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ChemicalBook >> CAS DataBase List >> 1,1'-Bis(diphenylphosphino)ferrocene

1,1'-Bis(diphenylphosphino)ferrocene

1,1'-Bis(diphenylphosphino)ferrocene price.
  • $5 - $2000
  • Product name: 1,1'-Bis(diphenylphosphino)ferrocene
  • CAS: 12150-46-8
  • MF: C34H28FeP210*
  • MW: 554.38
  • EINECS:640-119-0
  • MDL Number:MFCD00001422
  • Synonyms:1,1''-BIS(DIPHENYLPHOSPHINO)ERROCENE;1,1''-BIS(DIPHENYLPHOSPHINO)FERROCENE (DPPF);DPPF/1,1''-BIS(DIPHENYLPHOSPHINO) FERROCENE;1,1'-Bis(diphenylphosphiNA)ferrocene;DPPF, (Ferrocene-1,1'-diyl)bis(diphenylphosphine);1,1-(twophenylphosphine)Er Maotie;1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE;1,1'-FERROCENEBIS(DIPHENYLPHOSPHINE)
66 prices
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  • ManufacturerAcrotein
  • Product numberAC-3105
  • Product description1,1'-Bis(diphenylphosphino)ferrocene 97%
  • Packaging100g
  • Price$119.17
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberP147
  • Product descriptionDPPF,1,1'-Bis(diphenylphosphino)ferrocene
  • Packaging5g
  • Price$14
  • Updated2021-12-16
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  • ManufacturerAK Scientific
  • Product numberJ91434
  • Product descriptionDPPF,1,1'-Bis(diphenylphosphino)ferrocene
  • Packaging25g
  • Price$30
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberJ91434
  • Product descriptionDPPF,1,1'-Bis(diphenylphosphino)ferrocene
  • Packaging100g
  • Price$80
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberB21166
  • Product description1,1'-Bis(diphenylphosphino)ferrocene, 97%
  • Packaging1g
  • Price$49.3
  • Updated2023-06-20
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberB21166
  • Product description1,1'-Bis(diphenylphosphino)ferrocene, 97%
  • Packaging5g
  • Price$124
  • Updated2023-06-20
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberB21166
  • Product description1,1'-Bis(diphenylphosphino)ferrocene, 97%
  • Packaging25g
  • Price$594
  • Updated2023-06-20
  • Buy
  • ManufacturerAlichem
  • Product number12150468
  • Product description1,1-Bis(diphenylphosphino)ferrocene
  • Packaging500g
  • Price$265
  • Updated2021-12-16
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  • ManufacturerAlichem
  • Product number12150468
  • Product description1,1-Bis(diphenylphosphino)ferrocene
  • Packaging1000g
  • Price$469.2
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA323581
  • Product description1,1-Bis(diphenylphosphino)ferrocene 97%
  • Packaging1g
  • Price$5
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA323581
  • Product description1,1-Bis(diphenylphosphino)ferrocene 97%
  • Packaging5g
  • Price$7
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA323581
  • Product description1,1-Bis(diphenylphosphino)ferrocene 97%
  • Packaging10g
  • Price$11
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA323581
  • Product description1,1-Bis(diphenylphosphino)ferrocene 97%
  • Packaging25g
  • Price$17
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA323581
  • Product description1,1-Bis(diphenylphosphino)ferrocene 97%
  • Packaging100g
  • Price$56
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA323581
  • Product description1,1-Bis(diphenylphosphino)ferrocene 97%
  • Packaging500g
  • Price$245
  • Updated2021-12-16
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  • ManufacturerApolloscientific
  • Product numberOR1945
  • Product description1,1'-Bis(diphenylphosphino)ferrocene 99%
  • Packaging5g
  • Price$15
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Acrotein AC-3105 1,1'-Bis(diphenylphosphino)ferrocene 97% 100g $119.17 2021-12-16 Buy
AK Scientific P147 DPPF,1,1'-Bis(diphenylphosphino)ferrocene 5g $14 2021-12-16 Buy
AK Scientific J91434 DPPF,1,1'-Bis(diphenylphosphino)ferrocene 25g $30 2021-12-16 Buy
AK Scientific J91434 DPPF,1,1'-Bis(diphenylphosphino)ferrocene 100g $80 2021-12-16 Buy
Alfa Aesar B21166 1,1'-Bis(diphenylphosphino)ferrocene, 97% 1g $49.3 2023-06-20 Buy
Alfa Aesar B21166 1,1'-Bis(diphenylphosphino)ferrocene, 97% 5g $124 2023-06-20 Buy
Alfa Aesar B21166 1,1'-Bis(diphenylphosphino)ferrocene, 97% 25g $594 2023-06-20 Buy
Alichem 12150468 1,1-Bis(diphenylphosphino)ferrocene 500g $265 2021-12-16 Buy
Alichem 12150468 1,1-Bis(diphenylphosphino)ferrocene 1000g $469.2 2021-12-16 Buy
Ambeed A323581 1,1-Bis(diphenylphosphino)ferrocene 97% 1g $5 2021-12-16 Buy
Ambeed A323581 1,1-Bis(diphenylphosphino)ferrocene 97% 5g $7 2021-12-16 Buy
Ambeed A323581 1,1-Bis(diphenylphosphino)ferrocene 97% 10g $11 2021-12-16 Buy
Ambeed A323581 1,1-Bis(diphenylphosphino)ferrocene 97% 25g $17 2021-12-16 Buy
Ambeed A323581 1,1-Bis(diphenylphosphino)ferrocene 97% 100g $56 2021-12-16 Buy
Ambeed A323581 1,1-Bis(diphenylphosphino)ferrocene 97% 500g $245 2021-12-16 Buy
Apolloscientific OR1945 1,1'-Bis(diphenylphosphino)ferrocene 99% 5g $15 2021-12-16 Buy

Properties

Melting point :181-182 °C (dec.)(lit.)
storage temp. :2-8°C
solubility :Chloroform, Ethyl Acetate
form :crystal
color :yellow to orange
Water Solubility :Soluble in chloroform, dichloromethane, alcohol and pentane. Insoluble in water.
Sensitive :Air Sensitive
Hydrolytic Sensitivity :7: reacts slowly with moisture/water
Stability :Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference :12150-46-8(CAS DataBase Reference)
NIST Chemistry Reference :

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

Description

1,1'-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.

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