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    ChemicalBook >> CAS DataBase List >> Lithium Triethylborohydride

    Lithium Triethylborohydride

    Lithium Triethylborohydride price.
    • $27.4 - $874
    • Product name: Lithium Triethylborohydride
    • CAS: 22560-16-3
    • MF: C6H13BLi
    • MW: 102.92
    • EINECS:245-076-8
    • MDL Number:MFCD00011703
    • Synonyms:lithiumtriethylborohydride,calselect?lt, ;lithiumtriethylborohydride,calselect?lt,intetrahydrofuran ;Lithium triethylborohydrideLithium triethylhydroborate;Lithium triethylborahydride (super-hydride);Super-Hydride solution,Lithium triethylborohydride solution;Lithium triethylborohydride, 1M solution in THF, AcroSeal;LithiuM triethylborohydride, 1M solution in THF, AcroSeal 100ML;LithiuM triethylborohydride, 1M solution in THF, AcroSeal 800ML
    20 prices
    Selected condition:
    Brand
    • Alfa Aesar
    • American Custom Chemicals Corporation
    • Sigma-Aldrich
    • TCI Chemical
    • TRC
    • Usbiological
    Package
    • 5MG
    • 25ml
    • 50ml
    • 100ml
    • 4X25ML
    • 250ml
    • 500ml
    • 800ml
    • 2l
    • 8l
    • ManufacturerAlfa Aesar
    • Product number089144
    • Product descriptionLithium triethylborohydride, 1M in THF
    • Packaging25ml
    • Price$27.4
    • Updated2022-04-27
    • Buy
    • ManufacturerAlfa Aesar
    • Product number042491
    • Product descriptionLithium triethylborohydride, 1M in THF, packaged under Argon in resealable ChemSeal? bottles
    • Packaging25ml
    • Price$33.2
    • Updated2021-12-16
    • Buy
    • ManufacturerAlfa Aesar
    • Product number042491
    • Product descriptionLithium triethylborohydride, 1M in THF, packaged under Argon in resealable ChemSeal? bottles
    • Packaging50ml
    • Price$60.4
    • Updated2021-12-16
    • Buy
    • ManufacturerAlfa Aesar
    • Product numberH36830
    • Product descriptionLithium triethylborohydride, 1.7M in THF packaged under Nitrogen in resealable AcroSeal[t bottles
    • Packaging100ml
    • Price$80.9
    • Updated2021-12-16
    • Buy
    • ManufacturerAlfa Aesar
    • Product number089144
    • Product descriptionLithium triethylborohydride, 1M in THF
    • Packaging100ml
    • Price$83.1
    • Updated2022-04-27
    • Buy
    • ManufacturerAlfa Aesar
    • Product number042491
    • Product descriptionLithium triethylborohydride, 1M in THF, packaged under Argon in resealable ChemSeal? bottles
    • Packaging100ml
    • Price$98
    • Updated2021-12-16
    • Buy
    • ManufacturerAlfa Aesar
    • Product number042491
    • Product descriptionLithium triethylborohydride, 1M in THF, packaged under Argon in resealable ChemSeal? bottles
    • Packaging500ml
    • Price$366
    • Updated2021-12-16
    • Buy
    • ManufacturerAlfa Aesar
    • Product numberH36830
    • Product descriptionLithium triethylborohydride, 1.7M in THF packaged under Nitrogen in resealable AcroSeal[t bottles
    • Packaging800ml
    • Price$366
    • Updated2021-12-16
    • Buy
    • ManufacturerAlfa Aesar
    • Product number089144
    • Product descriptionLithium triethylborohydride, 1M in THF
    • Packaging500ml
    • Price$366
    • Updated2022-04-27
    • Buy
    • ManufacturerAmerican Custom Chemicals Corporation
    • Product numberING0010991
    • Product descriptionLITHIUM TRIETHYLBOROHYDRIDE 95.00%
    • Packaging25ML
    • Price$131
    • Updated2021-12-16
    • Buy
    • ManufacturerAmerican Custom Chemicals Corporation
    • Product numberING0010991
    • Product descriptionLITHIUM TRIETHYLBOROHYDRIDE 95.00%
    • Packaging5MG
    • Price$500.87
    • Updated2021-12-16
    • Buy
    • ManufacturerSigma-Aldrich
    • Product number179728
    • Product descriptionSuper-Hydride? solution 1.0 M lithium triethylborohydride in THF
    • Packaging100ml
    • Price$110
    • Updated2024-03-01
    • Buy
    • ManufacturerSigma-Aldrich
    • Product number179728
    • Product descriptionSuper-Hydride? solution 1.0?M lithium triethylborohydride in THF
    • Packaging4X25ML
    • Price$152
    • Updated2024-03-01
    • Buy
    • ManufacturerSigma-Aldrich
    • Product number179728
    • Product descriptionSuper-Hydride? solution 1.0 M lithium triethylborohydride in THF
    • Packaging800ml
    • Price$477
    • Updated2024-03-01
    • Buy
    • ManufacturerSigma-Aldrich
    • Product number179728
    • Product descriptionSuper-Hydride? solution 1.0 M lithium triethylborohydride in THF
    • Packaging8l
    • Price$820
    • Updated2024-03-01
    • Buy
    • ManufacturerSigma-Aldrich
    • Product number179728
    • Product descriptionSuper-Hydride? solution 1.0 M lithium triethylborohydride in THF
    • Packaging2l
    • Price$874
    • Updated2023-06-20
    • Buy
    Manufacturer Product number Product description Packaging Price Updated Buy
    Alfa Aesar 089144 Lithium triethylborohydride, 1M in THF 25ml $27.4 2022-04-27 Buy
    Alfa Aesar 042491 Lithium triethylborohydride, 1M in THF, packaged under Argon in resealable ChemSeal? bottles 25ml $33.2 2021-12-16 Buy
    Alfa Aesar 042491 Lithium triethylborohydride, 1M in THF, packaged under Argon in resealable ChemSeal? bottles 50ml $60.4 2021-12-16 Buy
    Alfa Aesar H36830 Lithium triethylborohydride, 1.7M in THF packaged under Nitrogen in resealable AcroSeal[t bottles 100ml $80.9 2021-12-16 Buy
    Alfa Aesar 089144 Lithium triethylborohydride, 1M in THF 100ml $83.1 2022-04-27 Buy
    Alfa Aesar 042491 Lithium triethylborohydride, 1M in THF, packaged under Argon in resealable ChemSeal? bottles 100ml $98 2021-12-16 Buy
    Alfa Aesar 042491 Lithium triethylborohydride, 1M in THF, packaged under Argon in resealable ChemSeal? bottles 500ml $366 2021-12-16 Buy
    Alfa Aesar H36830 Lithium triethylborohydride, 1.7M in THF packaged under Nitrogen in resealable AcroSeal[t bottles 800ml $366 2021-12-16 Buy
    Alfa Aesar 089144 Lithium triethylborohydride, 1M in THF 500ml $366 2022-04-27 Buy
    American Custom Chemicals Corporation ING0010991 LITHIUM TRIETHYLBOROHYDRIDE 95.00% 25ML $131 2021-12-16 Buy
    American Custom Chemicals Corporation ING0010991 LITHIUM TRIETHYLBOROHYDRIDE 95.00% 5MG $500.87 2021-12-16 Buy
    Sigma-Aldrich 179728 Super-Hydride? solution 1.0 M lithium triethylborohydride in THF 100ml $110 2024-03-01 Buy
    Sigma-Aldrich 179728 Super-Hydride? solution 1.0?M lithium triethylborohydride in THF 4X25ML $152 2024-03-01 Buy
    Sigma-Aldrich 179728 Super-Hydride? solution 1.0 M lithium triethylborohydride in THF 800ml $477 2024-03-01 Buy
    Sigma-Aldrich 179728 Super-Hydride? solution 1.0 M lithium triethylborohydride in THF 8l $820 2024-03-01 Buy
    Sigma-Aldrich 179728 Super-Hydride? solution 1.0 M lithium triethylborohydride in THF 2l $874 2023-06-20 Buy

    Properties

    Melting point :66-67° (Binger); mp 78-83° (dec) (Brown, 1977)
    Density :0.892 g/mL at 25 °C
    Flash point :1 °F
    storage temp. :Flammables + water-Freezer (-20°C)e area
    solubility :Miscible with tetrahydrofuran and benzene.
    form :Liquid
    color :Colorless to light gray
    Sensitive :Air & Moisture Sensitive
    Merck :14,5544
    BRN :4151240
    Exposure limits :ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
    OSHA: TWA 200 ppm(590 mg/m3)
    NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3) CAS DataBase Reference :22560-16-3(CAS DataBase Reference)

    Safety Information

    Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
    Signal word: Danger
    Hazard statements:
    Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
    H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
    H260 In contact with water releases flammable gases which may ignite spontaneously Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 1 Danger GHS hazard pictograms P223, P231+P232, P280, P335+ P334,P370+P378, P402+P404, P501
    H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
    H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
    H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger GHS hazard pictograms P280, P305+P351+P338, P310
    H333 May be harmful if inhaled Acute toxicity,inhalation Category 5 P304+P312
    H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
    H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
    Precautionary statements:
    P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
    P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire.
    P231+P232 Handle under inert gas. Protect from moisture.
    P280 Wear protective gloves/protective clothing/eye protection/face protection.
    P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
    P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
    P370+P378 In case of fire: Use … for extinction.
    P402+P404 Store in a dry place. Store in a closed container.
    P403+P235 Store in a well-ventilated place. Keep cool.
    P405 Store locked up.

    Description

    Lithium triethylborohydride is used as a powerful reducing agent in organic synthesis for the conversion of carbonyl compounds to alcohols. It is also used in the preparation of alkynyl alcohols from the cleavage of cyclic keto-vinyl triflates. It is also used in the reduction of esters and lactones to alcohol and diol respectively. Further, it is used to prepare 1-methylcyclohexanol and 1,4-butanediol from 1,2-epoxybutane and gamma-butyrolactone respectively. It is also utilized for reductive cleavage of mesylates and tosylates in synthetic organic chemistry.

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