) - > 1.000 mg/l - 48 h Remarks: (ECHA)
(OECD Test Guideline 209)
Persistence and degradability
Biodegradability aerobic - Exposure time 8 h
Result: 100 % - Readily biodegradable. Remarks: (ECHA)
Bioaccumulative potential
No data available
Mobility in soil
No data available
Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Other adverse effects
No data available
Waste treatment methods
Product
See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.
UN number
ADR/RID: 3077 IMDG: 3077 IATA: 3077
UN proper shipping name
ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (troclosene
sodium, dihydrate)
IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (troclosene
sodium, dihydrate)
IATA: Environmentally hazardous substance, solid, n.o.s. (troclosene sodium, dihydrate)
Transport hazard class(es)
ADR/RID: 9 IMDG: 9 IATA: 9
Packaging group
ADR/RID: III IMDG: III IATA: III
Environmental hazards
ADR/RID: yes IMDG Marine pollutant: yes IATA: yes
Special precautions for user
Further information
EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids.Packages smaller than or equal to 5 kg / L , not dangerous goods of Class 9
Safety, health and environmental regulations/legislation specific for the substance or mixture
Regulations on the Safety Management of Hazardous ChemicalsAbbreviations and acronyms
- ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
- CAS: Chemical Abstracts Service
- EC50: Effective Concentration 50%
- IATA: International Air Transportation Association
- IMDG: International Maritime Dangerous Goods
- LC50: Lethal Concentration 50%
- LD50: Lethal Dose 50%
- RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
- STEL: Short term exposure limit
- TWA: Time Weighted Average
References
【1】CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
【2】ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
【3】ECHA - European Chemicals Agency, website: https://echa.europa.eu/
【4】eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
【5】ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
【6】Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
【7】HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
【8】IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
【9】IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
【10】Sigma-Aldrich, website: https://www.sigmaaldrich.com/
The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.