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Chemical Communications

Chemical Communications

IF: 4.29
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A fire-retarding electrolyte using triethyl phosphate as a solvent for sodium-ion batteries?

Published:7 December 2021 DOI: 10.1039/D1CC04958E PMID: 34908036
Kang Du, Chen Wang, Palani Balaya, Satyanarayana Reddy Gajjela and Markas Law

Abstract

We introduce a fire-retarding phosphate-based electrolyte, 1 M NaBF4 in triethyl phosphate with 3% vinylene carbonate as an SEI-forming additive, for sodium-ion batteries. With this electrolyte formulation, we achieved stable cycling performance with a capacity of 80.5 mA h g?1 and a retention of 77.8% after 200 cycles in the Na-ion full cell of Na3.2V1.8Zn0.2(PO4)3vs. hard carbon.

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