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ChemicalBook >> CAS DataBase List >> Bis(cyclopentadienyl)zirconium dichloride

Bis(cyclopentadienyl)zirconium dichloride

Bis(cyclopentadienyl)zirconium dichloride price.
  • $10 - $700
  • Product name: Bis(cyclopentadienyl)zirconium dichloride
  • CAS: 1291-32-3
  • MF: C10H10Cl2Zr
  • MW: 292.32
  • EINECS:215-066-8
  • MDL Number:MFCD00003726
  • Synonyms:BIS(CYCLOPENTADIENYL)ZIRCONIUMICHLORIDE;BIS(CYCLOPENTADIENYL)ZIRCONIUM DICHLORIDE;DICHLORODICYCLOPENTADIENYLZIRCONIUM;DICYCLOPENTADIENYLZIRCONIUM DICHLORIDE;bis(3-cyclopentadienyl)dichlorozirconium;Bis(cyclopentadienyl)zirconium dichloride~Dichlorobis(cyclopentadienyl)zirconium;ZirconiuM, dichlorobis(h5-2,4-cyclopentadien-1-yl)-;Bis(cyclopentadienyl)zirconiuM(IV) dichloride >=98%
33 prices
Selected condition：
Brand
  • AK Scientific
  • Alfa Aesar
  • American Custom Chemicals Corporation
  • Arctom
  • Chem-Impex
  • Oakwood
  • Rare Earth Products
  • Sigma-Aldrich
  • Strem Chemicals
  • TCI Chemical
  • TRC
  • Usbiological
Package
  • 100mg
  • 1g
  • 5g
  • 10g
  • 25gm
  • 25g
  • 100gm
  • 100g
  • 500g
  • ManufacturerAK Scientific
  • Product numberJ90570
  • Product descriptionZirconocene Dichloride
  • Packaging500g
  • Price$700
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number039558
  • Product descriptionBis(cyclopentadienyl)zirconium dichloride, 99+%
  • Packaging1g
  • Price$18.2
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number012548
  • Product descriptionBis(cyclopentadienyl)zirconium dichloride
  • Packaging5g
  • Price$40.2
  • Updated2023-06-20
  • Buy
  • ManufacturerAlfa Aesar
  • Product number039558
  • Product descriptionBis(cyclopentadienyl)zirconium dichloride, 99+%
  • Packaging5g
  • Price$49.7
  • Updated2023-06-20
  • Buy
  • ManufacturerAlfa Aesar
  • Product number012548
  • Product descriptionBis(cyclopentadienyl)zirconium dichloride
  • Packaging25g
  • Price$121
  • Updated2023-06-20
  • Buy
  • ManufacturerAlfa Aesar
  • Product number039558
  • Product descriptionBis(cyclopentadienyl)zirconium dichloride, 99+%
  • Packaging25g
  • Price$152
  • Updated2023-06-20
  • Buy
  • ManufacturerAlfa Aesar
  • Product number012548
  • Product descriptionBis(cyclopentadienyl)zirconium dichloride
  • Packaging100g
  • Price$357
  • Updated2023-06-20
  • Buy
  • ManufacturerAlfa Aesar
  • Product number039558
  • Product descriptionBis(cyclopentadienyl)zirconium dichloride, 99+%
  • Packaging100g
  • Price$601
  • Updated2023-06-20
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0005701
  • Product descriptionBIS(CYCLOPENTADIENYL)ZIRCONIUM DICHLORIDE 95.00%
  • Packaging5G
  • Price$500
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0005701
  • Product descriptionBIS(CYCLOPENTADIENYL)ZIRCONIUM DICHLORIDE 95.00%
  • Packaging25G
  • Price$640
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberSY010219
  • Product descriptionBis(cyclopentadienyl)zirconium(IV) dichloride ≥98%
  • Packaging1g
  • Price$10
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberSY010219
  • Product descriptionBis(cyclopentadienyl)zirconium(IV) dichloride ≥98%
  • Packaging5g
  • Price$16
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberSY010219
  • Product descriptionBis(cyclopentadienyl)zirconium(IV) dichloride ≥98%
  • Packaging10g
  • Price$30
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberSY010219
  • Product descriptionBis(cyclopentadienyl)zirconium(IV) dichloride ≥98%
  • Packaging25g
  • Price$60
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberSY010219
  • Product descriptionBis(cyclopentadienyl)zirconium(IV) dichloride ≥98%
  • Packaging100g
  • Price$214
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number41302
  • Product descriptionZirconocenedichloride,97%(Assaybytitration) 97%(Assaybytitration)
  • Packaging5G
  • Price$39.2
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific J90570 Zirconocene Dichloride 500g $700 2021-12-16 Buy
Alfa Aesar 039558 Bis(cyclopentadienyl)zirconium dichloride, 99+% 1g $18.2 2021-12-16 Buy
Alfa Aesar 012548 Bis(cyclopentadienyl)zirconium dichloride 5g $40.2 2023-06-20 Buy
Alfa Aesar 039558 Bis(cyclopentadienyl)zirconium dichloride, 99+% 5g $49.7 2023-06-20 Buy
Alfa Aesar 012548 Bis(cyclopentadienyl)zirconium dichloride 25g $121 2023-06-20 Buy
Alfa Aesar 039558 Bis(cyclopentadienyl)zirconium dichloride, 99+% 25g $152 2023-06-20 Buy
Alfa Aesar 012548 Bis(cyclopentadienyl)zirconium dichloride 100g $357 2023-06-20 Buy
Alfa Aesar 039558 Bis(cyclopentadienyl)zirconium dichloride, 99+% 100g $601 2023-06-20 Buy
American Custom Chemicals Corporation ING0005701 BIS(CYCLOPENTADIENYL)ZIRCONIUM DICHLORIDE 95.00% 5G $500 2021-12-16 Buy
American Custom Chemicals Corporation ING0005701 BIS(CYCLOPENTADIENYL)ZIRCONIUM DICHLORIDE 95.00% 25G $640 2021-12-16 Buy
Arctom SY010219 Bis(cyclopentadienyl)zirconium(IV) dichloride ≥98% 1g $10 2021-12-16 Buy
Arctom SY010219 Bis(cyclopentadienyl)zirconium(IV) dichloride ≥98% 5g $16 2021-12-16 Buy
Arctom SY010219 Bis(cyclopentadienyl)zirconium(IV) dichloride ≥98% 10g $30 2021-12-16 Buy
Arctom SY010219 Bis(cyclopentadienyl)zirconium(IV) dichloride ≥98% 25g $60 2021-12-16 Buy
Arctom SY010219 Bis(cyclopentadienyl)zirconium(IV) dichloride ≥98% 100g $214 2021-12-16 Buy
Chem-Impex 41302 Zirconocenedichloride,97%(Assaybytitration) 97%(Assaybytitration) 5G $39.2 2021-12-16 Buy

Properties

Melting point :242-245 °C(lit.)
Boiling point :124-125°C/15mm
Flash point :124-125°C/15mm
storage temp. :Keep in dark place,Inert atmosphere,2-8°C
form :Powder
color :white to off-white
Water Solubility :hydrolysis
Hydrolytic Sensitivity :4: no reaction with water under neutral conditions
Sensitive :Air & Moisture Sensitive
Exposure limits :ACGIH: TWA 5 mg/m3; STEL 10 mg/m3
NIOSH: IDLH 25 mg/m3; TWA 5 mg/m3; STEL 10 mg/m3 CAS DataBase Reference :1291-32-3(CAS DataBase Reference)
NIST Chemistry Reference :Bis(cyclopentadienyl)zirconium dichloride(1291-32-3)
EPA Substance Registry System :Zirconocene dichloride (1291-32-3)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Bis(cyclopentadienyl)zirconium dichloride is used for for Stereoselective Glycosidation. It is also used in the catalyzed transamidation of primary amides with amines. Zirconocene dichloride can also be used to prepare the Negishi reagent,in oxidative cyclisation reactions. Other applications include it is used to promote greener amidations of carboxylic acids and amines in catalytic amounts. This technology avoids the requirement of preactivation of the carboxylic acid or use of coupling reagents.

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