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Inorganic acid Esters

Inorganic acid ester is obtained through the reaction between alcohol and oxygen-containing organic acids or inorganic acid to generate esters (inorganic acid ester or organic acid esters) and water reaction. For example, sulfuric acid and ethanol, nitric acid and glycerol or pentaerythritol esters can have esterification reaction to generate important inorganic acids ester.

The compound obtained through the dehydration reaction between acid (inorganic and organic acids) and the alcohol is ester. It can be divided into inorganic acid esters (e.g., dimethyl sulfate, methyl hydrogen sulfate, glyceryltrinitrate, tributyl phosphate, etc.), and organic acid esters (e.g., ethyl acetate, vinyl acetate, and [alpha] methyl methacrylate ester, etc.) two categories. But the latter one is more important. In accordance with the intramolecular or intermolecular esterification of hydroxy acid (alcohol acid), it can also be divided into two kinds, lactone and lactide. Ester is generally neutral substance and can be subject to hydrolysis. Carboxylic acid ester can participate in a series of reactions including transesterification (alcoholysis), ammonolysis, reduction (hydrogenolysis) and the Grignard reaction.

Usually refers to a carboxylic acid ester with the general formula being RCOOR ', being the product with the hydrogen in the carboxyl group of carboxylic acid being replaced by hydrocarbon. The names of the esters are based on the names of corresponding carboxylic acid and alcohol or phenol such as "a certain acid ester." The cyclic ester is called lactone.
The chemical properties of ester are similar to acyl halide and acid anhydride. It is prone to have hydrolysis, alcoholysis and aminolysis reaction. The lower esters are aromatic volatile colorless liquid with the high-grade ester being solid. Esters are important solvents and synthetic chemicals with some kinds of ester itself being medicines. Depending on the type of acid, esters can be divided into inorganic and organic esters, such as hydrogen methyl sulfate (CH3OSO3H) for the former one and ethyl acetate CH3COOCH2CH3 for the later one; depending on the type of hydrocarbon, the ester can also be divided into fatty esters and aromatic esters and ring esters; ethyl acetate belongs to fatty esters; the phenyl acetate belongs to aromatic esters; while methyl furoate belongs to cyclic ester.

From the broad definition, the reaction between alcohols and acids for generating ester should be called as esterification. But usually it only refers to acid esterification and the esterification of alcohol is called as acylation. Esterification is reversible with the ester having hydrolysis with water to generate the original alcohol (or phenol) and acid. In general, the esterfication should be conducted in the presence of catalyst (hydrogen ion) and heating conditions, in order to shorten the time required for reaching equilibrium.

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Structure Chemical Name CAS MF
DimethylCarbonate DimethylCarbonate C3H6O3
STARCH PHOSPHATE STARCH PHOSPHATE
Hexaethyl tetraphosphate Hexaethyl tetraphosphate 757-58-4 C12H30O13P4
dibutyl sulfite dibutyl sulfite C8H18O3S
CARBONICACID,DIPENTYLESTER CARBONICACID,DIPENTYLESTER 2050-94-4 C11H22O3
2-(DODECYLSULFANYLTHIOCARBONYLSULFANYL)-2-METHYLPROPIONIC ACID 2-(DODECYLSULFANYLTHIOCARBONYLSULFANYL)-2-METHYLPROPIONIC ACID 461642-78-4 C17H32O2S3
phenylsulfate phenylsulfate 937-34-8 C6H6O4S
Pentyl dihydrogen phosphate Pentyl dihydrogen phosphate 12789-46-7 C5H13O4P
4-methyl-1,3,2-dioxathiane 2-oxide 4-methyl-1,3,2-dioxathiane 2-oxide 4426-51-1 C4H8O3S
phosphoric acid,2-naphthalenyl diphenyl ester phosphoric acid,2-naphthalenyl diphenyl ester 18872-49-6 C22H17O4P
Propyl butylsulfonate Propyl butylsulfonate C7H16O3S
propylene carbonate propylene carbonate C4H6O3
2,3-Butylene carbonate 2,3-Butylene carbonate C5H8O3
Dicaprylyl carbonate Dicaprylyl carbonate 1680-31-5 C17H34O3
Cholesteryl carbonate Cholesteryl carbonate C28H46O3
Phosphoric acid, monobutyl monophenyl ester Phosphoric acid, monobutyl monophenyl ester 46438-39-5 C10H15O4P
allyl diglycocarbonate allyl diglycocarbonate C12H14O7
diphenyl-o-chlorophenyl phosphate diphenyl-o-chlorophenyl phosphate C18H14ClO4P
n-octyl nitrate n-octyl nitrate C8H17NO3
trithiophenyl phosphate trithiophenyl phosphate C6H9O4PS3
tris(methylphenyl) phosphite tris(methylphenyl) phosphite 25586-42-9 C21H21O3P
1-(2-Pyridyla20)-2-Naphthol(Pan) 1-(2-Pyridyla20)-2-Naphthol(Pan)
Methyl Bisulfate Methyl Bisulfate CH4O4S
dodecyl sulfate dodecyl sulfate C12H26O4S
monoethyl sulfate monoethyl sulfate C2H6O4S
pentaerythitol tetranitrate pentaerythitol tetranitrate C5H8N4O12
decyl nitrate decyl nitrate C10H21NO3
dichloropropyl nitrate dichloropropyl nitrate C3H5Cl2NO3
diphenyl tert-butyl phosphate diphenyl tert-butyl phosphate C16H19O4P
Di-iso-amyl phosphate Di-iso-amyl phosphate 3985-20-4 C10H23O4P
Phosphoric acid, hexyl ester Phosphoric acid, hexyl ester 68511-03-5 C6H15O4P
DIETHYLHEXYL CARBONATE DIETHYLHEXYL CARBONATE C11H22O3
Phosphorous acid, dinonylphenyl nonylphenyl ester Phosphorous acid, dinonylphenyl nonylphenyl ester 68186-33-4 C24H42O.xC15H24O.xH3O3P
heptyl sulfate heptyl sulfate C7H16O4S
n-octyl nitrite n-octyl nitrite C8H17NO2
propyl hydrogen sulfate propyl hydrogen sulfate 13425-84-8 C3H8O4S
1-decanol sulfate 1-decanol sulfate C10H22O4S
Cellulose, dinitrate Cellulose, dinitrate 50935-18-7
4427-96-7 4427-96-7 4427-96-7
Poly(oxy-1,2-ethanediyl), .alpha.-sulfo-.omega.-hydroxy-, C6-10-alkyl ethers, ammonium salts Poly(oxy-1,2-ethanediyl), .alpha.-sulfo-.omega.-hydroxy-, C6-10-alkyl ethers, ammonium salts 68037-05-8
chloromethyl methyl sulfate chloromethyl methyl sulfate C2H5ClO4S
decyl nitrite decyl nitrite C10H21NO2
heptyl nitrite heptyl nitrite C7H15NO2
mononitroglycerin mononitroglycerin C3H5(OH)2ONO2
nonyl sulfate nonyl sulfate C9H20O4S
phenyl hydrogen sulfate phenyl hydrogen sulfate C6H6O4S
Isoamyl nitrate γ-Methylbutyl nitrate Isoamyl nitrate γ-Methylbutyl nitrate C5H11NO3
diisobutyl sulfate diisobutyl sulfate C8H18O4S
n-octyl sulfate n-octyl sulfate C8H18O4S
tetradecyl sulfate tetradecyl sulfate C14H30O4S
Butyl orthosilicate Butyl orthosilicate C4H12O4Si
π-Propyl nitrite π-Propyl nitrite
isotridecyl dihydrogen phosphate isotridecyl dihydrogen phosphate 50977-11-2 C13H29O4P
tris(nonylphenyl) phosphate tris(nonylphenyl) phosphate 26569-53-9 C45H69O4P
amyl hydrogen sulfate amyl hydrogen sulfate C5H12O4S
amyl sulfate amyl sulfate C5H12O4S
diamyl carbonate diamyl carbonate C11H22O3
diisoamyl sulfate diisoamyl sulfate C10H22O4S
di-n-dodecyl sulfate di-n-dodecyl sulfate C24H50O4S
isoamyl sulfate isoamyl sulfate C5H12O4S
nitromannite nitromannite C6H8(NO3)6
tri-p-biphenyl phosphate tri-p-biphenyl phosphate C36H33O4P
ISOPROPYLPHENYLDIPHENYL PHOSPHATE ISOPROPYLPHENYLDIPHENYL PHOSPHATE C21H21O4P
Diethyl silicate Diethyl silicate Si2Ti
Methyl nitrate Methyl nitrate 589-58-3 CH3NO3
carbonic acid diisoamyl ester carbonic acid diisoamyl ester C11H22O3
sec-butylnitrate sec-butylnitrate 924-52-7 C4H9NO3
hexyl sulfate hexyl sulfate C6H14O4S
tetramethylene phosphate tetramethylene phosphate 51374-71-1 C4H9O4P
2-bromoethyl nitrate 2-bromoethyl nitrate C2H4BrNO3
butyl hydrogen sulfate butyl hydrogen sulfate C4H10O4S
cetyl sulfate cetyl sulfate C16H34O4S
Phosphoric acid,methyl ester Phosphoric acid,methyl ester 12789-45-6 CH4O.xH3O4P
Ethyl butyl carbonate Ethyl butyl carbonate C7H14O3
SULFATED GLYCERYL OLEATE SULFATED GLYCERYL OLEATE
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