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12-??????????

12-??????????
12-?????????? ??? ???
?? ??:
106-14-9
???:
12-??????????
???(??):
12-??????????;12-??????????;12-?????????;12-?????????;????A;????????????;12-??????????
???:
12-HYDROXYSTEARIC ACID
???(??):
12-HSA;12-hydroxy-octadecanoicaci;KOW;12-hydroxystearic;12-HYDROXYOCTADECANOIC ACID;Octadecanoic acid, 12-hydroxy-;harwaxa;d-12HSA;Harwax A;ceritfac3
CBNumber:
CB9162185
???:
C18H36O3
??? ??:
300.48
MOL ??:
106-14-9.mol
MSDS ??:
SDS

12-?????????? ??

???
74-76 °C (lit.)
?? ?
180 °C
??
1.0238 (rough estimate)
???
0Pa at 20℃
???
1.4200 (estimate)
?? ??
−20°C
???
?????(?? ???, ??), ???????(?? ???, ??), ???
??? ??
?? ??
?? ?? (pKa)
4.78±0.10(Predicted)
??
???
???
???, ???, ?????? ?????. ?? ???.
BRN
1726730
LogP
5.7
CAS ??????
106-14-9(CAS DataBase Reference)
EPA
Octadecanoic acid, 12-hydroxy- (106-14-9)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi
?? ???? ?? 36/37/38
????? 26-36
WGK ?? 3
RTECS ?? WI3850000
TSCA Yes
HS ?? 29181990
?? ?? ??? 106-14-9(Hazardous Substances Data)
???? ?? KE-20750
????(GHS): GHS hazard pictograms
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ?? GHS hazard pictograms
??????:
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P280 ????/???/???/?????? ?????.
P302+P352 ??? ??? ??? ?? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P321 (…) ??? ???.
P332+P313 ?? ??? ??? ???? ??· ??? ????.
P362 ??? ??? ?? ?? ?? ?????
NFPA 704
0
0 0

12-?????????? C??? ??, ??, ??

??

12-Hydroxy stearic acid (12-HSA) is a saturated hydroxy fatty acid. It's a waxy, odourless, tasteless and cream coloured compound in flakes / powder.
appearance creamish flakes or powder
melting point °C min. 70
colour Gardner max. 6
colour (on 1” Lovibond) max 20 yellow / max. 4,5 red
acid value mg KOH/g min. 175
iodine value (Wijs) g I2/100g max. 5
hydroxyl value min. 150
saponification value mg KOH/g 175 - 190

??? ??

white powder

??

12-Hydroxystearic acid is used in cosmetics, wax blends, heavy duty greases, polishes, inks and hot melt adhesives, as a lubricant for natural and synthetic rubbers and as a source for industrial oleo chemicals. It is also used as an intermediate in pharmaceuticals.

??

ChEBI: A hydroxy fatty acid that is stearic acid bearing a hydroxy substituent at position 12.

?? ??

Non-isothermal nucleation rate of a self-assembling fibrillar network of 12-hydroxyoctadecanoic acid (12-hydroxystearic acid) in canola oil has been reported. It is commonly used as gelling agent for organic solvents. Self-assembled monolayers of 12-hydroxyoctadecanoic acid and its 4,4′-bipyridinium salt have been observed on the solution graphite interface using scanning tunnelling microscopy.

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