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1344-48-5
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Mercury(II) sulfide
???(??):
almaden;CINNABAR;vermilion;c.i.77766;Liver ore;vermillion;redcinnabar;pigmentred106;Mercurysulfide;ETHIOPS MINERAL
CBNumber:
CB6173856
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HgS
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232.65
MOL ??:
1344-48-5.mol
MSDS ??:
SDS

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583.5 °C(lit.)
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584°C
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8.1 g/mL at 25 °C
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insoluble in H2O; soluble in acid solutions, ethanol
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Crystal Structure
Cubic, Sphalerite Structure - Space Group F(-4)3m
crystal system
Three sides
Merck
14,5888
Space group
P3121
Solubility Product Constant (Ksp)
pKsp: 52.4
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.413170.413170.9445190901200.1396
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ACGIH: TWA 0.025 mg/m3 (Skin)
NIOSH: IDLH 10 mg/m3; TWA 0.05 mg/m3; Ceiling 0.1 mg/m3
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CAS ??????
1344-48-5(CAS DataBase Reference)
EPA
Mercury sulfide (HgS) (1344-48-5)
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  • ?? ? ???? ?? (GHS)
??? ?? N-T,Xi
?? ???? ?? 50/53-36-33-23/24/25-43-31
????? 61-60-45-36/37/39-28A-26-36/37
????(UN No.) 2025
WGK ?? -
RTECS ?? OX0720000
F ?????? 8
TSCA Yes
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???? II
HS ?? 28521000
???? ?? KE-23133
????(GHS): GHS hazard pictograms
?? ?: Warning
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H317 ????? ?? ??? ??? ? ?? ?? ??? ?? ?? 1 ?? GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
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P261 ??·?·??·???·??·...·????? ??? ????.
P272 ??? ??? ??? ??? ???? ???.
P280 ????/???/???/?????? ?????.
P302+P352 ??? ??? ??? ?? ????.
P333+P313 ????? ?? ??? ???? ???? ??·??? ????.
NFPA 704
0
4 0

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Fine, bright-scarlet powder.Insoluble in water and alcohol.
Mercury(II) sulfide
Cinnabar, HgS, cherry red crystal to 5 mm among snow white rhombic dolomite, CaMg(CO3)2. Wanshan mine, Tongren Pref., Guizhou prov., China.

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Mercury(II) sulfide is used in paint, sealing wax and preservatives.

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cinnabar: A bright red mineralform of mercury(II) sulphide, HgS,crystallizing in the hexagonal system;the principal ore of mercury. Itis deposited in veins and impregnationsnear recent volcanic rocks andhot springs. The chief sources includeSpain, Italy, and Yugoslavia.

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Readily oxidized as to be pyrophoric in air [Bretherick 1979. p. 120].

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Inorganic reducing agents, such as MERCURY(II) SULFIDE, react with oxidizing agents to generate heat and products that may be flammable, combustible, or otherwise reactive.

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Highly toxic by ingestion, inhalation, and skin absorption.

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Acute poisoning can result from inhaling dust concentrations of 1.2-8.5 mg/m 3 in air; symptoms include pain and tightness in chest, coughing, and difficulty in breathing. If ingested, toxicity depends on release of t he Hg ++ ion; chronic mercury poisoning can cause kidney, mental, and nervous disturbances. Dust irritates eyes and frequently causes allergic dermatitis; absorption through skin can cause systemic poisoning.

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