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ChemicalBook >> CAS DataBase List >>Hexamethylenetetramine

Hexamethylenetetramine suppliers

Hexamethylenetetramine

CAS:
100-97-0
MF:
C6H12N4
MW:
140.19

Properties

Melting point:
280 °C (subl.) (lit.)
Boiling point:
246.7°C (rough estimate)
Density 
1.33
vapor density 
4.9 (vs air)
vapor pressure 
<0.01 mm Hg ( 20 °C)
refractive index 
1.4260 (estimate)
Flash point:
482 °F
storage temp. 
Store below +30°C.
solubility 
H2O: 1 M at 20 °C, clear, colorless
form 
Solid
pka
5.1(at 25℃)
color 
white
Odor
Odorless
PH
7-10 (100g/l, H2O, 20℃)
Water Solubility 
895 g/L (20 ºC)
Sensitive 
Hygroscopic
Merck 
14,5966
Sublimation 
263-295 ºC
BRN 
2018
Stability:
Stable. Incompatible with strong acids, strong oxidizing agents.
LogP
-2.18--2 at 20℃

Safety Information

Symbol(GHS) 
GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07
Signal word 
Warning
Hazard statements 
H228-H317
Precautionary statements 
P210-P240-P241-P261-P280-P302+P352
Hazard Codes 
F,Xn,Xi
Risk Statements 
11-42/43-43
Safety Statements 
16-22-24-37
RIDADR 
UN 1328 4.1/PG 3
WGK Germany 
1
RTECS 
MN4725000
9-23
Autoignition Temperature
770 °F
TSCA 
Yes
HS Code 
2933 69 40
HazardClass 
4.1
PackingGroup 
III
Toxicity
LD50 orally in Rabbit: 9200 mg/kg

Use

Hexamethylenetetramine is hygroscopic. Hexamethylenetetramine is sensitive to exposure to heat. Hexamethylenetetramine is incompatible with oxidizing agents. Hexamethylenetetramine is also incompatible with acids. Hexamethylenetetramine reacts violently with sodium peroxide. Hexamethylenetetramine reacts explosively with 1-bromopentaborane(9) at temperatures above 194° F. The complex with iodine deflagrates at 280° F. The 1:1 addition complex with iodoform has exploded at 352° F. Hexamethylenetetramine is corrosive to some metals, such as aluminum and zinc . Special Hazards of Combustion Products: Formaldehyde gas and ammonia may be given off when hot [USCG, 1999].

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