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ChemicalBook >> CAS DataBase List >> (R)-DM-BINAP

(R)-DM-BINAP

(R)-DM-BINAP price.
  • $32 - $383
  • Product name: (R)-DM-BINAP
  • CAS: 137219-86-4
  • MF: C52H48P2
  • MW: 734.89
  • EINECS:681-153-6
  • MDL Number:MFCD01630821
  • Synonyms:(R)-(+)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL;(R)-(+)-2,2'-BIS[BIS(3,5-DIMETHYLPHENYL)PHOSPHINO]-1,1'-BINAPHTHYL;RACEMIC-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL;RAC-XYLYL-BINAP;(R)-3,5-XYLYL-BINAP;(R)-(+)-2,2'-Bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl, ((R)-Xylyl-B ;(R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,98%(R)-3,5-xylyl-BINAP;(R)-(+)-2,2'-bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl
14 prices
Selected condition：
Brand
  • Alfa Aesar
  • Ambeed
  • Chem-Impex
  • ChemSupplyAustralia
  • Sigma-Aldrich
  • Strem Chemicals
  • TCI Chemical
  • TRC
Package
  • 2.5mg
  • 100mg
  • 200MG
  • 250mg
  • 500mg
  • 1G
  • 5g
  • ManufacturerAlfa Aesar
  • Product numberH27680
  • Product description(R)-(+)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl, 98%
  • Packaging100mg
  • Price$72.4
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberH27680
  • Product description(R)-(+)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl, 98%
  • Packaging500mg
  • Price$214
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA324365
  • Product description(R)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl 98%
  • Packaging250mg
  • Price$32
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA324365
  • Product description(R)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl 98%
  • Packaging5g
  • Price$383
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number41143
  • Product description(R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,99%(Chiralpurity) 99%(Chiralpurity)
  • Packaging200MG
  • Price$53.76
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number41143
  • Product description(R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,99%(Chiralpurity) 99%(Chiralpurity)
  • Packaging1G
  • Price$200.48
  • Updated2021-12-16
  • Buy
  • ManufacturerChemSupplyAustralia
  • Product number300006
  • Product description(R)-(+)-2,2'-Bis[di-(3,5-dimethylphenyl)phosphino]-1,1'-binaphthyl, 98%
  • Packaging250mg
  • Price$48.4
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number692379
  • Product description(R)-DM-BINAP
  • Packaging100mg
  • Price$78.7
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number15-0476
  • Product description(R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl, 98% (R)-(+)-XylBINAP
  • Packaging250mg
  • Price$48
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number15-0476
  • Product description(R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl, 98% (R)-(+)-XylBINAP
  • Packaging1g
  • Price$142
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number15-0476
  • Product description(R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl, 98% (R)-(+)-XylBINAP
  • Packaging5g
  • Price$341
  • Updated2024-03-01
  • Buy
  • ManufacturerTCI Chemical
  • Product numberX0070
  • Product description(R)-(+)-XylBINAP >97.0%(HPLC)
  • Packaging200mg
  • Price$60
  • Updated2024-03-01
  • Buy
  • ManufacturerTCI Chemical
  • Product numberX0070
  • Product description(R)-(+)-XylBINAP >97.0%(HPLC)
  • Packaging1g
  • Price$203
  • Updated2024-03-01
  • Buy
  • ManufacturerTRC
  • Product numberX750970
  • Product description(R)-(+)-XylBINAP
  • Packaging2.5mg
  • Price$45
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Alfa Aesar H27680 (R)-(+)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl, 98% 100mg $72.4 2021-12-16 Buy
Alfa Aesar H27680 (R)-(+)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl, 98% 500mg $214 2021-12-16 Buy
Ambeed A324365 (R)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl 98% 250mg $32 2021-12-16 Buy
Ambeed A324365 (R)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl 98% 5g $383 2021-12-16 Buy
Chem-Impex 41143 (R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,99%(Chiralpurity) 99%(Chiralpurity) 200MG $53.76 2021-12-16 Buy
Chem-Impex 41143 (R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,99%(Chiralpurity) 99%(Chiralpurity) 1G $200.48 2021-12-16 Buy
ChemSupplyAustralia 300006 (R)-(+)-2,2'-Bis[di-(3,5-dimethylphenyl)phosphino]-1,1'-binaphthyl, 98% 250mg $48.4 2021-12-16 Buy
Sigma-Aldrich 692379 (R)-DM-BINAP 100mg $78.7 2024-03-01 Buy
Strem Chemicals 15-0476 (R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl, 98% (R)-(+)-XylBINAP 250mg $48 2024-03-01 Buy
Strem Chemicals 15-0476 (R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl, 98% (R)-(+)-XylBINAP 1g $142 2024-03-01 Buy
Strem Chemicals 15-0476 (R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl, 98% (R)-(+)-XylBINAP 5g $341 2024-03-01 Buy
TCI Chemical X0070 (R)-(+)-XylBINAP >97.0%(HPLC) 200mg $60 2024-03-01 Buy
TCI Chemical X0070 (R)-(+)-XylBINAP >97.0%(HPLC) 1g $203 2024-03-01 Buy
TRC X750970 (R)-(+)-XylBINAP 2.5mg $45 2021-12-16 Buy

Properties

Melting point :203-206°C
Boiling point :825.3±65.0 °C(Predicted)
alpha :169 º (c=1 in chloroform)
storage temp. :Inert atmosphere,Room Temperature
Water Solubility :Insoluble in water
form :crystal
color :white to pale yellow
optical activity :[α]20/D +169°, c = 1 in chloroform

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

Description

(R)-(+)-XylBINAP is a phosphine-based ligand used in the preparation of various catalysts, such as Pd catalysts for the asymmetric dearomative alkenylation of indoles through a reductive-?Heck reaction.

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