1-Bromo-3-chloro-5,5-dimethylhydantoin
Product identifier
- Product name: 1-Bromo-3-chloro-5,5-dimethylhydantoin
- CBnumber: CB3489387
- CAS: 16079-88-2
- EINECS Number: 240-230-0
- Synonyms: 1-Bromo-3-chloro-5,5-dimethylhydantoin,agribrom
Relevant identified uses of the substance or mixture and uses advised against
- Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
- Uses advised against: none
Company Identification
- Company: Chemicalbook
- Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
- Telephone: 400-158-6606
Classification of the substance or mixture
Acute toxicity - Category 4, Oral
Skin corrosion, Sub-category 1B
Hazardous to the aquatic environment, short-term (Acute) - Category Acute 1
Label elements
Pictogram(s)
-
Signal word
Danger
H272 May intensify fire; oxidizer
H302 Harmful if swallowed
H314 Causes severe skin burns and eye damage
H400 Very toxic to aquatic life
P264 Wash ... thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P273 Avoid release to the environment.
P301+P317 IF SWALLOWED: Get medical help.
P330 Rinse mouth.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P363 Wash contaminated clothing before reuse.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P316 Get emergency medical help immediately.
P321 Specific treatment (see ... on this label).
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P391 Collect spillage.
P405 Store locked up.
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
Other hazards
no data available
Substance
- Product name: 1-Bromo-3-chloro-5,5-dimethylhydantoin
- Synonyms: 1-Bromo-3-chloro-5,5-dimethylhydantoin,agribrom
- CAS: 16079-88-2
- EC number: 240-230-0
- MF: C5H6BrClN2O2
- MW: 241.47
Description of first aid measures
If inhaledMove the victim into fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration and consult a doctor immediately. Do not use mouth to mouth resuscitation if the victim ingested or inhaled the chemical.
Take off contaminated clothing immediately. Wash off with soap and plenty of water. Consult a doctor.
Rinse with pure water for at least 15 minutes. Consult a doctor.
Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.
Most important symptoms and effects, both acute and delayed
no data available
Indication of any immediate medical attention and special treatment needed
FIRST AID: If in eyes, hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. If on skin or clothing, Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice. If inhaled, move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration . Call a poison control center or doctor for further treatment advice. If swallowed, call poison control center, or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by the poison control center or doctor. Do not give anything by mouth to an unconscious person./98% 1-Bromo-3-chloro-5,5-dimethylhydantoin/
Extinguishing media
Do not use ammonium phosphate extinguisher near water and /1-bromo-3-chloro-5,5-dimethylhandoin/.
Specific Hazards Arising from the Chemical
no data available
Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
Personal precautions, protective equipment and emergency procedures
Avoid dust formation. Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. Use personal protective equipment.Wear chemical impermeable gloves. Ensure adequate ventilation.Remove all sources of ignition. Evacuate personnel to safe areas.Keep people away from and upwind of spill/leak.
Environmental precautions
Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.
Methods and materials for containment and cleaning up
When handling or dealing with spills, use impact-resistant goggles with side shields, or face shield, body-covering clothes, including impervious rubber or plastic gloves and boots; use a dust respirator if dusting occurs. Sweep up dry spills and dispose of as described for pesticide disposal. If drum contents are contaminated or decomposing, do not reseal container; isolate unsealed drum in the open or in a well-ventilated area; flood with large volumes of water if necessary. 98% 1-Bromo-3-chloro-5,5-dimethylhydantoin
Precautions for safe handling
Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Conditions for safe storage, including any incompatibilities
Store in a dark, cool (below 66 deg F (30"C)), dark well-ventilated area, In well closed original containers, away from energy sources, combustible organic materials, oxidizers, stong bases, and moisture.
Control parameters
Occupational Exposure limit valuesno data available
no data available
Exposure controls
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Individual protection measures
Eye/face protectionWear tightly fitting safety goggles with side-shields conforming to EN 166(EU) or NIOSH (US).
Wear fire/flame resistant and impervious clothing. Handle with gloves. Gloves must be inspected prior to use. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
If the exposure limits are exceeded, irritation or other symptoms are experienced, use a full-face respirator.
no data available
Information on basic physicochemical properties
- Physical state
DryPowder,PelletsLargeCrystals
- Colour
Free-flowing, white powder
- Odour
Faint halogen odor
- Melting point/freezing point
159 - 163°C (Decomposes)
- Boiling point or initial boiling point and boiling range
232.7°C at 760mmHg
- Flammability
no data available
- Lower and upper explosion limit/flammability limit
no data available
- Flash point
94.5°C
- Auto-ignition temperature
no data available
- Decomposition temperature
no data available
- pH
pH of 3.5 at 0.15% diluted solution
- Kinematic viscosity
no data available
- Solubility
In water, 0.15 g/100g water at 20 deg C
- Partition coefficient n-octanol/water
log Kow = 0.35
- Vapour pressure
Negligible
- Density and/or relative density
1.91g/cm3
- Relative vapour density
no data available
- Particle characteristics
no data available
Reactivity
no data available
Chemical stability
no data available
Possibility of hazardous reactions
no data available
Conditions to avoid
no data available
Incompatible materials
Strong oxidizer, mix with water only/ Reaction with combustible organic materials, bases, moisture or with oxidizers may generate heat, hazardous gases and, possibly fire or explosion. 98% 1-Bromo-3-chloro-5,5-dimethylhydantoin
Hazardous decomposition products
When heated to decomposition it emits toxic vapors of /nitrogen oxides, hydrogen bromide, and hydrogen chloride/.
Acute toxicity
- Oral: LD50 Rat oral 1390 mg/kg
- Inhalation: no data available
- Dermal: no data available
Skin corrosion/irritation
no data available
Serious eye damage/irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
no data available
Reproductive toxicity
no data available
STOT-single exposure
no data available
STOT-repeated exposure
no data available
Aspiration hazard
no data available
Toxicity
- Toxicity to fish: LC50; Species: Pimephales promelas (Fathead minnow); Conditions: freshwater, static; Concentration: 14100 ppm for 96 hr (95% confidence interval: 13386-14990 ppm) /97% purity
- Toxicity to daphnia and other aquatic invertebrates: EC50; Species: Daphnia magna (Water flea) juvenile; Conditions: freshwater, flow through; Concentration: 0.1 ppm for 96 hr; Effect: intoxication, immobilization /96% purity
- Toxicity to algae: no data available
- Toxicity to microorganisms: no data available
Persistence and degradability
no data available
Bioaccumulative potential
An estimated BCF of 3 was calculated in fish for 1-bromo-3-chloro-5,5-dimethylhydantoin(SRC), using a log Kow of 0.35(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC).
Mobility in soil
Using a structure estimation method based on molecular connectivity indices(1), the Koc of 1-bromo-3-chloro-5,5-dimethylhydantoin can be estimated to be 10(SRC). According to a classification scheme(2), this estimated Koc value suggests that 1-bromo-3-chloro-5,5-dimethylhydantoin is expected to have very high mobility in soil(SRC).
Other adverse effects
no data available
Disposal methods
ProductThe material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
UN Number
ADR/RID: UN3085 (For reference only, please check.)
IMDG: UN3085 (For reference only, please check.)
IATA: UN3085 (For reference only, please check.)
UN Proper Shipping Name
ADR/RID: OXIDIZING SOLID, CORROSIVE, N.O.S. (For reference only, please check.)
IMDG: OXIDIZING SOLID, CORROSIVE, N.O.S. (For reference only, please check.)
IATA: OXIDIZING SOLID, CORROSIVE, N.O.S. (For reference only, please check.)
Transport hazard class(es)
ADR/RID: 5.1 (For reference only, please check.)
IMDG: 5.1 (For reference only, please check.)
IATA: 5.1 (For reference only, please check.)
Packing group, if applicable
ADR/RID: I (For reference only, please check.)
IMDG: I (For reference only, please check.)
IATA: I (For reference only, please check.)
Environmental hazards
ADR/RID: Yes
IMDG: Yes
IATA: Yes
Special precautions for user
no data available
Transport in bulk according to IMO instruments
no data available
Safety, health and environmental regulations specific for the product in question
European Inventory of Existing Commercial Chemical Substances (EINECS)Abbreviations and acronyms
- CAS: Chemical Abstracts Service
- ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
- RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
- IMDG: International Maritime Dangerous Goods
- IATA: International Air Transportation Association
- TWA: Time Weighted Average
- STEL: Short term exposure limit
- LC50: Lethal Concentration 50%
- LD50: Lethal Dose 50%
- EC50: Effective Concentration 50%
References
- IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
- HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
- IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
- eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
- CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
- ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
- ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
- Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
- ECHA - European Chemicals Agency, website: https://echa.europa.eu/
The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.