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ChemicalBook >> CAS DataBase List >> 1,3-Bis(2,4,6-trimethylphenyl)imidazolium chloride

1,3-Bis(2,4,6-trimethylphenyl)imidazolium chloride

1,3-Bis(2,4,6-trimethylphenyl)imidazolium chloride price.
  • $8 - $700.4
  • Product name: 1,3-Bis(2,4,6-trimethylphenyl)imidazolium chloride
  • CAS: 141556-45-8
  • MF: C21H25ClN2
  • MW: 340.89
  • EINECS:
  • MDL Number:MFCD02684541
  • Synonyms:1,3-DIMESITYLIMIDAZOLIUM CHLORIDE;1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOLIUM CHLORIDE;1,3-(2,4,6-TRIMETHYLPHENYL)IMIDAZOLIUM CHLORIDE;N,N'-(2,4,6-TRIMETHYLPHENYL)DIHYDROIMADAZOLIUM CHLORIDE;1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOLI&;1,3-Bis(2,4,6-trimethylphenyl)imidazoliumchloride,min.95%;1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-1H-IMIDAZOLIUM CHLORIDE;1,3-Bis-(2,4,6-trimethyl-phenyl)-3H-imidazol-1-ium chloride
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  • AK Scientific
  • Alfa Aesar
  • Alichem
  • Arctom
  • Biosynth Carbosynth
  • Chemenu
  • Chem-Impex
  • ChemScene
  • ChemSupplyAustralia
  • Crysdot
  • Matrix Scientific
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  • TRC
Package
  • 250mg
  • 1g
  • 2g
  • 5g
  • 10g
  • 25g
  • 100g
  • ManufacturerAK Scientific
  • Product number6881AA
  • Product description1,3-Dimesitylimidazolium Chloride
  • Packaging5g
  • Price$172
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product number6881AA
  • Product description1,3-Dimesitylimidazolium Chloride
  • Packaging1g
  • Price$77
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberH27535
  • Product description1,3-Dimesitylimidazolium chloride, 96%
  • Packaging1g
  • Price$73.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberH27535
  • Product description1,3-Dimesitylimidazolium chloride, 96%
  • Packaging5g
  • Price$257
  • Updated2024-03-01
  • Buy
  • ManufacturerAlichem
  • Product number141556458
  • Product description1,3-Dimesityl-1H-imidazol-3-iumchloride
  • Packaging25g
  • Price$250
  • Updated2021-12-16
  • Buy
  • ManufacturerAlichem
  • Product number141556458
  • Product description1,3-Dimesityl-1H-imidazol-3-iumchloride
  • Packaging100g
  • Price$700.4
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS730428
  • Product description1,3-Dimesityl-1H-imidazol-3-iumchloride 98%
  • Packaging250mg
  • Price$8
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS730428
  • Product description1,3-Dimesityl-1H-imidazol-3-iumchloride 98%
  • Packaging1g
  • Price$10
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS730428
  • Product description1,3-Dimesityl-1H-imidazol-3-iumchloride 98%
  • Packaging5g
  • Price$32
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS730428
  • Product description1,3-Dimesityl-1H-imidazol-3-iumchloride 98%
  • Packaging10g
  • Price$59
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS730428
  • Product description1,3-Dimesityl-1H-imidazol-3-iumchloride 98%
  • Packaging25g
  • Price$138
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFD60750
  • Product description1,3-Dimesitylimidazolium Chloride
  • Packaging1g
  • Price$40
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFD60750
  • Product description1,3-Dimesitylimidazolium Chloride
  • Packaging2g
  • Price$70
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFD60750
  • Product description1,3-Dimesitylimidazolium Chloride
  • Packaging5G
  • Price$110
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFD60750
  • Product description1,3-Dimesitylimidazolium Chloride
  • Packaging10g
  • Price$200
  • Updated2021-12-16
  • Buy
  • ManufacturerChemenu
  • Product numberCM187464
  • Product description1,3-Dimesityl-1H-imidazol-3-iumchloride 98%
  • Packaging10g
  • Price$128
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific 6881AA 1,3-Dimesitylimidazolium Chloride 5g $172 2021-12-16 Buy
AK Scientific 6881AA 1,3-Dimesitylimidazolium Chloride 1g $77 2021-12-16 Buy
Alfa Aesar H27535 1,3-Dimesitylimidazolium chloride, 96% 1g $73.65 2024-03-01 Buy
Alfa Aesar H27535 1,3-Dimesitylimidazolium chloride, 96% 5g $257 2024-03-01 Buy
Alichem 141556458 1,3-Dimesityl-1H-imidazol-3-iumchloride 25g $250 2021-12-16 Buy
Alichem 141556458 1,3-Dimesityl-1H-imidazol-3-iumchloride 100g $700.4 2021-12-16 Buy
Arctom AS730428 1,3-Dimesityl-1H-imidazol-3-iumchloride 98% 250mg $8 2021-12-16 Buy
Arctom AS730428 1,3-Dimesityl-1H-imidazol-3-iumchloride 98% 1g $10 2021-12-16 Buy
Arctom AS730428 1,3-Dimesityl-1H-imidazol-3-iumchloride 98% 5g $32 2021-12-16 Buy
Arctom AS730428 1,3-Dimesityl-1H-imidazol-3-iumchloride 98% 10g $59 2021-12-16 Buy
Arctom AS730428 1,3-Dimesityl-1H-imidazol-3-iumchloride 98% 25g $138 2021-12-16 Buy
Biosynth Carbosynth FD60750 1,3-Dimesitylimidazolium Chloride 1g $40 2021-12-16 Buy
Biosynth Carbosynth FD60750 1,3-Dimesitylimidazolium Chloride 2g $70 2021-12-16 Buy
Biosynth Carbosynth FD60750 1,3-Dimesitylimidazolium Chloride 5G $110 2021-12-16 Buy
Biosynth Carbosynth FD60750 1,3-Dimesitylimidazolium Chloride 10g $200 2021-12-16 Buy
Chemenu CM187464 1,3-Dimesityl-1H-imidazol-3-iumchloride 98% 10g $128 2021-12-16 Buy

Properties

Melting point :>300 °C (lit.)
Boiling point :499.2°C (rough estimate)
Density :1.0279 (rough estimate)
refractive index :1.5940 (estimate)
storage temp. :under inert gas (nitrogen or Argon) at 2–8 °C
form :Powder
color :Off-white to beige
Water Solubility :Slightly soluble in water.
InChIKey :OTOSIXGMLYKKOW-UHFFFAOYSA-M
CAS DataBase Reference :141556-45-8(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

1,3-Bis(2,4,6-trimethylphenyl)imidazolium chloride is used as a phosphine-free ligand in various metal-catalyzed coupling reactions, often with advantageous results in difficult cases. For use in the Pd-catalyzed cross-coupling of aryl Grignards with aryl chlorides (Kumada reaction). Many examples have been recorded of the use of NHC ligands in the Suzuki coupling reaction, for examples utilizing 1,3-dimesitylimidazol-2-ylidene, in the coupling of arylboronic acids with relatively unreactive aryl chlorides.

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