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Synthetic Communications

Synthetic Communications

IF: 1.8
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Regiospecific Carboalkoxylation of 2,5-Dibromopyridine

Published:1 February 1997 DOI: 10.1080/00397919708006053
R. J. Chambers,?A. Marfat

Abstract

Abstract Carboalkoxylation of 2,5-dibromopyridine with carbon monoxide and an alcohol in the presence of palladium acetate and 1,1′-bis(diphenylphosphino) ferrocene (dppf) occurs regiospecifically to afford esters of 5-bromo-pyridine-2-carboxylic acid in good yield.

Synthesis

carbon monoxide
5-Bromo-2-iodopyridine
Benzyl alcohol
5-bromopyridine-2-carboxylic acid benzyl ester

Substances (7)

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