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Postion:Product Catalog >Chemical Reagents>Organic reagents>Phosphine ligand>(R)-DM-BINAP
(R)-DM-BINAP
  • (R)-DM-BINAP

(R)-DM-BINAP

Price $1
Package 1KG
Min. Order: 1KG
Supply Ability: 100KG
Update Time: 2019-08-30

Product Details

Product Name: (R)-DM-BINAP CAS No.: 137219-86-4
Min. Order: 1KG Purity: 95%-99%
Supply Ability: 100KG Release date: 2019/08/30
Product Name:
(R)-DM-BINAP
Synonyms:
(R)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,(R)-XylBINAP;(R)-(+)-2,2'-Bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl, ((R)-Xylyl-BINAP);(R)-(+)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL;(R)-(+)-2,2'-BIS[BIS(3,5-DIMETHYLPHENYL)PHOSPHINO]-1,1'-BINAPHTHYL;RACEMIC-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL;RAC-XYLYL-BINAP;(R)-3,5-XYLYL-BINAP;2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL
CAS:
137219-86-4
MF:
C52H48P2
MW:
734.89
EINECS:
681-153-6
Product Categories:
BINAP Series;Chiral Phosphine
Mol File:
137219-86-4.mol
Article illustration
 
(R)-DM-BINAP Chemical Properties
Melting point 
203-206°C
alpha 
169 º (c=1 in chloroform)
form 
crystal
color 
white to pale yellow
optical activity
[α]20/D +169°, c = 1 in chloroform
 
Safety Information
WGK Germany 
3

 

Reaction
  1. Ligand used in copper-catalyzed asymmetric Mannich-type reactions of N-acylimino esters.
  2. Ligand used in the enantioselective fluorination of oxindoles.
  3. Ligand used in [2+2+2] cycloaddition of tetraynes and hexaynes.
  4. Ligand used in the asymmetric reduction of ketone via ruthenium-catalyzed transfer hydrogenation.
  5. Asymmetric hydroboration of unsaturated imines.
Article illustration

Company Profile Introduction

Established in 2014,Career Henan Chemical Co. is a manufacturerspecializing in the sale of fine chemicals. Mainly deals in the sales of: Pharmaceutical intermediates OLED intermediates: Pharmaceutical intermediates; OLED intermediates;

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