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Pyridine compound

Pyridine compound is one of the most widely developed and used heterocyclic compound. As an important fine chemical raw material, its derivatives mainly include alkyl pyridine, halogenated pyridine, aminopyridine, bromo pyridine, picoline , iodine pyridine, chloropyridine, nitropyridine-hydroxypyridine, benzyl pyridine, ethyl pyridine, pyridine cyano, fluoro pyridine, dihydropyridine, etc., in which the pesticide accounts for about 50% of the total consumption of pyridine products, feed additive about 30% and  medicine and other areas 20%.

Pyridine is a colorless or slightly yellow liquid that has weak alkaline and special odor. It is an important chemical raw material and solvent, which naturally presents in coal tar, shale oil, gas and petroleum and is miscible with most of the water, alcohols, ethers, petroleum ether, oils, benzene, chloroform and other organic solvents.

The important derivatives of pyridine mainly include nicotinic acid, nicotinamide, isonicotinic hydrazide, nicotine, strychnine, and vitamin B6.

Pyridine has a close hexagonal structure that is similar to benzene. Because of the electron-withdrawing effect of the nitrogen atom in the ring, the electron density of 2,4,6 positions is less than that of 3,5 positions. In an acidic medium, electrophilic substitution reactions occur in the 3,5 positions and nucleophilic reactions, such as amination, alkylation, arylation, acylation, occur in the 2,4,6 positions. Pyridine is a weak tertiary amine, which can form different water-soluble salts with various acids (such as picric acid, perchloric acid or the like) in an ethanol solution. Due to the alkaline of pyridine, it can generate hydrochloride (C5H5N•HCl)with hydrochloric acid. In the effect of nickel catalyst at 200 ℃ and 15-30MPa, it can generate piperidine via hydrogenation or electrolysis reduction. The reduction of pyridine is easier than benzene, while the oxidation is more difficult than benzene. But we can oxidize pyridine by the catalysis of hydrogen peroxide or peroxy acids. N-pyridine oxide is an important pyridine derivative, which is easier for the happen of aryl group electrophilic substitution reaction because the oxidation of nitrogen atoms make the formation of positively charged pyridinium cation impossible. Electrophilic substitutions, such as pyridine nitration, sulfonation, halogenation, are relatively difficult, but the previous actions are slightly easier than halogenation. We can obtain 3,5-dichloro-pyridine or 3,4,5-trichloro pyridine via pyridine nitration and sulfonation at more than 200℃. Pyridine can form many crystalline complex compounds with various metal ions.

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Structure Chemical Name CAS MF
2-Phenylpyridine 2-Phenylpyridine 1008-89-5 C11H9N
2,5-Diaminopyridine 2,5-Diaminopyridine 4318-76-7 C5H7N3
2,5-Dichloro-3-nitropyridine 2,5-Dichloro-3-nitropyridine 21427-62-3 C5H2Cl2N2O2
2-Hydroxy-5-bromopyridine 2-Hydroxy-5-bromopyridine 13466-38-1 C5H4BrNO
3-Bromo-2-methoxy-5-nitropyridine 3-Bromo-2-methoxy-5-nitropyridine 15862-50-7 C6H5BrN2O3
3-HYDROXY-5-METHYLPYRIDINE 3-HYDROXY-5-METHYLPYRIDINE 42732-49-0 C6H7NO
3,5-Dibromo-2-pyridylamine 3,5-Dibromo-2-pyridylamine 35486-42-1 C5H4Br2N2
2-Pyridinethione 2-Pyridinethione 2637-34-5 C5H5NS
3-Amino-2-chloro-6-(trifluoromethyl)pyridine 3-Amino-2-chloro-6-(trifluoromethyl)pyridine 117519-09-2 C6H4ClF3N2
2,6-Dichloroisonicotinonitrile 2,6-Dichloroisonicotinonitrile 32710-65-9 C6H2Cl2N2
2-Chloromethyl-4-methoxy-3,5-dimethylpyridine hydrochloride 2-Chloromethyl-4-methoxy-3,5-dimethylpyridine hydrochloride 86604-75-3 C9H13Cl2NO
5-CHLORO-3-PYRIDINAMINE 5-CHLORO-3-PYRIDINAMINE 22353-34-0 C5H5ClN2
3-Bromo-2-methylpyridine 3-Bromo-2-methylpyridine 38749-79-0 C6H6BrN
4-FORMYL-1-METHYL-PYRIDINIUM BENZENESULFONATE 4-FORMYL-1-METHYL-PYRIDINIUM BENZENESULFONATE 82228-89-5 C13H13NO4S
2-Picoline 2-Picoline 109-06-8 C6H7N
2-AMINO-3-CHLORO-5-METHYLPYRIDINE 2-AMINO-3-CHLORO-5-METHYLPYRIDINE 31430-41-8 C6H7ClN2
3-Chloropyridin-2-ol 3-Chloropyridin-2-ol 13466-35-8 C5H4ClNO
4-Phenylpyridine 4-Phenylpyridine 939-23-1 C11H9N
3-Amino-2-bromopyridine 3-Amino-2-bromopyridine 39856-58-1 C5H5BrN2
2-(N-BOC-AMINO)-5-BROMOPYRIDINE 2-(N-BOC-AMINO)-5-BROMOPYRIDINE 159451-66-8 C10H13BrN2O2
2-Fluoro-3-methylpyridine 2-Fluoro-3-methylpyridine 2369-18-8 C6H6FN
3-Amino-2-fluoropyridine 3-Amino-2-fluoropyridine 1597-33-7 C5H5FN2
2-Chloro-4-nitropyridine 2-Chloro-4-nitropyridine 23056-36-2 C5H3ClN2O2
3-AMINO-2-CHLORO-6-PICOLINE 3-AMINO-2-CHLORO-6-PICOLINE 39745-40-9 C6H7ClN2
2-Iodopyridine 2-Iodopyridine 5029-67-4 C5H4IN
5-Chloropyridine-2-boronic acid 5-Chloropyridine-2-boronic acid 652148-91-9 C5H5BClNO2
5-Bromo-2-ethoxypyridine 5-Bromo-2-ethoxypyridine 55849-30-4 C7H8BrNO
2-AMINO-3-IODO-5-NITROPYRIDINE 2-AMINO-3-IODO-5-NITROPYRIDINE 25391-56-4 C5H4IN3O2
4-AMINO-5-BROMO-2-CHLOROPYRIDINE 4-AMINO-5-BROMO-2-CHLOROPYRIDINE 857730-21-3 C5H4BrClN2
2-chloro-5-(trifluoromethyl)-4-iodopyridine 2-chloro-5-(trifluoromethyl)-4-iodopyridine 505084-55-9 C6H2ClF3IN
5-AMINO-3-BROMO-2-METHOXYPYRIDINE 5-AMINO-3-BROMO-2-METHOXYPYRIDINE 53242-18-5 C6H7BrN2O
4-(4-Aminophenoxy)-N-methylpicolinamide 4-(4-Aminophenoxy)-N-methylpicolinamide 284462-37-9 C13H13N3O2
2-ACETAMIDO-5-AMINOPYRIDINE 2-ACETAMIDO-5-AMINOPYRIDINE 29958-14-3 C7H9N3O
3,5-Difluoropyridine-2,6-diamine 3,5-Difluoropyridine-2,6-diamine 247069-27-8 C5H5F2N3
2-Cyano-3-chloropyridine 2-Cyano-3-chloropyridine 38180-46-0 C6H3ClN2
2,3-Diamino-5-bromopyridine 2,3-Diamino-5-bromopyridine 38875-53-5 C5H6BrN3
2-Methoxy-3-chloro-5-bromopyridine 2-Methoxy-3-chloro-5-bromopyridine 848366-28-9 C6H5BrClNO
3-Amino-2-fluoro-6-methylpyridine 3-Amino-2-fluoro-6-methylpyridine 374633-34-8 C6H7FN2
3-Amino-5-bromo-2-chloropyridine 3-Amino-5-bromo-2-chloropyridine 588729-99-1 C5H4BrClN2
3-Cyano-2,6-dihydroxy-4-methylpyridine 3-Cyano-2,6-dihydroxy-4-methylpyridine 5444-02-0 C7H6N2O2
3-AMINO-2-CHLORO-5-PICOLINE 3-AMINO-2-CHLORO-5-PICOLINE 34552-13-1 C6H7ClN2
2,6-DICHLOROPYRIDINE-4-CARBONYL CHLORIDE 2,6-DICHLOROPYRIDINE-4-CARBONYL CHLORIDE 42521-08-4 C6H2Cl3NO
2-Chloropyridine-4-carbonyl chloride 2-Chloropyridine-4-carbonyl chloride 65287-34-5 C6H3Cl2NO
2-FLUORO-4-NITROPYRIDINE 2-FLUORO-4-NITROPYRIDINE 18614-46-5 C5H3FN2O2
2-Chloro-3-fluoro-6-picoline 2-Chloro-3-fluoro-6-picoline 374633-32-6 C6H5ClFN
Nitrapyrin Nitrapyrin 1929-82-4 C6H3Cl4N
3-Methylpyridine-2-carboxylic acid 3-Methylpyridine-2-carboxylic acid 4021-07-2 C7H7NO2
4-CYANO-7-AZAINDOLE 4-CYANO-7-AZAINDOLE 344327-11-3 C8H5N3
2-Hydroxy-4-methyl-5-nitropyridine 2-Hydroxy-4-methyl-5-nitropyridine 21901-41-7 C6H6N2O3
2-AMINO-4,7-DIHYDRO-5H-THIENO[2,3-C]PYRIDINE-3,6-DICARBOXYLIC ACID 6-TERT BUTYL ESTER 3-ETHYL ESTER 2-AMINO-4,7-DIHYDRO-5H-THIENO[2,3-C]PYRIDINE-3,6-DICARBOXYLIC ACID 6-TERT BUTYL ESTER 3-ETHYL ESTER 193537-14-3 C15H22N2O4S
2-AMINO-5-IODO-3-NITROPYRIDINE 2-AMINO-5-IODO-3-NITROPYRIDINE 25391-57-5 C5H4IN3O2
5-Fluoro-2-hydroxypyridine 5-Fluoro-2-hydroxypyridine 51173-05-8 C5H4FNO
N-Methyl-3-pyridinamine N-Methyl-3-pyridinamine 18364-47-1 C6H8N2
3-Fluoro-2-nitropyridine 3-Fluoro-2-nitropyridine 54231-35-5 C5H3FN2O2
2-Amino-3-nitropyridine 2-Amino-3-nitropyridine 4214-75-9 C5H5N3O2
5-BROMO-2-METHOXY-NICOTINIC ACID 5-BROMO-2-METHOXY-NICOTINIC ACID 54916-66-4 C7H6BrNO3
3-Bromo-2-chloro-5-nitropyridine 3-Bromo-2-chloro-5-nitropyridine 5470-17-7 C5H2BrClN2O2
3-Chloro-5-(trifluoromethyl)pyridin-2-amine 3-Chloro-5-(trifluoromethyl)pyridin-2-amine 79456-26-1 C6H4ClF3N2
6-Chloronicotinamide 6-Chloronicotinamide 6271-78-9 C6H5ClN2O
5-FLUORO-2-METHOXY-6-PICOLINE 5-FLUORO-2-METHOXY-6-PICOLINE 375368-86-8 C7H8FNO
Pentafluoropyridine Pentafluoropyridine 700-16-3 C5F5N
4-Hydroxy-2,6-dimethylpyridine 4-Hydroxy-2,6-dimethylpyridine 13603-44-6 C7H9NO
6-Methylnicotinic acid 6-Methylnicotinic acid 3222-47-7 C7H7NO2
3-AMINO-2,6-DICHLORO-4-(TRIFLUOROMETHYL)PYRIDINE 3-AMINO-2,6-DICHLORO-4-(TRIFLUOROMETHYL)PYRIDINE 175277-67-5 C6H3Cl2F3N2
2,6-Dichloropyridine-4-carboxaldehyde 2,6-Dichloropyridine-4-carboxaldehyde 113293-70-2 C6H3Cl2NO
2-Chloro-3-cyanopyridine 2-Chloro-3-cyanopyridine 6602-54-6 C6H3ClN2
1-FLUORO-2,4,6-TRIMETHYLPYRIDINIUM TRIFLATE 1-FLUORO-2,4,6-TRIMETHYLPYRIDINIUM TRIFLATE 107264-00-6 C9H11F4NO3S
2-Benzylaminopyridine 2-Benzylaminopyridine 6935-27-9 C12H12N2
3-AMINO-4-CYANOPYRIDINE 3-AMINO-4-CYANOPYRIDINE 78790-79-1 C6H5N3
2-CYANOPYRIDINE-5-BORONIC ACID PINACOL ESTER 2-CYANOPYRIDINE-5-BORONIC ACID PINACOL ESTER 741709-63-7 C12H15BN2O2
3-BROMO-2,5-DICHLOROPYRIDINE 3-BROMO-2,5-DICHLOROPYRIDINE 138006-41-4 C5H2BrCl2N
3-Amino-4-iodopyridine 3-Amino-4-iodopyridine 105752-11-2 C5H5IN2
2-Amino-4-methoxypyridine 2-Amino-4-methoxypyridine 10201-73-7 C6H8N2O
3-(1-Pyridinio)-1-propanesulfonate 3-(1-Pyridinio)-1-propanesulfonate 15471-17-7 C8H11NO3S
2-Fluoro-3-iodo-5-methylpyridine 2-Fluoro-3-iodo-5-methylpyridine 153034-78-7 C6H5FIN
5-Bromo-2-pyridinecarbonitrile 5-Bromo-2-pyridinecarbonitrile 97483-77-7 C6H3BrN2
3-AMINO-ISONICOTINIC ACID METHYL ESTER 3-AMINO-ISONICOTINIC ACID METHYL ESTER 55279-30-6 C7H8N2O2
2-Amino-5-bromo-3-methylpyridine 2-Amino-5-bromo-3-methylpyridine 3430-21-5 C6H7BrN2
5-Bromo-2-methoxy-4-methylpyridine 5-Bromo-2-methoxy-4-methylpyridine 164513-39-7 C7H8BrNO
4-IODO-2-FLUORO-3-FORMYLPYRIDINE 4-IODO-2-FLUORO-3-FORMYLPYRIDINE 153034-82-3 C6H3FINO
3-FLUORO-4-IODOPYRIDINE 3-FLUORO-4-IODOPYRIDINE 22282-75-3 C5H3FIN
1-Ethylpyridinium bromide 1-Ethylpyridinium bromide 1906-79-2 C7H10BrN
3-Bromo-2-fluoro-5-methylpyridine 3-Bromo-2-fluoro-5-methylpyridine 17282-01-8 C6H5BrFN
2-Amino-6-methyl-5-nitropyridine 2-Amino-6-methyl-5-nitropyridine 22280-62-2 C6H7N3O2
4-(Trifluoromethyl)pyridine-3-carboxamide oxime 4-(Trifluoromethyl)pyridine-3-carboxamide oxime 175204-85-0 C7H6F3N3O
2-Amino-6-methoxy-3-nitropyridine 2-Amino-6-methoxy-3-nitropyridine 73896-36-3 C6H7N3O3
5-Chloro-2-hydroxy-3-nitropyridine 5-Chloro-2-hydroxy-3-nitropyridine 21427-61-2 C5H3ClN2O3
4-NITRO-PYRIDIN-3-YLAMINE 4-NITRO-PYRIDIN-3-YLAMINE 13505-02-7 C5H5N3O2
6-Methyl-2-pyridinecarboxylic acid 6-Methyl-2-pyridinecarboxylic acid 934-60-1 C7H7NO2
3-BROMO-2-HYDROXY-6-PICOLINE 3-BROMO-2-HYDROXY-6-PICOLINE 374633-33-7 C6H6BrNO
2,6-dichloro-4-iodopyridine 2,6-dichloro-4-iodopyridine 98027-84-0 C5H2Cl2IN
2-CHLOROPYRIDINE N-OXIDE HYDROCHLORIDE 2-CHLOROPYRIDINE N-OXIDE HYDROCHLORIDE 20295-64-1 C5H5Cl2NO
3-Methyl-4-aminopyridine 3-Methyl-4-aminopyridine 1990-90-5 C6H8N2
1-Ethylpyridinium chloride 1-Ethylpyridinium chloride 2294-38-4 C7H10ClN
4-(4-Nitrobenzyl)pyridine 4-(4-Nitrobenzyl)pyridine 1083-48-3 C12H10N2O2
2,6-Dibromopyridin-3-amine 2,6-Dibromopyridin-3-amine 39856-57-0 C5H4Br2N2
5-METHOXY-PYRIDIN-2-YLAMINE 5-METHOXY-PYRIDIN-2-YLAMINE 10167-97-2 C6H8N2O
2-Chloroisonicotinaldehyde 2-Chloroisonicotinaldehyde 101066-61-9 C6H4ClNO
2,4-Dichloro-3-methylpyridine 2,4-Dichloro-3-methylpyridine 132097-09-7 C6H5Cl2N
2-Chloro-3,4-diaminopyridine 2-Chloro-3,4-diaminopyridine 39217-08-8 C5H6ClN3
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