The structures of tetrachloro-p-benzoquinone and tetrachloro-o-benzoquinone (p- and o-chloranil) have been investigated by gas electron diffraction. The ring distances are slightly larger and the carbonyl bonds slightly smaller than in the corresponding unsubstituted quinones. The molecules are planar to within experimental error, but small deviations from planarity such as those found for the para compound in the crystal are completely compatible with the data. Values for the geometrical parameters (r_a distances and bond angles) and for some of the more important amplitudes (l) with parenthesized uncertainties of 2σ including estimated systematic error and correlation effects are as follows. Tetrachloro-p-benzoquinone: D_2h symmetry (assumed); r(CO) = 1.216 ?(4), r(CC) = 1.353 ?(6), r(C-C) = 1.492 ?(3), r(C-Cl) = 1.701 ?(3), ∠C-C-C = 117.1° (7), ∠CC-C1 = 122.7° (2), l(CO)= 0.037 ?(5), l(CC) = l(C-C) - 0.008 ?(assumed) = 0.049 ?(7), and l(C-Cl) = 0.054 ?(3). Tetrachloro-o-benzoquinone: C_2v symmetry (assumed); r(CO) = 1.205 ?(5), r(CC) = 1.354 ?(9), r(C_cl-C_cl) = 1.478 ?(28), r(Co-C_cl) = 1.483 ?(24), r(C_o-C_o) = 1.526 ?(2), r(C-Cl)= 1.705 ?(3), <C_o-CO = 121.0° (22), ∠C-C-C = 117.2° (9), ∠C_co, ClC-Cl = 118.9° (22), ∠C_ccl, ClC-Cl = 122.2°(12), l(CO) = 0.039 ?(5), and l(C_cl-C_cl) = l(C_o-C_cl) = l( Co-Co) = l(CC) + 0.060 ?(equalities assumed) = 0.055 ?(9). Vibrational'shortenings (shrinkages) of a few of the long non-bond distances have also been measured.