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ChemicalBook >> CAS DataBase List >>1,4-DINITROBENZENE

1,4-DINITROBENZENE suppliers

1,4-DINITROBENZENE

CAS:
100-25-4
MF:
C6H4N2O4
MW:
168.11

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Properties

Melting point:
170-173 °C(lit.)
Boiling point:
183.4 °C34 mm Hg(lit.)
Density 
1.625 g/mL at 25 °C(lit.)
vapor pressure 
2.25 x 10-4 mmHg at 35 °C (Hine et al., 1963)
refractive index 
1.725 (589.3 nm)
Flash point:
150 °C
storage temp. 
Store below +30°C.
solubility 
alcohol: soluble1g in 300ml
form 
Crystals or Powder
color 
Ochre to orange
Water Solubility 
Soluble in water. (0.8 g/L) at 20°C.
Merck 
14,3273
BRN 
1105828
Henry's Law Constant
4.79(x 10-7 atm?m3/mol) at 35 °C (approximate - calculated from water solubility and vapor pressure)
Exposure limits
NIOSH REL: TWA 1, IDLH 50; OSHA PEL: TWA 1 ACGIH TLV: TWA 0.15 ppm for all isomers (adopted).
Stability:
Stable, but may be shock-sensitive. May explode if heated. Incompatible with oxidizing agents, strong bases, nitric acid, many metals, tin oxides.
CAS DataBase Reference
100-25-4(CAS DataBase Reference)
EPA Substance Registry System
p-Dinitrobenzene (100-25-4)

Safety Information

Symbol(GHS) 
GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS06,GHS08,GHS09
Signal word 
Danger
Hazard statements 
H300+H310+H330-H373-H410
Precautionary statements 
P262-P264-P273-P280-P302+P352+P310-P304+P340+P310
Hazard Codes 
T+,N,T,F
Risk Statements 
26/27/28-33-34-50/53-52/53-39/23/24/25-23/24/25-11
Safety Statements 
28-36/37-45-60-61-16
RIDADR 
UN 3443 6.1/PG 2
OEB
C
OEL
TWA: 1 mg/m3 [skin]
WGK Germany 
3
RTECS 
CZ7525000
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
II
HS Code 
29042090
Hazardous Substances Data
100-25-4(Hazardous Substances Data)
Toxicity
IC50 (24-h) for river bacteria 1.27 mg/L (Yuan and Lang, 1997).

Use

Crystallise 1,4-dinitrobenzene from EtOH or EtOAc. Dry it under vacuum over P2O5. It can be sublimed in a vacuum. [Beilstein 5 IV 741.]

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