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      Chemical Safety Data Sheet MSDS / SDS

      2,3-DIHYDROXYBENZONITRILE

      Revision Date:2022-12-31Revision Number:1

      SECTION 1: Identification of the substance/mixture and of the company/undertaking

      Product identifier

      • Product name: 2,3-DIHYDROXYBENZONITRILE
      • CBnumber: CB8742722
      • CAS: 67984-81-0
      • EINECS Number: 268-005-2
      • Synonyms: 2,3-dihydroxybenzonitrile

      Relevant identified uses of the substance or mixture and uses advised against

      • Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
      • Uses advised against: none

      Company Identification

      • Company: Chemicalbook
      • Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
      • Telephone: 400-158-6606

      SECTION 2: Hazards identification

      Classification of the substance or mixture

      Acute toxicity - Category 4, Oral

      Skin irritation, Category 2

      Eye irritation, Category 2

      Specific target organ toxicity – single exposure, Category 3

      Label elements

      Pictogram(s)
      • Signal word

        Warning

      Hazard statement(s)

      H302 Harmful if swallowed

      H315 Causes skin irritation

      H319 Causes serious eye irritation

      H335 May cause respiratory irritation

      Precautionary statement(s)
      Prevention

      P264 Wash ... thoroughly after handling.

      P270 Do not eat, drink or smoke when using this product.

      P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...

      P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

      P271 Use only outdoors or in a well-ventilated area.

      Response

      P301+P317 IF SWALLOWED: Get medical help.

      P330 Rinse mouth.

      P302+P352 IF ON SKIN: Wash with plenty of water/...

      P321 Specific treatment (see ... on this label).

      P332+P317 If skin irritation occurs: Get medical help.

      P362+P364 Take off contaminated clothing and wash it before reuse.

      P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

      P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

      P319 Get medical help if you feel unwell.

      Storage

      P403+P233 Store in a well-ventilated place. Keep container tightly closed.

      P405 Store locked up.

      Disposal

      P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

      Other hazards

      no data available

      SECTION 3: Composition/information on ingredients

      Substance

      • Product name: 2,3-DIHYDROXYBENZONITRILE
      • Synonyms: 2,3-dihydroxybenzonitrile
      • CAS: 67984-81-0
      • EC number: 268-005-2
      • MF: C7H5NO2
      • MW: 135.12

      SECTION 4: First aid measures

      Description of first aid measures

      If inhaled

      Move the victim into fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration and consult a doctor immediately. Do not use mouth to mouth resuscitation if the victim ingested or inhaled the chemical.

      Following skin contact

      Take off contaminated clothing immediately. Wash off with soap and plenty of water. Consult a doctor.

      Following eye contact

      Rinse with pure water for at least 15 minutes. Consult a doctor.

      Following ingestion

      Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.

      Most important symptoms and effects, both acute and delayed

      no data available

      Indication of any immediate medical attention and special treatment needed

      no data available

      SECTION 5: Firefighting measures

      Extinguishing media

      Use dry chemical, carbon dioxide or alcohol-resistant foam.

      Specific Hazards Arising from the Chemical

      no data available

      Advice for firefighters

      Wear self-contained breathing apparatus for firefighting if necessary.

      SECTION 6: Accidental release measures

      Personal precautions, protective equipment and emergency procedures

      Avoid dust formation. Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. Use personal protective equipment.Wear chemical impermeable gloves. Ensure adequate ventilation.Remove all sources of ignition. Evacuate personnel to safe areas.Keep people away from and upwind of spill/leak.

      Environmental precautions

      Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.

      Methods and materials for containment and cleaning up

      Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.

      SECTION 7: Handling and storage

      Precautions for safe handling

      Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

      Conditions for safe storage, including any incompatibilities

      Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials.

      SECTION 8: Exposure controls/personal protection

      Control parameters

      Occupational Exposure limit values

      no data available

      Biological limit values

      no data available

      Exposure controls

      Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.

      Individual protection measures

      Eye/face protection

      Wear tightly fitting safety goggles with side-shields conforming to EN 166(EU) or NIOSH (US).

      Skin protection

      Wear fire/flame resistant and impervious clothing. Handle with gloves. Gloves must be inspected prior to use. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

      Respiratory protection

      If the exposure limits are exceeded, irritation or other symptoms are experienced, use a full-face respirator.

      Thermal hazards

      no data available

      SECTION 9: Physical and chemical properties

      Information on basic physicochemical properties

      • Physical state

        no data available

      • Colour

        no data available

      • Odour

        no data available

      • Melting point/freezing point

        no data available

      • Boiling point or initial boiling point and boiling range

        305.2°C at 760 mmHg

      • Flammability

        no data available

      • Lower and upper explosion limit/flammability limit

        no data available

      • Flash point

        138.4°C

      • Auto-ignition temperature

        no data available

      • Decomposition temperature

        no data available

      • pH

        no data available

      • Kinematic viscosity

        no data available

      • Solubility

        no data available

      • Partition coefficient n-octanol/water

        no data available

      • Vapour pressure

        no data available

      • Density and/or relative density

        1.42g/cm3

      • Relative vapour density

        no data available

      • Particle characteristics

        no data available

      SECTION 10: Stability and reactivity

      Reactivity

      no data available

      Chemical stability

      no data available

      Possibility of hazardous reactions

      no data available

      Conditions to avoid

      no data available

      Incompatible materials

      no data available

      Hazardous decomposition products

      no data available

      SECTION 11: Toxicological information

      Acute toxicity

      • Oral: no data available
      • Inhalation: no data available
      • Dermal: no data available

      Skin corrosion/irritation

      no data available

      Serious eye damage/irritation

      no data available

      Respiratory or skin sensitization

      no data available

      Germ cell mutagenicity

      no data available

      Carcinogenicity

      no data available

      Reproductive toxicity

      no data available

      STOT-single exposure

      no data available

      STOT-repeated exposure

      no data available

      Aspiration hazard

      no data available

      SECTION 12: Ecological information

      Toxicity

      • Toxicity to fish: no data available
      • Toxicity to daphnia and other aquatic invertebrates: no data available
      • Toxicity to algae: no data available
      • Toxicity to microorganisms: no data available

      Persistence and degradability

      no data available

      Bioaccumulative potential

      no data available

      Mobility in soil

      no data available

      Other adverse effects

      no data available

      SECTION 13: Disposal considerations

      Disposal methods

      Product

      The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

      Contaminated packaging

      Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

      SECTION 14: Transport information

      UN Number

      ADR/RID: no data available

      IMDG: no data available

      IATA: no data available

      UN Proper Shipping Name

      ADR/RID: no data available

      IMDG: no data available

      IATA: no data available

      Transport hazard class(es)

      ADR/RID: no data available

      IMDG: no data available

      IATA: no data available

      Packing group, if applicable

      ADR/RID: no data available

      IMDG: no data available

      IATA: no data available

      Environmental hazards

      ADR/RID: No

      IMDG: No

      IATA: No

      Special precautions for user

      no data available

      Transport in bulk according to IMO instruments

      no data available

      SECTION 15: Regulatory information

      Safety, health and environmental regulations specific for the product in question

      European Inventory of Existing Commercial Chemical Substances (EINECS)
      Listed.
      EC Inventory
      Listed.
      United States Toxic Substances Control Act (TSCA) Inventory
      Not Listed.
      China Catalog of Hazardous chemicals 2015
      Not Listed.
      New Zealand Inventory of Chemicals (NZIoC)
      Not Listed.
      PICCS
      Not Listed.
      Vietnam National Chemical Inventory
      Not Listed.
      IECSC
      Not Listed.
      Korea Existing Chemicals List (KECL)
      Not Listed.

      SECTION 16: Other information

      Abbreviations and acronyms

      • CAS: Chemical Abstracts Service
      • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
      • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
      • IMDG: International Maritime Dangerous Goods
      • IATA: International Air Transportation Association
      • TWA: Time Weighted Average
      • STEL: Short term exposure limit
      • LC50: Lethal Concentration 50%
      • LD50: Lethal Dose 50%
      • EC50: Effective Concentration 50%

      References

      • IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
      • HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
      • IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
      • eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
      • CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
      • ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
      • ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
      • Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
      • ECHA - European Chemicals Agency, website: https://echa.europa.eu/
      Disclaimer:

      The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.

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